Effect of chemical composition on borosilicate glass behavior under irradiation
Assessing the behavior under irradiation of oxide glasses used for nuclear waste immobilization is essential for qualifying the long-term behavior of the wasteform. This study focuses on a series of borosilicate glasses of increasing chemical complexity. The effects of irradiation in these materials...
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| Veröffentlicht in: | Journal of non-crystalline solids 2010-03, Vol.356 (6), p.388-393 |
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| container_issue | 6 |
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| container_title | Journal of non-crystalline solids |
| container_volume | 356 |
| creator | Bonfils, J. de Peuget, S. Panczer, G. Ligny, D. de Henry, S. Noël, P.-Y. Chenet, A. Champagnon, B. |
| description | Assessing the behavior under irradiation of oxide glasses used for nuclear waste immobilization is essential for qualifying the long-term behavior of the wasteform. This study focuses on a series of borosilicate glasses of increasing chemical complexity. The effects of irradiation in these materials were investigated through multi-energy external irradiation by gold ions to obtain a constant nuclear damage level to a depth of about 2
μm. The macroscopic behavior of the glass was estimated from Vickers hardness measurement. The mechanical properties of all the borosilicate glasses studied were observed to improve, their hardness decreasing with the dose down by 30–35%. This evolution is also associated to an increase of the fracture toughness of the glass under irradiation. Analysis of the structural changes in the sodium borosilicate glass common to all the compositions studied with respect to dose revealed a progressive shift to higher wavenumbers in the vibration Raman band near 495
cm
−1 indicating a drop in the mean Si–O–Si angle. At the same time, modifications in the
Q
n
band between 850 and 1200
cm
−1 are observed and characterize increasing depolymerization of the silicate network. |
| doi_str_mv | 10.1016/j.jnoncrysol.2009.11.030 |
| format | Article |
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μm. The macroscopic behavior of the glass was estimated from Vickers hardness measurement. The mechanical properties of all the borosilicate glasses studied were observed to improve, their hardness decreasing with the dose down by 30–35%. This evolution is also associated to an increase of the fracture toughness of the glass under irradiation. Analysis of the structural changes in the sodium borosilicate glass common to all the compositions studied with respect to dose revealed a progressive shift to higher wavenumbers in the vibration Raman band near 495
cm
−1 indicating a drop in the mean Si–O–Si angle. At the same time, modifications in the
Q
n
band between 850 and 1200
cm
−1 are observed and characterize increasing depolymerization of the silicate network.</description><identifier>ISSN: 0022-3093</identifier><identifier>EISSN: 1873-4812</identifier><identifier>DOI: 10.1016/j.jnoncrysol.2009.11.030</identifier><identifier>CODEN: JNCSBJ</identifier><language>eng</language><publisher>Oxford: Elsevier B.V</publisher><subject>Borosilicates ; Condensed Matter ; Condensed matter: structure, mechanical and thermal properties ; Cross-disciplinary physics: materials science; rheology ; Exact sciences and technology ; Glasses (including metallic glasses) ; Hardness ; Indentation ; Ion radiation effects ; Materials Science ; Medium-range order ; Micro-indentation ; Physical radiation effects, radiation damage ; Physics ; Radiation effects ; Raman scattering ; Raman spectroscopy ; Specific materials ; Structure of solids and liquids; crystallography</subject><ispartof>Journal of non-crystalline solids, 2010-03, Vol.356 (6), p.388-393</ispartof><rights>2009 Elsevier B.V.</rights><rights>2015 INIST-CNRS</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c491t-33394a43648df4b6df8b539ab282fff428bcf838b84c8ddf2fca7fea79941bd93</citedby><cites>FETCH-LOGICAL-c491t-33394a43648df4b6df8b539ab282fff428bcf838b84c8ddf2fca7fea79941bd93</cites><orcidid>0000-0001-5708-6376</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.jnoncrysol.2009.11.030$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>230,314,778,782,883,3539,27913,27914,45984</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=22513994$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://in2p3.hal.science/in2p3-00610270$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Bonfils, J. de</creatorcontrib><creatorcontrib>Peuget, S.</creatorcontrib><creatorcontrib>Panczer, G.</creatorcontrib><creatorcontrib>Ligny, D. de</creatorcontrib><creatorcontrib>Henry, S.</creatorcontrib><creatorcontrib>Noël, P.-Y.</creatorcontrib><creatorcontrib>Chenet, A.</creatorcontrib><creatorcontrib>Champagnon, B.</creatorcontrib><title>Effect of chemical composition on borosilicate glass behavior under irradiation</title><title>Journal of non-crystalline solids</title><description>Assessing the behavior under irradiation of oxide glasses used for nuclear waste immobilization is essential for qualifying the long-term behavior of the wasteform. This study focuses on a series of borosilicate glasses of increasing chemical complexity. The effects of irradiation in these materials were investigated through multi-energy external irradiation by gold ions to obtain a constant nuclear damage level to a depth of about 2
μm. The macroscopic behavior of the glass was estimated from Vickers hardness measurement. The mechanical properties of all the borosilicate glasses studied were observed to improve, their hardness decreasing with the dose down by 30–35%. This evolution is also associated to an increase of the fracture toughness of the glass under irradiation. Analysis of the structural changes in the sodium borosilicate glass common to all the compositions studied with respect to dose revealed a progressive shift to higher wavenumbers in the vibration Raman band near 495
cm
−1 indicating a drop in the mean Si–O–Si angle. At the same time, modifications in the
Q
n
band between 850 and 1200
cm
−1 are observed and characterize increasing depolymerization of the silicate network.</description><subject>Borosilicates</subject><subject>Condensed Matter</subject><subject>Condensed matter: structure, mechanical and thermal properties</subject><subject>Cross-disciplinary physics: materials science; rheology</subject><subject>Exact sciences and technology</subject><subject>Glasses (including metallic glasses)</subject><subject>Hardness</subject><subject>Indentation</subject><subject>Ion radiation effects</subject><subject>Materials Science</subject><subject>Medium-range order</subject><subject>Micro-indentation</subject><subject>Physical radiation effects, radiation damage</subject><subject>Physics</subject><subject>Radiation effects</subject><subject>Raman scattering</subject><subject>Raman spectroscopy</subject><subject>Specific materials</subject><subject>Structure of solids and liquids; crystallography</subject><issn>0022-3093</issn><issn>1873-4812</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2010</creationdate><recordtype>article</recordtype><recordid>eNqFkF1LwzAUhoMoOKf_ITdeSWu-1qaXc0wnDHaj1yGfLqVrSlIH-_dmVOalIRAOeZ_knAcAiFGJEa6e27LtQ6_jKYWuJAg1JcYlougKzDCvacE4JtdghhAhBUUNvQV3KbUor5ryGditnbN6hMFBvbcHr2UHdTgMIfnRhx7mrULMVZevRgu_OpkSVHYvjz5E-N0bG6GPURovz8A9uHGyS_bh95yDz9f1x2pTbHdv76vlttCswWNBKW2YZLRi3DimKuO4WtBGKsKJc44RrrTjlCvONDfGEadl7aysm4ZhZRo6B0_Tu3vZiSH6g4wnEaQXm-VW-J4MVCBUYURqdMQ5zae0zqOkaN0FwUicNYpW_GkUZ40CY5E1ZvRxQgeZshwXZa99uvCELDDNTeXcy5Szeeqjt1Ek7W2vrfExCxYm-P8_-wHYCY8w</recordid><startdate>20100301</startdate><enddate>20100301</enddate><creator>Bonfils, J. de</creator><creator>Peuget, S.</creator><creator>Panczer, G.</creator><creator>Ligny, D. de</creator><creator>Henry, S.</creator><creator>Noël, P.-Y.</creator><creator>Chenet, A.</creator><creator>Champagnon, B.</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>1XC</scope><orcidid>https://orcid.org/0000-0001-5708-6376</orcidid></search><sort><creationdate>20100301</creationdate><title>Effect of chemical composition on borosilicate glass behavior under irradiation</title><author>Bonfils, J. de ; Peuget, S. ; Panczer, G. ; Ligny, D. de ; Henry, S. ; Noël, P.-Y. ; Chenet, A. ; Champagnon, B.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c491t-33394a43648df4b6df8b539ab282fff428bcf838b84c8ddf2fca7fea79941bd93</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2010</creationdate><topic>Borosilicates</topic><topic>Condensed Matter</topic><topic>Condensed matter: structure, mechanical and thermal properties</topic><topic>Cross-disciplinary physics: materials science; rheology</topic><topic>Exact sciences and technology</topic><topic>Glasses (including metallic glasses)</topic><topic>Hardness</topic><topic>Indentation</topic><topic>Ion radiation effects</topic><topic>Materials Science</topic><topic>Medium-range order</topic><topic>Micro-indentation</topic><topic>Physical radiation effects, radiation damage</topic><topic>Physics</topic><topic>Radiation effects</topic><topic>Raman scattering</topic><topic>Raman spectroscopy</topic><topic>Specific materials</topic><topic>Structure of solids and liquids; crystallography</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Bonfils, J. de</creatorcontrib><creatorcontrib>Peuget, S.</creatorcontrib><creatorcontrib>Panczer, G.</creatorcontrib><creatorcontrib>Ligny, D. de</creatorcontrib><creatorcontrib>Henry, S.</creatorcontrib><creatorcontrib>Noël, P.-Y.</creatorcontrib><creatorcontrib>Chenet, A.</creatorcontrib><creatorcontrib>Champagnon, B.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Hyper Article en Ligne (HAL)</collection><jtitle>Journal of non-crystalline solids</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Bonfils, J. de</au><au>Peuget, S.</au><au>Panczer, G.</au><au>Ligny, D. de</au><au>Henry, S.</au><au>Noël, P.-Y.</au><au>Chenet, A.</au><au>Champagnon, B.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Effect of chemical composition on borosilicate glass behavior under irradiation</atitle><jtitle>Journal of non-crystalline solids</jtitle><date>2010-03-01</date><risdate>2010</risdate><volume>356</volume><issue>6</issue><spage>388</spage><epage>393</epage><pages>388-393</pages><issn>0022-3093</issn><eissn>1873-4812</eissn><coden>JNCSBJ</coden><abstract>Assessing the behavior under irradiation of oxide glasses used for nuclear waste immobilization is essential for qualifying the long-term behavior of the wasteform. This study focuses on a series of borosilicate glasses of increasing chemical complexity. The effects of irradiation in these materials were investigated through multi-energy external irradiation by gold ions to obtain a constant nuclear damage level to a depth of about 2
μm. The macroscopic behavior of the glass was estimated from Vickers hardness measurement. The mechanical properties of all the borosilicate glasses studied were observed to improve, their hardness decreasing with the dose down by 30–35%. This evolution is also associated to an increase of the fracture toughness of the glass under irradiation. Analysis of the structural changes in the sodium borosilicate glass common to all the compositions studied with respect to dose revealed a progressive shift to higher wavenumbers in the vibration Raman band near 495
cm
−1 indicating a drop in the mean Si–O–Si angle. At the same time, modifications in the
Q
n
band between 850 and 1200
cm
−1 are observed and characterize increasing depolymerization of the silicate network.</abstract><cop>Oxford</cop><pub>Elsevier B.V</pub><doi>10.1016/j.jnoncrysol.2009.11.030</doi><tpages>6</tpages><orcidid>https://orcid.org/0000-0001-5708-6376</orcidid></addata></record> |
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| source | Elsevier ScienceDirect Journals Complete - AutoHoldings |
| subjects | Borosilicates Condensed Matter Condensed matter: structure, mechanical and thermal properties Cross-disciplinary physics: materials science rheology Exact sciences and technology Glasses (including metallic glasses) Hardness Indentation Ion radiation effects Materials Science Medium-range order Micro-indentation Physical radiation effects, radiation damage Physics Radiation effects Raman scattering Raman spectroscopy Specific materials Structure of solids and liquids crystallography |
| title | Effect of chemical composition on borosilicate glass behavior under irradiation |
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