Feasibility of multiple excited-state proton transfer processes in hydroxyquinoline-containing benzobisimidazole dyes

Two new benzobisimidazole platforms incorporating 7-hydroxyquinoline moieties were synthesized and characterized to explore potential multiple proton transfer processes. Combining experimental analysis with theoretical insights, we investigated the photophysical properties and excited-state proton t...

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Veröffentlicht in:New journal of chemistry 2024-07, Vol.48 (3), p.13289-13295
Hauptverfasser: Munteanu, Tatiana, Yordanov, Dancho, Canard, Gabriel, Siri, Olivier, Jacquemin, Denis, Georgiev, Anton, Pascal, Simon
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container_issue 3
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container_title New journal of chemistry
container_volume 48
creator Munteanu, Tatiana
Yordanov, Dancho
Canard, Gabriel
Siri, Olivier
Jacquemin, Denis
Georgiev, Anton
Pascal, Simon
description Two new benzobisimidazole platforms incorporating 7-hydroxyquinoline moieties were synthesized and characterized to explore potential multiple proton transfer processes. Combining experimental analysis with theoretical insights, we investigated the photophysical properties and excited-state proton transfer phenomena within these systems and found that double proton transfer is unlikely to happen. Two new benzobisimidazole platforms incorporating 7-hydroxyquinoline moieties were synthesized and characterized to explore potential multiple proton transfer processes.
doi_str_mv 10.1039/d4nj01787k
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subjects Chemical Sciences
Excitation
Hydroxyquinoline
or physical chemistry
Organic chemistry
Protons
Theoretical and
title Feasibility of multiple excited-state proton transfer processes in hydroxyquinoline-containing benzobisimidazole dyes
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