Helicene Aromaticity Deviates from the Clar Rule—On the Electronic Dissimilarity of Large Isomeric Fibonacenes

This combined experimental and theoretical study illustrates the profound consequences of non‐planarity on the electronic properties of polycyclic arenes. Three isomeric [10]fibonacene tetraesters were synthesized through a robust and regiocontrolled Perkin/Mallory approach: a nearly planar [10]phen...

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Veröffentlicht in:	Angewandte Chemie International Edition 2024-06, Vol.63 (23), p.e202403170-n/a
Hauptverfasser:	Sturm, Ludmilla, Artigas, Albert, Coquerel, Yoann, Bechtold, Ivan H., Durola, Fabien, Bock, Harald
Format:	Artikel
Sprache:	eng
Schlagworte:	Aromatic compounds Aromaticity Chemical Sciences helicenes Isomers Perkin reaction phenacenes polycyclic arenes
Online-Zugang:	Volltext
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