Impedance Spectroscopy of Perovskite Solar Cells With SnO2 Embedding Graphene Nanoplatelets

Characterizing the electron transport layer (ETL)/perovskite interface in perovskite solar cells (PSCs) is of paramount importance for their overall performance. In this article the effect of different concentrations of graphene nanoplatelets in addition to SnO 2 is investigated by considering degra...

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Veröffentlicht in:IEEE journal of photovoltaics 2023-11, Vol.13 (6), p.1-7
Hauptverfasser: Matacena, Ilaria, Lancellotti, Laura, Daliento, Santolo, Alfano, Brigida, De Maria, Antonella, La Ferrara, Vera, Mercaldo, Lucia V., Lucia Miglietta, Maria, Polichetti, Tiziana, Rametta, Gabriella, Sannino, Gennaro V., Veneri, Paola Delli, Guerriero, Pierluigi
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container_issue 6
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container_title IEEE journal of photovoltaics
container_volume 13
creator Matacena, Ilaria
Lancellotti, Laura
Daliento, Santolo
Alfano, Brigida
De Maria, Antonella
La Ferrara, Vera
Mercaldo, Lucia V.
Lucia Miglietta, Maria
Polichetti, Tiziana
Rametta, Gabriella
Sannino, Gennaro V.
Veneri, Paola Delli
Guerriero, Pierluigi
description Characterizing the electron transport layer (ETL)/perovskite interface in perovskite solar cells (PSCs) is of paramount importance for their overall performance. In this article the effect of different concentrations of graphene nanoplatelets in addition to SnO 2 is investigated by considering degradation over time. PSCs behavior is monitored by collecting dark current-voltage curves as fabricated and after two months. A deeper insight is gained through impedance spectroscopy analysis. From Nyquist plots equivalent circuit models and the corresponding time constants are extracted. Moreover, resistive part of the impedance associated with high frequency has been related to static shunt resistance, assessing one of the considered ETL doping concentration as the more suitable choice to reduce degradation.
doi_str_mv 10.1109/JPHOTOV.2023.3301674
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subjects Behavioral sciences
Dark current
Degradation
Electron transport
Equivalent circuits
Fabrication
Graphene
Impedance
Impedance spectroscopy
Impedance spectroscopy (IS)
Nyquist plots
perovskite solar cells (PSCs)
Perovskites
Photovoltaic cells
Platelets (materials)
Resistance
Shunt resistance
Solar cells
Tin dioxide
title Impedance Spectroscopy of Perovskite Solar Cells With SnO2 Embedding Graphene Nanoplatelets
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