A green and efficient process for the synthesis of Benzothiazinones using Phosphate fertilizers MAP, DAP and TSP as heterogeneous catalysts
The aim of this work is to prove the efficiency of the Phosphate fertilizers mono-ammonium phosphate (MAP), di-ammonium phosphate (DAP) and triple-super phosphate (TSP) as a “green” heterogeneous catalysts for the synthesis of 2-aryl-2H-benzo[b][1,4]thiazin-3(4H)-ones via the C-S and C-N coupling pr...
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Veröffentlicht in: | Journal of the Turkish Chemical Society, Section A, Chemistry Section A, Chemistry, 2019-10, Vol.6 (3), p.349-354 |
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container_title | Journal of the Turkish Chemical Society, Section A, Chemistry |
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creator | BAHAMMOU, İmane MALEK, Badr GHAILANE, Tourya GHAILANE, Rachida BOUKHRIS, Said SOUIZI, Abdelaziz |
description | The aim of this work is
to prove the efficiency of the Phosphate fertilizers mono-ammonium phosphate
(MAP), di-ammonium phosphate (DAP) and triple-super phosphate (TSP) as a
“green” heterogeneous catalysts for the synthesis of 2-aryl-2H-benzo[b][1,4]thiazin-3(4H)-ones
via the C-S and C-N coupling process of gem-dicyano epoxide with
α-aminothiophenol. To optimize the reaction conditions, the synthesis was
conducted with a range of solvents, catalyst amounts and catalyst particle
sizes. Also, the potential recyclability of the catalysts was confirmed by
running the reaction using the recycled catalyst. |
doi_str_mv | 10.18596/jotcsa.563093 |
format | Article |
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to prove the efficiency of the Phosphate fertilizers mono-ammonium phosphate
(MAP), di-ammonium phosphate (DAP) and triple-super phosphate (TSP) as a
“green” heterogeneous catalysts for the synthesis of 2-aryl-2H-benzo[b][1,4]thiazin-3(4H)-ones
via the C-S and C-N coupling process of gem-dicyano epoxide with
α-aminothiophenol. To optimize the reaction conditions, the synthesis was
conducted with a range of solvents, catalyst amounts and catalyst particle
sizes. Also, the potential recyclability of the catalysts was confirmed by
running the reaction using the recycled catalyst.</description><identifier>ISSN: 2149-0120</identifier><identifier>EISSN: 2149-0120</identifier><identifier>DOI: 10.18596/jotcsa.563093</identifier><language>eng</language><publisher>Türkiye Kimya Derneği</publisher><subject>Kimya</subject><ispartof>Journal of the Turkish Chemical Society, Section A, Chemistry, 2019-10, Vol.6 (3), p.349-354</ispartof><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c2273-818fc507bbc0ea84d502ce5744d1960a05fb3793a67cab922a01c7b1ed9c13463</citedby><cites>FETCH-LOGICAL-c2273-818fc507bbc0ea84d502ce5744d1960a05fb3793a67cab922a01c7b1ed9c13463</cites><orcidid>0000-0002-4713-2057 ; 0000-0002-1139-8451 ; 0000-0001-9541-4318 ; 0000-0002-6241-2954 ; 0000-0002-5424-839X ; 0000-0002-6796-1442</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27903,27904</link.rule.ids></links><search><contributor>Küçükbay,Hasan</contributor><creatorcontrib>BAHAMMOU, İmane</creatorcontrib><creatorcontrib>MALEK, Badr</creatorcontrib><creatorcontrib>GHAILANE, Tourya</creatorcontrib><creatorcontrib>GHAILANE, Rachida</creatorcontrib><creatorcontrib>BOUKHRIS, Said</creatorcontrib><creatorcontrib>SOUIZI, Abdelaziz</creatorcontrib><title>A green and efficient process for the synthesis of Benzothiazinones using Phosphate fertilizers MAP, DAP and TSP as heterogeneous catalysts</title><title>Journal of the Turkish Chemical Society, Section A, Chemistry</title><description>The aim of this work is
to prove the efficiency of the Phosphate fertilizers mono-ammonium phosphate
(MAP), di-ammonium phosphate (DAP) and triple-super phosphate (TSP) as a
“green” heterogeneous catalysts for the synthesis of 2-aryl-2H-benzo[b][1,4]thiazin-3(4H)-ones
via the C-S and C-N coupling process of gem-dicyano epoxide with
α-aminothiophenol. To optimize the reaction conditions, the synthesis was
conducted with a range of solvents, catalyst amounts and catalyst particle
sizes. Also, the potential recyclability of the catalysts was confirmed by
running the reaction using the recycled catalyst.</description><subject>Kimya</subject><issn>2149-0120</issn><issn>2149-0120</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNpNkD1PwzAURSMEElXpyuyRgRbbifMxhrZApSIqUebIcZ4bV8Gu_Nyh_Qv8aaKGgek8PV3dK50oumd0xnJRpE97FxTKmUhjWsRX0YizpJhSxun1v_s2miDuKaX9hwqRjKKfkuw8gCXSNgS0NsqADeTgnQJEop0noQWCJ9sDDRKnyTPYswutkWdjnQUkRzR2Rzatw0MrAxANPpjOnMEjeS83j2RRbi4D28-eSFoI4N0OLLgjEiWD7E4Y8C660bJDmPxxHH29LLfzt-n643U1L9dTxXkWT3OWayVoVteKgsyTRlCuQGRJ0rAipZIKXcdZEcs0U7IuOJeUqaxm0BSKxUkaj6OHodc0IDtnO2Oh2rujt_1qtVosy3XFWMpF0UdnQ1R5h-hBVwdvvqU_VYxWF_HVIL4axMe_HA54_w</recordid><startdate>20191020</startdate><enddate>20191020</enddate><creator>BAHAMMOU, İmane</creator><creator>MALEK, Badr</creator><creator>GHAILANE, Tourya</creator><creator>GHAILANE, Rachida</creator><creator>BOUKHRIS, Said</creator><creator>SOUIZI, Abdelaziz</creator><general>Türkiye Kimya Derneği</general><scope>AAYXX</scope><scope>CITATION</scope><scope>IEBAR</scope><orcidid>https://orcid.org/0000-0002-4713-2057</orcidid><orcidid>https://orcid.org/0000-0002-1139-8451</orcidid><orcidid>https://orcid.org/0000-0001-9541-4318</orcidid><orcidid>https://orcid.org/0000-0002-6241-2954</orcidid><orcidid>https://orcid.org/0000-0002-5424-839X</orcidid><orcidid>https://orcid.org/0000-0002-6796-1442</orcidid></search><sort><creationdate>20191020</creationdate><title>A green and efficient process for the synthesis of Benzothiazinones using Phosphate fertilizers MAP, DAP and TSP as heterogeneous catalysts</title><author>BAHAMMOU, İmane ; MALEK, Badr ; GHAILANE, Tourya ; GHAILANE, Rachida ; BOUKHRIS, Said ; SOUIZI, Abdelaziz</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2273-818fc507bbc0ea84d502ce5744d1960a05fb3793a67cab922a01c7b1ed9c13463</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Kimya</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>BAHAMMOU, İmane</creatorcontrib><creatorcontrib>MALEK, Badr</creatorcontrib><creatorcontrib>GHAILANE, Tourya</creatorcontrib><creatorcontrib>GHAILANE, Rachida</creatorcontrib><creatorcontrib>BOUKHRIS, Said</creatorcontrib><creatorcontrib>SOUIZI, Abdelaziz</creatorcontrib><collection>CrossRef</collection><collection>Idealonline online kütüphane - Journals</collection><jtitle>Journal of the Turkish Chemical Society, Section A, Chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>BAHAMMOU, İmane</au><au>MALEK, Badr</au><au>GHAILANE, Tourya</au><au>GHAILANE, Rachida</au><au>BOUKHRIS, Said</au><au>SOUIZI, Abdelaziz</au><au>Küçükbay,Hasan</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A green and efficient process for the synthesis of Benzothiazinones using Phosphate fertilizers MAP, DAP and TSP as heterogeneous catalysts</atitle><jtitle>Journal of the Turkish Chemical Society, Section A, Chemistry</jtitle><date>2019-10-20</date><risdate>2019</risdate><volume>6</volume><issue>3</issue><spage>349</spage><epage>354</epage><pages>349-354</pages><issn>2149-0120</issn><eissn>2149-0120</eissn><abstract>The aim of this work is
to prove the efficiency of the Phosphate fertilizers mono-ammonium phosphate
(MAP), di-ammonium phosphate (DAP) and triple-super phosphate (TSP) as a
“green” heterogeneous catalysts for the synthesis of 2-aryl-2H-benzo[b][1,4]thiazin-3(4H)-ones
via the C-S and C-N coupling process of gem-dicyano epoxide with
α-aminothiophenol. To optimize the reaction conditions, the synthesis was
conducted with a range of solvents, catalyst amounts and catalyst particle
sizes. Also, the potential recyclability of the catalysts was confirmed by
running the reaction using the recycled catalyst.</abstract><pub>Türkiye Kimya Derneği</pub><doi>10.18596/jotcsa.563093</doi><tpages>6</tpages><orcidid>https://orcid.org/0000-0002-4713-2057</orcidid><orcidid>https://orcid.org/0000-0002-1139-8451</orcidid><orcidid>https://orcid.org/0000-0001-9541-4318</orcidid><orcidid>https://orcid.org/0000-0002-6241-2954</orcidid><orcidid>https://orcid.org/0000-0002-5424-839X</orcidid><orcidid>https://orcid.org/0000-0002-6796-1442</orcidid><oa>free_for_read</oa></addata></record> |
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source | Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals |
subjects | Kimya |
title | A green and efficient process for the synthesis of Benzothiazinones using Phosphate fertilizers MAP, DAP and TSP as heterogeneous catalysts |
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