Valence-tautomerism in high-valent iron and manganese porphyrins

Iron and manganese hemes are "high-valent" when the valence state of the metal exceeds III. Redox chemistry of the high valent metal complexes involves redistribution of holes and electrons over the metal ion and the porphyrin and axial ligands, defined as valence tautomerism. Thus, cataly...

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Veröffentlicht in:	Journal of biological inorganic chemistry 2001-10, Vol.6 (8), p.831-845
Hauptverfasser:	Weiss, R, Bulach, V, Gold, A, Terner, J, Trautwein, A X
Format:	Artikel
Sprache:	eng
Schlagworte:	Catalase - chemistry Chemical Sciences Cytochrome P-450 Enzyme System - chemistry Iron - chemistry Manganese - chemistry Metalloporphyrins - chemistry Oxidation-Reduction Peroxidases - chemistry
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