Reductive hydrothermal conversion of uranyl oxalates into UO$_{2+x}$ monitored by in situ XANES analyses

Hydrothermal conversion of actinide oxalates has recently gained attraction as an innovative fabrication route for nuclear fuels but remained mainly limited to tetra-of tri-valent cations. We report herein the reductive conversion of mixtures of uranyl and oxalates ions into UO$_{2+x}$ oxides under...

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2024, Vol.53, p.13982-13995
Hauptverfasser: Benarib, Sofian, Munoz, Maëva, Kieffer, Isabelle, Hazemann, Jean-Louis F, Dacheux, Nicolas, Clavier, Nicolas
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Sprache:eng
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