Hafnium coordination vitrimer based on carboxylate exchange: synthesis, properties, and mechanistic investigations on the [Hf6O4(OH)4(O2CMe)12]2 model compound

A hafnium‐based coordination vitrimer (Hf−CooAN‐10) has been prepared by carboxylate ligand exchange from [Hf6O4(OH)4(O2CMe)12]2 and poly‐((ethylhexyl methacylate)‐co‐(carboxyethyl acrylate)) (Mn = 14.4 kg mol−1, Đ = 2.2, 90 : 10 comonomer molar ratio), using a 10 % molar Hf loading with respect to...

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