Trace Metal Enrichments in Water of the Okavango Delta (Botswana): Hydrological Consequences

The Okavango Delta in northern Botswana is an endorheic ecosystem formed by 150,000 islands surrounded by a flood plain. The vegetation of these islands displays an external tree ring enclosing a barren interior domain with evaporitic deposits. We sampled the groundwater into piezometers across an island at the southwest of the Delta, and drilled sediments. The geochemical analysis of the water exhibits two different compositions: a fresh water in the floodplain and a saline water in the interior part. These inner samples display enrichments in heavy metals, metalloids and critical metals such as, Rare Earth Elements (REE). The latest show a continuous enrichment from LREE to HREE and positive Ce and Eu anomalies, associated to alkaline pH. Overall, the two types of displayed REE patterns fingerprint two different water sources. The geochemistry of sediments indicates the same composition whatever the sample location and no traces of evaporitic deposits was found. The variations in the water table depth in the piezometers shows different hydrological behaviors in between the floodplain and the barren zone which does not follow the flood cycle. Thus, we document two different aquifers with independent hydrological behaviors: a surface fresh‐water aquifer in the floodplain connected to the channels, and a saline confined aquifer below the islands. The contrasted geochemical composition of the waters explains the distribution of the vegetation which survives through access to fresh water. The hydrological architecture of this island in the southwestern Delta differs from other islands, highlighting the hydrological complexity of the Okavango Delta. Plain Language Summary Endorheic basins are hotspots for biodiversity and human activities. The Okavango Delta in northern Botswana is one of the largest wetlands in Africa, and forms a huge oasis in the arid Kalahari Desert. The water flowing from Angola reaches the mega‐alluvial fan confined in between two fault zones, before being absorbed by evaporation and evapotranspiration. The 150,000 islands scattering the wetland are surrounded by an annually flooded alluvial plain. The depth of the water table in the floodplain follows the water level variations in the channels; whereas it remains deeper and nearly constant in the interior part of the island. The chemical analysis of the water samples recovered in piezometers reveals that the deep saline water contains high concentrations of trace elements, whereas the w