Clay Catalyzed Reactions of Indole and its Methyl Derivatives with α, β-unsaturated Carbonyl Compounds

Electrophilic substituons reactions of indole and 1-methylindole with methyl propiolate in the presence of K-10 montmorillonite were obtained the formation of the corresponding methyl 3,3-bis(indolyl)propanoates. The reaction of 1,3-dimethylindole with methyl propiolate was given methyl 3,3-bis(1,3-...

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Veröffentlicht in:	Croatica Chemica Acta 2014-07, Vol.87 (2), p.137-142
Hauptverfasser:	Dasbasi, Teslima, Abdullah, Meysun I.
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Sprache:	eng
Schlagworte:	benzoazepine bisindolylester K-10 montmorillonite Michael addition trisindolylester
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container_title	Croatica Chemica Acta
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creator	Dasbasi, Teslima Abdullah, Meysun I.
description	Electrophilic substituons reactions of indole and 1-methylindole with methyl propiolate in the presence of K-10 montmorillonite were obtained the formation of the corresponding methyl 3,3-bis(indolyl)propanoates. The reaction of 1,3-dimethylindole with methyl propiolate was given methyl 3,3-bis(1,3-dimethyl-1H-indol-2-yl)propanoate, methyl 1,5-dimethyl-1H-benzo[b]azepine-3-carboxylate and methyl 3,3,3-tris(1,3-dimethyl-1H-indol-2-yl)propanoate. The reaction of 1,3-dimethylindole with 2-cyclopentenone was yielded a typical addition product, similarly the reaction of indole and 1-methylindole with 2-cyclopentenone were concluded the expected addition products only.
doi_str_mv	10.5562/cca2285
format	Article
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The reaction of 1,3-dimethylindole with 2-cyclopentenone was yielded a typical addition product, similarly the reaction of indole and 1-methylindole with 2-cyclopentenone were concluded the expected addition products only.</description><subject>benzoazepine</subject><subject>bisindolylester</subject><subject>K-10 montmorillonite</subject><subject>Michael addition</subject><subject>trisindolylester</subject><issn>0011-1643</issn><issn>1334-417X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><recordid>eNo9kM1Kw0AcxBdRsFbxFfbmxeh-Jz1K_CpUBFHwFv7ZDxJNs2V3q8S30gfpMxlp8TTD8Js5DEKnlFxIqdil1sBYIffQhHIuMkHz1300IYTSjCrBD9FRjG-EMClkMUFN2cGAS0jQDV_W4CcLOrW-j9g7PO-N7yyG3uA2RfxgUzN0-NqG9gNS-2Ej_mxTgzff53jzk637CGkdII0zJYTa9yNc-uXKr3sTj9GBgy7ak51O0cvtzXN5ny0e7-bl1SLTTBYpc4IXRlMmOLM0F9oQJYwwTBlVuHw2c7VijtS1noEEcFQzMNZxVRSSKFtzPkXZdrcJGt6rVWiXEIbKQ1ttkxi0HW1FmZqpfOTPtrwOPsZg3X-Fkurv0Gp3KP8FfktsDA</recordid><startdate>20140701</startdate><enddate>20140701</enddate><creator>Dasbasi, Teslima</creator><creator>Abdullah, Meysun I.</creator><general>Hrvatsko kemijsko društvo</general><scope>AAYXX</scope><scope>CITATION</scope><scope>VP8</scope></search><sort><creationdate>20140701</creationdate><title>Clay Catalyzed Reactions of Indole and its Methyl Derivatives with α, β-unsaturated Carbonyl Compounds</title><author>Dasbasi, Teslima ; Abdullah, Meysun I.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c258t-f438dc12432e174cd064d4d26d68f799fb62f0bbc9a5aaf1c2adef3688506eb33</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>benzoazepine</topic><topic>bisindolylester</topic><topic>K-10 montmorillonite</topic><topic>Michael addition</topic><topic>trisindolylester</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Dasbasi, Teslima</creatorcontrib><creatorcontrib>Abdullah, Meysun I.</creatorcontrib><collection>CrossRef</collection><collection>Hrcak: Portal of scientific journals of Croatia</collection><jtitle>Croatica Chemica Acta</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Dasbasi, Teslima</au><au>Abdullah, Meysun I.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Clay Catalyzed Reactions of Indole and its Methyl Derivatives with α, β-unsaturated Carbonyl Compounds</atitle><jtitle>Croatica Chemica Acta</jtitle><date>2014-07-01</date><risdate>2014</risdate><volume>87</volume><issue>2</issue><spage>137</spage><epage>142</epage><pages>137-142</pages><issn>0011-1643</issn><eissn>1334-417X</eissn><coden>CCACAA</coden><abstract>Electrophilic substituons reactions of indole and 1-methylindole with methyl propiolate in the presence of K-10 montmorillonite were obtained the formation of the corresponding methyl 3,3-bis(indolyl)propanoates. 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subjects	benzoazepine bisindolylester K-10 montmorillonite Michael addition trisindolylester
title	Clay Catalyzed Reactions of Indole and its Methyl Derivatives with α, β-unsaturated Carbonyl Compounds
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