Local distortion energy and coarse-grained elasticity of the twist-bend nematic phase
The recently discovered twist-bend nematic phase of achiral bent-shaped molecules, NTB, has a doubly degenerate ground-state with a periodically modulated heliconical structure and unusual distortion elasticity, the theoretical description of which is still debated. We show that the NTB phase has th...
Gespeichert in:
Veröffentlicht in: | Soft matter 2016-01, Vol.12 (2), p.574-580 |
---|---|
Hauptverfasser: | , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
Online-Zugang: | Volltext |
Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
container_end_page | 580 |
---|---|
container_issue | 2 |
container_start_page | 574 |
container_title | Soft matter |
container_volume | 12 |
creator | Meyer, C Dozov, I |
description | The recently discovered twist-bend nematic phase of achiral bent-shaped molecules, NTB, has a doubly degenerate ground-state with a periodically modulated heliconical structure and unusual distortion elasticity, the theoretical description of which is still debated. We show that the NTB phase has the same macroscopic symmetry as another periodic mesophase, the chiral smectic-A, SmA*. Based on this NTB/SmA* analogy, we develop a coarse-grained elastic model for the NTB phase. Adopting one of the existing microscopic NTB elastic models, we calculate the coarse-grained elastic constants, coherence and penetration lengths in terms of a few Frank-like nematic elastic coefficients that can be measured in macroscopic experiments. The same coarse-grained approach, applied to different local elastic models, may provide an efficient experimental test of their validity. We show that the anisotropy of the NTB coarse-grained elasticity is opposite to that of the SmA*, leading probably to different configurations of some of the defects of the "layered" NTB structure. Moreover, we argue that the intrinsic chiral frustration of the NTB phase may be resolved by penetration of the twist field into the bulk through a network of screw dislocations of the NTB pseudo-layers, resulting in a twist-bend analogue of the twist grain boundary phase TGBA. |
doi_str_mv | 10.1039/c5sm02018b |
format | Article |
fullrecord | <record><control><sourceid>proquest_hal_p</sourceid><recordid>TN_cdi_hal_primary_oai_HAL_hal_04882486v1</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1811893911</sourcerecordid><originalsourceid>FETCH-LOGICAL-c494t-a3ea043da681a84afdfe524cb994092a3bd0276ae078b7434a2d1aa4c891d85c3</originalsourceid><addsrcrecordid>eNqNkU1LxEAMhgdR_Fi9-ANkjipUZzppOz3qoq6w4kEFbyWdSd1K21lnusr-e6ure1UIJCRPXhJexg6lOJNC5ecmCa2IhdTlBtuVGUCUatCb61o977C9EF6FUBpkus124jQRKgO5y56mzmDDbR165_vadZw68i9Ljp3lxqEPFL14rDuynBoMfW3qfsldxfsZ8f5j2ItKGtiOWhyGfD7DQPtsq8Im0MFPHrGn66vH8SSa3t_cji-mkYEc-ggVoQBlMdUSNWBlK0piMGWeg8hjVKUVcZYiiUyXGSjA2EpEMDqXVidGjdjJSneGTTH3dYt-WTisi8nFtPjqCdA6Bp2-y4E9XrFz794WFPqirYOhpsGO3CIUUqskjUEN8Tcqpc5VLv-hmiVy-CYdjBqx0xVqvAvBU7W-WIriy8hinDzcfRt5OcBHP7qLsiW7Rn-dU59QCJc2</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1751994610</pqid></control><display><type>article</type><title>Local distortion energy and coarse-grained elasticity of the twist-bend nematic phase</title><source>Royal Society Of Chemistry Journals 2008-</source><source>Alma/SFX Local Collection</source><creator>Meyer, C ; Dozov, I</creator><creatorcontrib>Meyer, C ; Dozov, I</creatorcontrib><description>The recently discovered twist-bend nematic phase of achiral bent-shaped molecules, NTB, has a doubly degenerate ground-state with a periodically modulated heliconical structure and unusual distortion elasticity, the theoretical description of which is still debated. We show that the NTB phase has the same macroscopic symmetry as another periodic mesophase, the chiral smectic-A, SmA*. Based on this NTB/SmA* analogy, we develop a coarse-grained elastic model for the NTB phase. Adopting one of the existing microscopic NTB elastic models, we calculate the coarse-grained elastic constants, coherence and penetration lengths in terms of a few Frank-like nematic elastic coefficients that can be measured in macroscopic experiments. The same coarse-grained approach, applied to different local elastic models, may provide an efficient experimental test of their validity. We show that the anisotropy of the NTB coarse-grained elasticity is opposite to that of the SmA*, leading probably to different configurations of some of the defects of the "layered" NTB structure. Moreover, we argue that the intrinsic chiral frustration of the NTB phase may be resolved by penetration of the twist field into the bulk through a network of screw dislocations of the NTB pseudo-layers, resulting in a twist-bend analogue of the twist grain boundary phase TGBA.</description><identifier>ISSN: 1744-683X</identifier><identifier>EISSN: 1744-6848</identifier><identifier>DOI: 10.1039/c5sm02018b</identifier><identifier>PMID: 26503741</identifier><language>eng</language><publisher>England: Royal Society of Chemistry</publisher><subject>Coarsening ; Condensed Matter ; Distortion ; Elastic constants ; Elasticity ; Mathematical models ; Nematic ; Penetration ; Physics ; Shape memory alloys ; Soft Condensed Matter</subject><ispartof>Soft matter, 2016-01, Vol.12 (2), p.574-580</ispartof><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c494t-a3ea043da681a84afdfe524cb994092a3bd0276ae078b7434a2d1aa4c891d85c3</citedby><cites>FETCH-LOGICAL-c494t-a3ea043da681a84afdfe524cb994092a3bd0276ae078b7434a2d1aa4c891d85c3</cites><orcidid>0000-0001-8120-9217 ; 0000-0002-9088-7471</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,314,776,780,881,27901,27902</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/26503741$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink><backlink>$$Uhttps://hal.science/hal-04882486$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Meyer, C</creatorcontrib><creatorcontrib>Dozov, I</creatorcontrib><title>Local distortion energy and coarse-grained elasticity of the twist-bend nematic phase</title><title>Soft matter</title><addtitle>Soft Matter</addtitle><description>The recently discovered twist-bend nematic phase of achiral bent-shaped molecules, NTB, has a doubly degenerate ground-state with a periodically modulated heliconical structure and unusual distortion elasticity, the theoretical description of which is still debated. We show that the NTB phase has the same macroscopic symmetry as another periodic mesophase, the chiral smectic-A, SmA*. Based on this NTB/SmA* analogy, we develop a coarse-grained elastic model for the NTB phase. Adopting one of the existing microscopic NTB elastic models, we calculate the coarse-grained elastic constants, coherence and penetration lengths in terms of a few Frank-like nematic elastic coefficients that can be measured in macroscopic experiments. The same coarse-grained approach, applied to different local elastic models, may provide an efficient experimental test of their validity. We show that the anisotropy of the NTB coarse-grained elasticity is opposite to that of the SmA*, leading probably to different configurations of some of the defects of the "layered" NTB structure. Moreover, we argue that the intrinsic chiral frustration of the NTB phase may be resolved by penetration of the twist field into the bulk through a network of screw dislocations of the NTB pseudo-layers, resulting in a twist-bend analogue of the twist grain boundary phase TGBA.</description><subject>Coarsening</subject><subject>Condensed Matter</subject><subject>Distortion</subject><subject>Elastic constants</subject><subject>Elasticity</subject><subject>Mathematical models</subject><subject>Nematic</subject><subject>Penetration</subject><subject>Physics</subject><subject>Shape memory alloys</subject><subject>Soft Condensed Matter</subject><issn>1744-683X</issn><issn>1744-6848</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNqNkU1LxEAMhgdR_Fi9-ANkjipUZzppOz3qoq6w4kEFbyWdSd1K21lnusr-e6ure1UIJCRPXhJexg6lOJNC5ecmCa2IhdTlBtuVGUCUatCb61o977C9EF6FUBpkus124jQRKgO5y56mzmDDbR165_vadZw68i9Ljp3lxqEPFL14rDuynBoMfW3qfsldxfsZ8f5j2ItKGtiOWhyGfD7DQPtsq8Im0MFPHrGn66vH8SSa3t_cji-mkYEc-ggVoQBlMdUSNWBlK0piMGWeg8hjVKUVcZYiiUyXGSjA2EpEMDqXVidGjdjJSneGTTH3dYt-WTisi8nFtPjqCdA6Bp2-y4E9XrFz794WFPqirYOhpsGO3CIUUqskjUEN8Tcqpc5VLv-hmiVy-CYdjBqx0xVqvAvBU7W-WIriy8hinDzcfRt5OcBHP7qLsiW7Rn-dU59QCJc2</recordid><startdate>20160101</startdate><enddate>20160101</enddate><creator>Meyer, C</creator><creator>Dozov, I</creator><general>Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>7QO</scope><scope>8FD</scope><scope>FR3</scope><scope>P64</scope><scope>7U5</scope><scope>L7M</scope><scope>1XC</scope><orcidid>https://orcid.org/0000-0001-8120-9217</orcidid><orcidid>https://orcid.org/0000-0002-9088-7471</orcidid></search><sort><creationdate>20160101</creationdate><title>Local distortion energy and coarse-grained elasticity of the twist-bend nematic phase</title><author>Meyer, C ; Dozov, I</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c494t-a3ea043da681a84afdfe524cb994092a3bd0276ae078b7434a2d1aa4c891d85c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Coarsening</topic><topic>Condensed Matter</topic><topic>Distortion</topic><topic>Elastic constants</topic><topic>Elasticity</topic><topic>Mathematical models</topic><topic>Nematic</topic><topic>Penetration</topic><topic>Physics</topic><topic>Shape memory alloys</topic><topic>Soft Condensed Matter</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Meyer, C</creatorcontrib><creatorcontrib>Dozov, I</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>Biotechnology Research Abstracts</collection><collection>Technology Research Database</collection><collection>Engineering Research Database</collection><collection>Biotechnology and BioEngineering Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Hyper Article en Ligne (HAL)</collection><jtitle>Soft matter</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Meyer, C</au><au>Dozov, I</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Local distortion energy and coarse-grained elasticity of the twist-bend nematic phase</atitle><jtitle>Soft matter</jtitle><addtitle>Soft Matter</addtitle><date>2016-01-01</date><risdate>2016</risdate><volume>12</volume><issue>2</issue><spage>574</spage><epage>580</epage><pages>574-580</pages><issn>1744-683X</issn><eissn>1744-6848</eissn><abstract>The recently discovered twist-bend nematic phase of achiral bent-shaped molecules, NTB, has a doubly degenerate ground-state with a periodically modulated heliconical structure and unusual distortion elasticity, the theoretical description of which is still debated. We show that the NTB phase has the same macroscopic symmetry as another periodic mesophase, the chiral smectic-A, SmA*. Based on this NTB/SmA* analogy, we develop a coarse-grained elastic model for the NTB phase. Adopting one of the existing microscopic NTB elastic models, we calculate the coarse-grained elastic constants, coherence and penetration lengths in terms of a few Frank-like nematic elastic coefficients that can be measured in macroscopic experiments. The same coarse-grained approach, applied to different local elastic models, may provide an efficient experimental test of their validity. We show that the anisotropy of the NTB coarse-grained elasticity is opposite to that of the SmA*, leading probably to different configurations of some of the defects of the "layered" NTB structure. Moreover, we argue that the intrinsic chiral frustration of the NTB phase may be resolved by penetration of the twist field into the bulk through a network of screw dislocations of the NTB pseudo-layers, resulting in a twist-bend analogue of the twist grain boundary phase TGBA.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>26503741</pmid><doi>10.1039/c5sm02018b</doi><tpages>7</tpages><orcidid>https://orcid.org/0000-0001-8120-9217</orcidid><orcidid>https://orcid.org/0000-0002-9088-7471</orcidid></addata></record> |
fulltext | fulltext |
identifier | ISSN: 1744-683X |
ispartof | Soft matter, 2016-01, Vol.12 (2), p.574-580 |
issn | 1744-683X 1744-6848 |
language | eng |
recordid | cdi_hal_primary_oai_HAL_hal_04882486v1 |
source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
subjects | Coarsening Condensed Matter Distortion Elastic constants Elasticity Mathematical models Nematic Penetration Physics Shape memory alloys Soft Condensed Matter |
title | Local distortion energy and coarse-grained elasticity of the twist-bend nematic phase |
url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-08T03%3A56%3A25IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_hal_p&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Local%20distortion%20energy%20and%20coarse-grained%20elasticity%20of%20the%20twist-bend%20nematic%20phase&rft.jtitle=Soft%20matter&rft.au=Meyer,%20C&rft.date=2016-01-01&rft.volume=12&rft.issue=2&rft.spage=574&rft.epage=580&rft.pages=574-580&rft.issn=1744-683X&rft.eissn=1744-6848&rft_id=info:doi/10.1039/c5sm02018b&rft_dat=%3Cproquest_hal_p%3E1811893911%3C/proquest_hal_p%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1751994610&rft_id=info:pmid/26503741&rfr_iscdi=true |