Site‐Selective Pd‐Catalysed Fujiwara‐Moritani type Reaction of N,S‐Heterocyclic Systems with Olefins

Dihydro‐1,4‐thiazine skeletons bearing olefin fragment at their α‐position were prepared through a Pd(OAc)2‐catalysed Fujiwara‐Moritani type reaction via C−H alkenylation with olefins. This approach is selective, generalizable to a wide range of olefins and requires only 1 eq. of Ag2CO3 without the...

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Veröffentlicht in:	Advanced synthesis & catalysis 2021-02, Vol.363 (4), p.1088-1095
Hauptverfasser:	Danton, Fanny, Najjar, Riham, Othman, Mohamed, Lawson, Ata Martin, Moncol, Ján, Ghinet, Alina, Rigo, Benoît, Oulyadi, Hassan, Daïch, Adam
Format:	Artikel
Sprache:	eng
Schlagworte:	1,4-Thiazine Alkenes Chemical Sciences Cycloaddition C−H Alkenylation Enamide Hydrogen bonds Oxidation Oxidative coupling Oxidizing agents Pd(II)-Catalysis Substitution reactions Valence
Online-Zugang:	Volltext
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