Solvent dependent hierarchical dual helicity in a fused [4]carbohelicene/quinoline oligoamide foldamer

Two classes of helical motif, namely a [4]carbohelicene and an aromatic oligoamide foldamer, were fused to form a hybrid molecular construct in which their helical axes are parallel. Depending on the solvent, the [4]carbohelicene can bias the dynamic screw sense of the aromatic oligoamide with a rev...

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Veröffentlicht in:Organic Chemistry Frontiers 2024-04, Vol.11 (9), p.2632-2637
Hauptverfasser: Borges-Anastácio, Rita, Moreno, Kevin, Merlet, Eric, Buffeteau, Thierry, Kauffmann, Brice, McClenaghan, Nathan, Ferrand, Yann, Olivier, Céline
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container_end_page 2637
container_issue 9
container_start_page 2632
container_title Organic Chemistry Frontiers
container_volume 11
creator Borges-Anastácio, Rita
Moreno, Kevin
Merlet, Eric
Buffeteau, Thierry
Kauffmann, Brice
McClenaghan, Nathan
Ferrand, Yann
Olivier, Céline
description Two classes of helical motif, namely a [4]carbohelicene and an aromatic oligoamide foldamer, were fused to form a hybrid molecular construct in which their helical axes are parallel. Depending on the solvent, the [4]carbohelicene can bias the dynamic screw sense of the aromatic oligoamide with a reverse handedness.
doi_str_mv 10.1039/D4QO00320A
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language eng
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source Royal Society of Chemistry E-Journals
subjects Aromatic compounds
Chemical Sciences
Handedness
Helicity
Quinoline
Solvents
title Solvent dependent hierarchical dual helicity in a fused [4]carbohelicene/quinoline oligoamide foldamer
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