Supramolecular Interactions Involved in the Solid State Structure of N,N'-[bis(pyridin-2-yl)formylidene]ethane-1,2-diamine

The structure of the symmetrical Schiff base, N,N'-[bis(pyridin-2-yl)formylidene]ethane-1,2-diamine (bpfd) has been characterized by single crystal X-ray diffraction. The non-covalent supramolecular chemistry involved in the crystal structure of this ligand has been carefully investigated. The...

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Veröffentlicht in:	Croatica Chemica Acta 2014-07, Vol.87 (2), p.123-128
Hauptverfasser:	El-Qisairi, Arab K., Qaseer, Hanan A., Alshahateet, Solhe F., Qaseer, M. K. Hasan, Zaghal, Mukarram H., Al-Btoush, Wa'el, Dawe, Louise N.
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Schlagworte:	centrosymmetric dimer interactions Chemical bonds Chemical properties Chemical reactions Crystal structure Diffraction high Z-value structure Identification and classification Molecular chemistry Observations Phase transitions Recrystallization Schiff bases Solid solutions spectral properties unit cell packing arrangement
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container_title	Croatica Chemica Acta
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creator	El-Qisairi, Arab K. Qaseer, Hanan A. Alshahateet, Solhe F. Qaseer, M. K. Hasan Zaghal, Mukarram H. Al-Btoush, Wa'el Dawe, Louise N.
description	The structure of the symmetrical Schiff base, N,N'-[bis(pyridin-2-yl)formylidene]ethane-1,2-diamine (bpfd) has been characterized by single crystal X-ray diffraction. The non-covalent supramolecular chemistry involved in the crystal structure of this ligand has been carefully investigated. The structure adopted different motifs of nitrogen-hydrogen interactions that led to the formation of centrosymmetric dimers. In addition, edge-edge and face-face nitrogen-nitrogen interactions were observed and reported. The Schiff base (bpfd) ligand crystallizes in a monoclinic space group C12/c1 with a = 19.128(2) Å; b = 5.8776(6) Å; c = 13.1403(15) Å; α = 90°; β = 121.970°(4); γ = 90° and z = 4. This structure is an example of compounds with many symmetry-independent molecules in the asymmetric unit cell (Z > 2). Keywords: centrosymmetric dimer interactions, unit cell packing arrangement, spectral properties, high Z-value structure
doi_str_mv	10.5562/cca2289
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K. Hasan ; Zaghal, Mukarram H. ; Al-Btoush, Wa'el ; Dawe, Louise N.</creator><creatorcontrib>El-Qisairi, Arab K. ; Qaseer, Hanan A. ; Alshahateet, Solhe F. ; Qaseer, M. K. Hasan ; Zaghal, Mukarram H. ; Al-Btoush, Wa'el ; Dawe, Louise N.</creatorcontrib><description>The structure of the symmetrical Schiff base, N,N'-[bis(pyridin-2-yl)formylidene]ethane-1,2-diamine (bpfd) has been characterized by single crystal X-ray diffraction. The non-covalent supramolecular chemistry involved in the crystal structure of this ligand has been carefully investigated. The structure adopted different motifs of nitrogen-hydrogen interactions that led to the formation of centrosymmetric dimers. In addition, edge-edge and face-face nitrogen-nitrogen interactions were observed and reported. The Schiff base (bpfd) ligand crystallizes in a monoclinic space group C12/c1 with a = 19.128(2) Å; b = 5.8776(6) Å; c = 13.1403(15) Å; α = 90°; β = 121.970°(4); γ = 90° and z = 4. 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K. Hasan</creatorcontrib><creatorcontrib>Zaghal, Mukarram H.</creatorcontrib><creatorcontrib>Al-Btoush, Wa'el</creatorcontrib><creatorcontrib>Dawe, Louise N.</creatorcontrib><title>Supramolecular Interactions Involved in the Solid State Structure of N,N'-[bis(pyridin-2-yl)formylidene]ethane-1,2-diamine</title><title>Croatica Chemica Acta</title><description>The structure of the symmetrical Schiff base, N,N'-[bis(pyridin-2-yl)formylidene]ethane-1,2-diamine (bpfd) has been characterized by single crystal X-ray diffraction. The non-covalent supramolecular chemistry involved in the crystal structure of this ligand has been carefully investigated. The structure adopted different motifs of nitrogen-hydrogen interactions that led to the formation of centrosymmetric dimers. In addition, edge-edge and face-face nitrogen-nitrogen interactions were observed and reported. The Schiff base (bpfd) ligand crystallizes in a monoclinic space group C12/c1 with a = 19.128(2) Å; b = 5.8776(6) Å; c = 13.1403(15) Å; α = 90°; β = 121.970°(4); γ = 90° and z = 4. This structure is an example of compounds with many symmetry-independent molecules in the asymmetric unit cell (Z > 2). 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subjects	centrosymmetric dimer interactions Chemical bonds Chemical properties Chemical reactions Crystal structure Diffraction high Z-value structure Identification and classification Molecular chemistry Observations Phase transitions Recrystallization Schiff bases Solid solutions spectral properties unit cell packing arrangement
title	Supramolecular Interactions Involved in the Solid State Structure of N,N'-[bis(pyridin-2-yl)formylidene]ethane-1,2-diamine
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