Copper-catalyzed silylation of activated alkenes by photoinduced ligand-to-metal charge transfer

A CuCl$_2$-mediated hydrosilylation of activated olefins with hydrosilanes under visible-light irradiation is reported. The photoactive CuCl$_2$ undergoes a ligand to metal charge transfer, generating a chlorine radical, which abstracts an hydrogen from the hydrosilane, forming a silyl radical, whic...

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Veröffentlicht in:	ARKIVOC free online journal of organic chemistry 2024-01, Vol.2024 (2)
Hauptverfasser:	Liu, Shuai, Robert, Frédéric, Landais, Yannick
Format:	Artikel
Sprache:	eng
Schlagworte:	Catalysis Chemical Sciences Organic chemistry
Online-Zugang:	Volltext
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