$Interactions between alkali cations and cyanide-bridged network in A$_2$Co$_2$[Fe(CN)$_6$]$_{3.3}$ Prussian blue analogues revealed by far-infrared spectroscopy$

Interactions between alkali cations and cyanide-bridged network in A$_2$Co$_2$[Fe(CN)$_6$]$_{3.3}$ Prussian blue analogues revealed by far-infrared spectroscopy

A series of Prussian Blue Analogues (PBAs) having the chemical formula A$_2$Co$_2$[Fe(CN)$_6$]$_{3.3}$.nH$_2$O (A+ = Na+, Rb+ and Cs+) was investigated by variable temperature far-infrared spectroscopy. Despite the same chemical composition of the cyanide-bridged CoFe network, the three compounds ar...

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Veröffentlicht in:	Materials advances 2024, Vol.5 (9), p.3794-3801
Hauptverfasser:	Dronova, Maria, Altenschmidt, Laura, Bordage, Amélie, Brubach, Jean-Blaise, Verseils, Marine, Balthazar, Gregory, Roy, Pascale, Bleuzen, Anne
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemical Sciences Inorganic chemistry Material chemistry
Online-Zugang:	Volltext
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