The molecular-level effect of alkoxide additives in iron-catalyzed Kumada cross-coupling with simple ferric salts

The molecular-level role of alkoxide salts, used as alternative additive to N -methylpyrrolidone in iron-catalyzed alkyl-alkenyl/aryl cross-coupling reactions, is investigated. Detailed spectroscopic studies reveal that alkoxides promote the formation of homoleptic organoferrates such as [FeMe 3 ] −...

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Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2023-01, Vol.59 (1), p.1317-132
Hauptverfasser:	Bakas, Nikki J, Chourreu, Pablo, Gayon, Eric, Lefèvre, Guillaume, Neidig, Michael L
Format:	Artikel
Sprache:	eng
Schlagworte:	Additives Alkoxides Chemical reactions Chemical Sciences Coupling (molecular) Cross coupling Ferric salts Iron
Online-Zugang:	Volltext
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