Antigorite crystallization during oceanic retrograde serpentinization of abyssal peridotites
We report on the presence of the serpentine-type antigorite in abyssal-serpentinized peridotite. At mid-ocean spreading ridges, antigorite crystallizes under retrograde metamorphic conditions during tectonic exhumation of the newly formed oceanic lithosphere. Using optical microscopy and micro-Raman...
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description | We report on the presence of the serpentine-type antigorite in abyssal-serpentinized peridotite. At mid-ocean spreading ridges, antigorite crystallizes under retrograde metamorphic conditions during tectonic exhumation of the newly formed oceanic lithosphere. Using optical microscopy and micro-Raman spectroscopy, we identified antigorite in 49 samples drilled at the Hess Deep (East Pacific Rise) and the Atlantis Massif (Mid-Atlantic Ridge, 30°N), and dredged along the Southwest Indian Ridge (62°–65°E). Overall, antigorite is common, but occurs in limited modal amounts. SEM and TEM investigations reveal its frequent crystallization after lizardite and chrysotile via dissolution–recrystallization processes and a local association with olivine or talc. We explain antigorite crystallization by the interaction with seawater-derived hydrothermal fluids moderately enriched in silica (metasomatism). The origin of silica is attributed to alteration of mafic intrusions or pyroxenes. Antigorite can, therefore, be considered a marker of preferential fluid pathways under rock-dominated conditions during exhumation of a portion of the oceanic lithosphere. We also measured the in-situ major and trace-element composition of antigorite and the predating and postdating phases. Most of the elements are immobile during the mineralogical transitions. Other elements (Ni, Ca, Al, and Ti) evolve within the serpentine textures, including antigorite, as a result of chemical exchanges accompanying the development of the sequence of serpentine textures. A further category includes elements that are specifically enriched (Mn, Sn) or depleted (Fluid-Mobile Elements: B, Sr, As, U, Sb, and Cl) in antigorite compared to lizardite and chrysotile. These enrichments and depletions possibly reflect a change of the fluid physicochemical characteristics allowing a change in element mobility during the dissolution–recrystallization accommodating the lizardite/chrysotile-to-antigorite transition. Such depletion in FME is comparable to depletions described in studies of serpentinization and antigorite formation in subduction zone setting, which suggests that the origin of antigorite in some subducted samples could be reevaluated. |
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At mid-ocean spreading ridges, antigorite crystallizes under retrograde metamorphic conditions during tectonic exhumation of the newly formed oceanic lithosphere. Using optical microscopy and micro-Raman spectroscopy, we identified antigorite in 49 samples drilled at the Hess Deep (East Pacific Rise) and the Atlantis Massif (Mid-Atlantic Ridge, 30°N), and dredged along the Southwest Indian Ridge (62°–65°E). Overall, antigorite is common, but occurs in limited modal amounts. SEM and TEM investigations reveal its frequent crystallization after lizardite and chrysotile via dissolution–recrystallization processes and a local association with olivine or talc. We explain antigorite crystallization by the interaction with seawater-derived hydrothermal fluids moderately enriched in silica (metasomatism). The origin of silica is attributed to alteration of mafic intrusions or pyroxenes. Antigorite can, therefore, be considered a marker of preferential fluid pathways under rock-dominated conditions during exhumation of a portion of the oceanic lithosphere. We also measured the in-situ major and trace-element composition of antigorite and the predating and postdating phases. Most of the elements are immobile during the mineralogical transitions. Other elements (Ni, Ca, Al, and Ti) evolve within the serpentine textures, including antigorite, as a result of chemical exchanges accompanying the development of the sequence of serpentine textures. A further category includes elements that are specifically enriched (Mn, Sn) or depleted (Fluid-Mobile Elements: B, Sr, As, U, Sb, and Cl) in antigorite compared to lizardite and chrysotile. These enrichments and depletions possibly reflect a change of the fluid physicochemical characteristics allowing a change in element mobility during the dissolution–recrystallization accommodating the lizardite/chrysotile-to-antigorite transition. Such depletion in FME is comparable to depletions described in studies of serpentinization and antigorite formation in subduction zone setting, which suggests that the origin of antigorite in some subducted samples could be reevaluated.</description><identifier>ISSN: 0010-7999</identifier><identifier>EISSN: 1432-0967</identifier><identifier>DOI: 10.1007/s00410-019-1595-1</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Aluminum ; Analytical methods ; Antimony ; Chemical analysis ; Chrysotile ; Crystallization ; Depletion ; Dissolution ; Dissolving ; Dredging ; Earth and Environmental Science ; Earth Sciences ; Enrichment ; Environmental Sciences ; Fluids ; Geology ; Hydrothermal fluids ; Light microscopy ; Lithosphere ; Magma ; Manganese ; Massifs ; Mid-ocean ridges ; Mineral Resources ; Mineralogy ; Nickel ; Olivine ; Optical microscopy ; Organic chemistry ; Original Paper ; Peridotite ; Petrology ; Raman spectroscopy ; Recrystallization ; Ridges ; Sea-water ; Seawater ; Serpentine ; Serpentinite ; Serpentinization ; Silica ; Silicon dioxide ; Spreading centres ; Subduction ; Subduction (geology) ; Subduction zones ; Talc ; Tectonics ; Tin ; Trace elements ; Water analysis</subject><ispartof>Contributions to mineralogy and petrology, 2019-07, Vol.174 (7), p.1-25, Article 60</ispartof><rights>Springer-Verlag GmbH Germany, part of Springer Nature 2019</rights><rights>COPYRIGHT 2019 Springer</rights><rights>Contributions to Mineralogy and Petrology is a copyright of Springer, (2019). All Rights Reserved.</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a544t-94408908a6d82ca4c8ab27273bbad59430b559bfe7a74dc805b0431db984e4d43</citedby><cites>FETCH-LOGICAL-a544t-94408908a6d82ca4c8ab27273bbad59430b559bfe7a74dc805b0431db984e4d43</cites><orcidid>0000-0002-1847-6790 ; 0000-0001-8043-0905</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s00410-019-1595-1$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s00410-019-1595-1$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>230,314,780,784,885,27922,27923,41486,42555,51317</link.rule.ids><backlink>$$Uhttps://hal.science/hal-04828885$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Rouméjon, Stéphane</creatorcontrib><creatorcontrib>Andreani, Muriel</creatorcontrib><creatorcontrib>Früh-Green, Gretchen L.</creatorcontrib><title>Antigorite crystallization during oceanic retrograde serpentinization of abyssal peridotites</title><title>Contributions to mineralogy and petrology</title><addtitle>Contrib Mineral Petrol</addtitle><description>We report on the presence of the serpentine-type antigorite in abyssal-serpentinized peridotite. At mid-ocean spreading ridges, antigorite crystallizes under retrograde metamorphic conditions during tectonic exhumation of the newly formed oceanic lithosphere. Using optical microscopy and micro-Raman spectroscopy, we identified antigorite in 49 samples drilled at the Hess Deep (East Pacific Rise) and the Atlantis Massif (Mid-Atlantic Ridge, 30°N), and dredged along the Southwest Indian Ridge (62°–65°E). Overall, antigorite is common, but occurs in limited modal amounts. SEM and TEM investigations reveal its frequent crystallization after lizardite and chrysotile via dissolution–recrystallization processes and a local association with olivine or talc. We explain antigorite crystallization by the interaction with seawater-derived hydrothermal fluids moderately enriched in silica (metasomatism). The origin of silica is attributed to alteration of mafic intrusions or pyroxenes. Antigorite can, therefore, be considered a marker of preferential fluid pathways under rock-dominated conditions during exhumation of a portion of the oceanic lithosphere. We also measured the in-situ major and trace-element composition of antigorite and the predating and postdating phases. Most of the elements are immobile during the mineralogical transitions. Other elements (Ni, Ca, Al, and Ti) evolve within the serpentine textures, including antigorite, as a result of chemical exchanges accompanying the development of the sequence of serpentine textures. A further category includes elements that are specifically enriched (Mn, Sn) or depleted (Fluid-Mobile Elements: B, Sr, As, U, Sb, and Cl) in antigorite compared to lizardite and chrysotile. These enrichments and depletions possibly reflect a change of the fluid physicochemical characteristics allowing a change in element mobility during the dissolution–recrystallization accommodating the lizardite/chrysotile-to-antigorite transition. Such depletion in FME is comparable to depletions described in studies of serpentinization and antigorite formation in subduction zone setting, which suggests that the origin of antigorite in some subducted samples could be reevaluated.</description><subject>Aluminum</subject><subject>Analytical methods</subject><subject>Antimony</subject><subject>Chemical analysis</subject><subject>Chrysotile</subject><subject>Crystallization</subject><subject>Depletion</subject><subject>Dissolution</subject><subject>Dissolving</subject><subject>Dredging</subject><subject>Earth and Environmental Science</subject><subject>Earth Sciences</subject><subject>Enrichment</subject><subject>Environmental Sciences</subject><subject>Fluids</subject><subject>Geology</subject><subject>Hydrothermal fluids</subject><subject>Light microscopy</subject><subject>Lithosphere</subject><subject>Magma</subject><subject>Manganese</subject><subject>Massifs</subject><subject>Mid-ocean ridges</subject><subject>Mineral Resources</subject><subject>Mineralogy</subject><subject>Nickel</subject><subject>Olivine</subject><subject>Optical microscopy</subject><subject>Organic chemistry</subject><subject>Original Paper</subject><subject>Peridotite</subject><subject>Petrology</subject><subject>Raman spectroscopy</subject><subject>Recrystallization</subject><subject>Ridges</subject><subject>Sea-water</subject><subject>Seawater</subject><subject>Serpentine</subject><subject>Serpentinite</subject><subject>Serpentinization</subject><subject>Silica</subject><subject>Silicon dioxide</subject><subject>Spreading centres</subject><subject>Subduction</subject><subject>Subduction (geology)</subject><subject>Subduction zones</subject><subject>Talc</subject><subject>Tectonics</subject><subject>Tin</subject><subject>Trace elements</subject><subject>Water 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crystallization during oceanic retrograde serpentinization of abyssal peridotites</title><author>Rouméjon, Stéphane ; Andreani, Muriel ; Früh-Green, Gretchen L.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a544t-94408908a6d82ca4c8ab27273bbad59430b559bfe7a74dc805b0431db984e4d43</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Aluminum</topic><topic>Analytical methods</topic><topic>Antimony</topic><topic>Chemical analysis</topic><topic>Chrysotile</topic><topic>Crystallization</topic><topic>Depletion</topic><topic>Dissolution</topic><topic>Dissolving</topic><topic>Dredging</topic><topic>Earth and Environmental Science</topic><topic>Earth Sciences</topic><topic>Enrichment</topic><topic>Environmental Sciences</topic><topic>Fluids</topic><topic>Geology</topic><topic>Hydrothermal fluids</topic><topic>Light microscopy</topic><topic>Lithosphere</topic><topic>Magma</topic><topic>Manganese</topic><topic>Massifs</topic><topic>Mid-ocean ridges</topic><topic>Mineral Resources</topic><topic>Mineralogy</topic><topic>Nickel</topic><topic>Olivine</topic><topic>Optical microscopy</topic><topic>Organic chemistry</topic><topic>Original Paper</topic><topic>Peridotite</topic><topic>Petrology</topic><topic>Raman spectroscopy</topic><topic>Recrystallization</topic><topic>Ridges</topic><topic>Sea-water</topic><topic>Seawater</topic><topic>Serpentine</topic><topic>Serpentinite</topic><topic>Serpentinization</topic><topic>Silica</topic><topic>Silicon dioxide</topic><topic>Spreading centres</topic><topic>Subduction</topic><topic>Subduction (geology)</topic><topic>Subduction zones</topic><topic>Talc</topic><topic>Tectonics</topic><topic>Tin</topic><topic>Trace elements</topic><topic>Water analysis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Rouméjon, 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(Corporate)</collection><collection>Earth, Atmospheric & Aquatic Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>Engineering Collection</collection><collection>ProQuest Central Basic</collection><collection>University of Michigan</collection><collection>Hyper Article en Ligne (HAL)</collection><jtitle>Contributions to mineralogy and petrology</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Rouméjon, Stéphane</au><au>Andreani, Muriel</au><au>Früh-Green, Gretchen L.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Antigorite crystallization during oceanic retrograde serpentinization of abyssal peridotites</atitle><jtitle>Contributions to mineralogy and petrology</jtitle><stitle>Contrib Mineral Petrol</stitle><date>2019-07-01</date><risdate>2019</risdate><volume>174</volume><issue>7</issue><spage>1</spage><epage>25</epage><pages>1-25</pages><artnum>60</artnum><issn>0010-7999</issn><eissn>1432-0967</eissn><abstract>We report on the presence of the serpentine-type antigorite in abyssal-serpentinized peridotite. At mid-ocean spreading ridges, antigorite crystallizes under retrograde metamorphic conditions during tectonic exhumation of the newly formed oceanic lithosphere. Using optical microscopy and micro-Raman spectroscopy, we identified antigorite in 49 samples drilled at the Hess Deep (East Pacific Rise) and the Atlantis Massif (Mid-Atlantic Ridge, 30°N), and dredged along the Southwest Indian Ridge (62°–65°E). Overall, antigorite is common, but occurs in limited modal amounts. SEM and TEM investigations reveal its frequent crystallization after lizardite and chrysotile via dissolution–recrystallization processes and a local association with olivine or talc. We explain antigorite crystallization by the interaction with seawater-derived hydrothermal fluids moderately enriched in silica (metasomatism). The origin of silica is attributed to alteration of mafic intrusions or pyroxenes. Antigorite can, therefore, be considered a marker of preferential fluid pathways under rock-dominated conditions during exhumation of a portion of the oceanic lithosphere. We also measured the in-situ major and trace-element composition of antigorite and the predating and postdating phases. Most of the elements are immobile during the mineralogical transitions. Other elements (Ni, Ca, Al, and Ti) evolve within the serpentine textures, including antigorite, as a result of chemical exchanges accompanying the development of the sequence of serpentine textures. A further category includes elements that are specifically enriched (Mn, Sn) or depleted (Fluid-Mobile Elements: B, Sr, As, U, Sb, and Cl) in antigorite compared to lizardite and chrysotile. These enrichments and depletions possibly reflect a change of the fluid physicochemical characteristics allowing a change in element mobility during the dissolution–recrystallization accommodating the lizardite/chrysotile-to-antigorite transition. Such depletion in FME is comparable to depletions described in studies of serpentinization and antigorite formation in subduction zone setting, which suggests that the origin of antigorite in some subducted samples could be reevaluated.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s00410-019-1595-1</doi><tpages>25</tpages><orcidid>https://orcid.org/0000-0002-1847-6790</orcidid><orcidid>https://orcid.org/0000-0001-8043-0905</orcidid></addata></record> |
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subjects | Aluminum Analytical methods Antimony Chemical analysis Chrysotile Crystallization Depletion Dissolution Dissolving Dredging Earth and Environmental Science Earth Sciences Enrichment Environmental Sciences Fluids Geology Hydrothermal fluids Light microscopy Lithosphere Magma Manganese Massifs Mid-ocean ridges Mineral Resources Mineralogy Nickel Olivine Optical microscopy Organic chemistry Original Paper Peridotite Petrology Raman spectroscopy Recrystallization Ridges Sea-water Seawater Serpentine Serpentinite Serpentinization Silica Silicon dioxide Spreading centres Subduction Subduction (geology) Subduction zones Talc Tectonics Tin Trace elements Water analysis |
title | Antigorite crystallization during oceanic retrograde serpentinization of abyssal peridotites |
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