Interplay of conductivity, magnetism (and nonlinear optics) in organic-inorganic compounds
The preparation and characterization of organic-inorganic molecule-based systems in which conduction electrons coexist with localized moments is reported. These systems comprise (i) charge transfer salts of organic donors, such as BETS (bis(ethylenedithio)tetraselena-fulvalene), and paramagnetic ino...
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| Veröffentlicht in: | Synthetic metals 1997-02, Vol.86 (1), p.1785-1788, Article 1785 |
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| creator | Brossard, L. Cassoux, P. Dyachenko, O. Faulmann, C. Graja, A. Kobayashi, H. Kobayashi, A. Kushch, N. Lacroix, P.G. Legros, J.-P. Malfant, I. Pokhodnia, K. Tokumoto, M. |
| description | The preparation and characterization of organic-inorganic molecule-based systems in which conduction electrons coexist with localized moments is reported. These systems comprise (i) charge transfer salts of organic donors, such as BETS (bis(ethylenedithio)tetraselena-fulvalene), and paramagnetic inorganic anions, such as [MX
4]
−, [M
2X
6]
2− with M = Fe, Cu, etc., and X = Cl, Br, etc., or (ii) charge transfer salts of inorganic acceptor bisdithiolato metal complexes, such as M(dmit)
2 (dmit
2− = 2-thioxo-1,3-dithiole-4,5-dithiolato), and paramagnetic organometallic cations, such as [MCp
2]
n+ (Cp = cyclopentadienyl-like ligands). In some favorable cases, such as λ-(BETS)
2(FeCl
4), new experimental evidence for interaction between the conduction electrons (of BETS) and magnetic moments (localized on [FeCl
4) is discussed. Current research towards the coupling of electrical and nonlinear optical properties in molecule-based compounds is reported. Additional evidence for the oxidation-induced symmetry breakdown in [bis-TTF]
+ radical cations is given. |
| doi_str_mv | 10.1016/S0379-6779(96)04589-4 |
| format | Article |
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4]
−, [M
2X
6]
2− with M = Fe, Cu, etc., and X = Cl, Br, etc., or (ii) charge transfer salts of inorganic acceptor bisdithiolato metal complexes, such as M(dmit)
2 (dmit
2− = 2-thioxo-1,3-dithiole-4,5-dithiolato), and paramagnetic organometallic cations, such as [MCp
2]
n+ (Cp = cyclopentadienyl-like ligands). In some favorable cases, such as λ-(BETS)
2(FeCl
4), new experimental evidence for interaction between the conduction electrons (of BETS) and magnetic moments (localized on [FeCl
4) is discussed. Current research towards the coupling of electrical and nonlinear optical properties in molecule-based compounds is reported. Additional evidence for the oxidation-induced symmetry breakdown in [bis-TTF]
+ radical cations is given.</description><identifier>ISSN: 0379-6779</identifier><identifier>EISSN: 1879-3290</identifier><identifier>DOI: 10.1016/S0379-6779(96)04589-4</identifier><language>eng</language><publisher>Elsevier B.V</publisher><subject>Chemical Sciences ; electrocrystallization ; electron spin resonance ; magnetic measurements ; or physical chemistry ; organic conductors based on radical cation and/or anion salts ; Organic superconductors ; Theoretical and ; X-ray diffraction</subject><ispartof>Synthetic metals, 1997-02, Vol.86 (1), p.1785-1788, Article 1785</ispartof><rights>1997</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c409t-60bbf132d8f0be454e5f84c5c408b9010f9d741b8db97909afd09b170d5fab983</citedby><cites>FETCH-LOGICAL-c409t-60bbf132d8f0be454e5f84c5c408b9010f9d741b8db97909afd09b170d5fab983</cites><orcidid>0000-0002-5676-6924 ; 0000-0002-1185-2124</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/S0379-6779(96)04589-4$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>230,314,780,784,885,3550,27924,27925,45995</link.rule.ids><backlink>$$Uhttps://hal.science/hal-04663755$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Brossard, L.</creatorcontrib><creatorcontrib>Cassoux, P.</creatorcontrib><creatorcontrib>Dyachenko, O.</creatorcontrib><creatorcontrib>Faulmann, C.</creatorcontrib><creatorcontrib>Graja, A.</creatorcontrib><creatorcontrib>Kobayashi, H.</creatorcontrib><creatorcontrib>Kobayashi, A.</creatorcontrib><creatorcontrib>Kushch, N.</creatorcontrib><creatorcontrib>Lacroix, P.G.</creatorcontrib><creatorcontrib>Legros, J.-P.</creatorcontrib><creatorcontrib>Malfant, I.</creatorcontrib><creatorcontrib>Pokhodnia, K.</creatorcontrib><creatorcontrib>Tokumoto, M.</creatorcontrib><title>Interplay of conductivity, magnetism (and nonlinear optics) in organic-inorganic compounds</title><title>Synthetic metals</title><description>The preparation and characterization of organic-inorganic molecule-based systems in which conduction electrons coexist with localized moments is reported. These systems comprise (i) charge transfer salts of organic donors, such as BETS (bis(ethylenedithio)tetraselena-fulvalene), and paramagnetic inorganic anions, such as [MX
4]
−, [M
2X
6]
2− with M = Fe, Cu, etc., and X = Cl, Br, etc., or (ii) charge transfer salts of inorganic acceptor bisdithiolato metal complexes, such as M(dmit)
2 (dmit
2− = 2-thioxo-1,3-dithiole-4,5-dithiolato), and paramagnetic organometallic cations, such as [MCp
2]
n+ (Cp = cyclopentadienyl-like ligands). In some favorable cases, such as λ-(BETS)
2(FeCl
4), new experimental evidence for interaction between the conduction electrons (of BETS) and magnetic moments (localized on [FeCl
4) is discussed. Current research towards the coupling of electrical and nonlinear optical properties in molecule-based compounds is reported. Additional evidence for the oxidation-induced symmetry breakdown in [bis-TTF]
+ radical cations is given.</description><subject>Chemical Sciences</subject><subject>electrocrystallization</subject><subject>electron spin resonance</subject><subject>magnetic measurements</subject><subject>or physical chemistry</subject><subject>organic conductors based on radical cation and/or anion salts</subject><subject>Organic superconductors</subject><subject>Theoretical and</subject><subject>X-ray diffraction</subject><issn>0379-6779</issn><issn>1879-3290</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1997</creationdate><recordtype>article</recordtype><recordid>eNqFkMtKBDEQRYMoOD4-QeilA7ZWppPuDi5EBl8w4ELduAnpPLSkJxmSODB_b88DF25cVVF1z10cQs4oXFKg9dULVI0o66YR56IeA-OtKNkeGdF2OFcTAftk9Bs5JEcpfQEAFRM-Iu9PPtu46NWqCK7QwZtvnXGJeXVRzNWHtxnTvDhX3hQ--B69VbEIi4w6jQv0RYgfyqMu0e-2oWO-CN_epBNy4FSf7OluHpO3-7vX6WM5e354mt7OSs1A5LKGrnO0mpjWQWcZZ5a7lmk-fNtOAAUnTMNo15pONAKEcgZERxsw3KlOtNUxGW97P1UvFxHnKq5kUCgfb2dyfQNW11XD-ZIOWb7N6hhSitb9AhTkWqbcyJRrU1LUciNTsoG7_sNpzCpj8Dkq7P-lb7a0HTQs0UaZNFqvrcFodZYm4D8NP-9Cj8g</recordid><startdate>19970228</startdate><enddate>19970228</enddate><creator>Brossard, L.</creator><creator>Cassoux, P.</creator><creator>Dyachenko, O.</creator><creator>Faulmann, C.</creator><creator>Graja, A.</creator><creator>Kobayashi, H.</creator><creator>Kobayashi, A.</creator><creator>Kushch, N.</creator><creator>Lacroix, P.G.</creator><creator>Legros, J.-P.</creator><creator>Malfant, I.</creator><creator>Pokhodnia, K.</creator><creator>Tokumoto, M.</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>AAYXX</scope><scope>CITATION</scope><scope>1XC</scope><orcidid>https://orcid.org/0000-0002-5676-6924</orcidid><orcidid>https://orcid.org/0000-0002-1185-2124</orcidid></search><sort><creationdate>19970228</creationdate><title>Interplay of conductivity, magnetism (and nonlinear optics) in organic-inorganic compounds</title><author>Brossard, L. ; Cassoux, P. ; Dyachenko, O. ; Faulmann, C. ; Graja, A. ; Kobayashi, H. ; Kobayashi, A. ; Kushch, N. ; Lacroix, P.G. ; Legros, J.-P. ; Malfant, I. ; Pokhodnia, K. ; Tokumoto, M.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c409t-60bbf132d8f0be454e5f84c5c408b9010f9d741b8db97909afd09b170d5fab983</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1997</creationdate><topic>Chemical Sciences</topic><topic>electrocrystallization</topic><topic>electron spin resonance</topic><topic>magnetic measurements</topic><topic>or physical chemistry</topic><topic>organic conductors based on radical cation and/or anion salts</topic><topic>Organic superconductors</topic><topic>Theoretical and</topic><topic>X-ray diffraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Brossard, L.</creatorcontrib><creatorcontrib>Cassoux, P.</creatorcontrib><creatorcontrib>Dyachenko, O.</creatorcontrib><creatorcontrib>Faulmann, C.</creatorcontrib><creatorcontrib>Graja, A.</creatorcontrib><creatorcontrib>Kobayashi, H.</creatorcontrib><creatorcontrib>Kobayashi, A.</creatorcontrib><creatorcontrib>Kushch, N.</creatorcontrib><creatorcontrib>Lacroix, P.G.</creatorcontrib><creatorcontrib>Legros, J.-P.</creatorcontrib><creatorcontrib>Malfant, I.</creatorcontrib><creatorcontrib>Pokhodnia, K.</creatorcontrib><creatorcontrib>Tokumoto, M.</creatorcontrib><collection>CrossRef</collection><collection>Hyper Article en Ligne (HAL)</collection><jtitle>Synthetic metals</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Brossard, L.</au><au>Cassoux, P.</au><au>Dyachenko, O.</au><au>Faulmann, C.</au><au>Graja, A.</au><au>Kobayashi, H.</au><au>Kobayashi, A.</au><au>Kushch, N.</au><au>Lacroix, P.G.</au><au>Legros, J.-P.</au><au>Malfant, I.</au><au>Pokhodnia, K.</au><au>Tokumoto, M.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Interplay of conductivity, magnetism (and nonlinear optics) in organic-inorganic compounds</atitle><jtitle>Synthetic metals</jtitle><date>1997-02-28</date><risdate>1997</risdate><volume>86</volume><issue>1</issue><spage>1785</spage><epage>1788</epage><pages>1785-1788</pages><artnum>1785</artnum><issn>0379-6779</issn><eissn>1879-3290</eissn><abstract>The preparation and characterization of organic-inorganic molecule-based systems in which conduction electrons coexist with localized moments is reported. These systems comprise (i) charge transfer salts of organic donors, such as BETS (bis(ethylenedithio)tetraselena-fulvalene), and paramagnetic inorganic anions, such as [MX
4]
−, [M
2X
6]
2− with M = Fe, Cu, etc., and X = Cl, Br, etc., or (ii) charge transfer salts of inorganic acceptor bisdithiolato metal complexes, such as M(dmit)
2 (dmit
2− = 2-thioxo-1,3-dithiole-4,5-dithiolato), and paramagnetic organometallic cations, such as [MCp
2]
n+ (Cp = cyclopentadienyl-like ligands). In some favorable cases, such as λ-(BETS)
2(FeCl
4), new experimental evidence for interaction between the conduction electrons (of BETS) and magnetic moments (localized on [FeCl
4) is discussed. Current research towards the coupling of electrical and nonlinear optical properties in molecule-based compounds is reported. Additional evidence for the oxidation-induced symmetry breakdown in [bis-TTF]
+ radical cations is given.</abstract><pub>Elsevier B.V</pub><doi>10.1016/S0379-6779(96)04589-4</doi><tpages>4</tpages><orcidid>https://orcid.org/0000-0002-5676-6924</orcidid><orcidid>https://orcid.org/0000-0002-1185-2124</orcidid></addata></record> |
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| subjects | Chemical Sciences electrocrystallization electron spin resonance magnetic measurements or physical chemistry organic conductors based on radical cation and/or anion salts Organic superconductors Theoretical and X-ray diffraction |
| title | Interplay of conductivity, magnetism (and nonlinear optics) in organic-inorganic compounds |
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