Tuning the Valence of MnOx Cathodes Reveals the Universality of the Proton‐Coupled Electrodissolution/Electrodeposition Mechanism in Rechargeable Aqueous Zn Batteries

The charge storage mechanism of manganese oxides (MnOx) in rechargeable mild aqueous Zn batteries is still a matter of debate, with no consensus on mechanism and charge carriers. In this work, this issue is addressed by relying on a quantitative and comparative electrochemical study of low‐valence c...

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Veröffentlicht in:	Advanced energy materials 2023-12, Vol.13 (46), p.n/a
Hauptverfasser:	Singh, Arvinder, Laberty‐Robert, Christel, Balland, Véronique, Limoges, Benoît
Format:	Artikel
Sprache:	eng
Schlagworte:	Aqueous electrolytes buffered electrolytes Cathodes charge storage mechanism Chemical Sciences Current carriers Degree of crystallinity Discharge Dissolution Electrodeposition Electrodissolution Electrolytes Manganese dioxide Manganese oxides Oxidation Phase transitions Protons Rechargeable batteries spinel Mn3O4 Valence Zinc zinc batteries
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