Thermally and Photoinduced Spin-Crossover Behavior in Iron(II)–Silver(I) Cyanido-Bridged Coordination Polymers Bearing Acetylpyridine Ligands

We report two new cyanido-bridged Fe­(II)–Ag­(I) coordination polymers using different acetylpyridine isomers, {Fe­(4acpy)2[Ag­(CN)2]2} 1 and {Fe­(3acpy)­[Ag­(CN)2]2} 2 (4acpy = 4-acetylpyridine; 3acpy = 3-acetylpyridine) displaying thermally and photoinduced spin crossover (SCO). In both cases, the...

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Veröffentlicht in:	Inorganic chemistry 2024-08, Vol.63 (38), p.17561-17573
Hauptverfasser:	Cruz, Carlos, Galdames, Jorge, Camayo-Gutierrez, Liz, Rouzières, Mathieu, Mathonière, Corine, Menéndez, Nieves, Audebrand, Nathalie, Reyes-Lillo, Sebastian E., Clérac, Rodolphe, Venegas-Yazigi, Diego, Paredes-García, Verónica
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemical Sciences Coordination chemistry Cristallography or physical chemistry Polymers Theoretical and
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