Coordination Adaptable Networks: Introducing Vitrimer Properties Using Dynamic Coordination Bonds
Coordination adaptable networks (CooANs) may be obtained by combination of ligand‐functionalized polymers and metal ions or clusters when the crosslink migration by ligand exchange with available free ligands in the polymer matrix is facile. These materials may be called “coordination vitrimers” if...
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Veröffentlicht in: | European journal of inorganic chemistry 2023-12, Vol.26 (36), p.n/a |
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creator | Murali, Meenu Manoury, Eric Poli, Rinaldo |
description | Coordination adaptable networks (CooANs) may be obtained by combination of ligand‐functionalized polymers and metal ions or clusters when the crosslink migration by ligand exchange with available free ligands in the polymer matrix is facile. These materials may be called “coordination vitrimers” if proven to follow an associative ligand exchange mechanism. This review presents various types of CooANs, classified according to the nature of the metal‐binding functions, e. g. imine, imidazoles, pyridines as L‐type ligands; catecholates, thiolates, carboxylates as X‐type ligands. Particular attention is placed on the crosslink migration mechanism.
Known Coordination Adaptable Networks (CooANs) have been classified by type of exchanging ligands; special attention has been devoted to the mechanism of ligand exchange responsible for crosslink migration, possibly allowing them to be considered as “coordination vitrimers”. |
doi_str_mv | 10.1002/ejic.202300574 |
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Known Coordination Adaptable Networks (CooANs) have been classified by type of exchanging ligands; special attention has been devoted to the mechanism of ligand exchange responsible for crosslink migration, possibly allowing them to be considered as “coordination vitrimers”.</description><subject>associative ligand exchange</subject><subject>Carboxylates</subject><subject>Chemical Sciences</subject><subject>Coordination</subject><subject>coordination adaptable networks</subject><subject>Crosslinking</subject><subject>dissociative ligand exchange</subject><subject>Imidazole</subject><subject>Ligands</subject><subject>Material chemistry</subject><subject>Pyridines</subject><subject>reshapable polymer materials</subject><subject>Vitrimers</subject><issn>1434-1948</issn><issn>1099-0682</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNqFkL1PwzAQxS0EEqWwMkdiYkg5f-TDbKUUWlQBA2W1HMcBlzQOdkrV_55EQUVMTHe6-72np4fQOYYRBiBXemXUiAChAFHCDtAAA-chxCk5bHdGWYg5S4_RifcrAKBA4wGSE2tdbirZGFsF41zWjcxKHTzqZmvdh78O5lXjbL5RpnoLXk3jzFq74NnZWrvGaB8sffe53VVybVTwx-7GVrk_RUeFLL0--5lDtLybvkxm4eLpfj4ZL0JFI8xCongUYcJpxFVBZBanRYR1qnSiqaIJwYTKiNMsw1gpDFhKFqdpnGVJntFcajpEl73vuyxF3caUbiesNGI2XojuBozEnAP-wi170bO1s58b7RuxshtXtfEE4UDTKE4S1lKjnlLOeu90sbfFILrKRVe52FfeCngv2JpS7_6hxfRhPvnVfgN2e4Vk</recordid><startdate>20231220</startdate><enddate>20231220</enddate><creator>Murali, Meenu</creator><creator>Manoury, Eric</creator><creator>Poli, Rinaldo</creator><general>Wiley Subscription Services, Inc</general><general>Wiley-VCH Verlag</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>1XC</scope><scope>VOOES</scope><orcidid>https://orcid.org/0000-0002-5220-2515</orcidid><orcidid>https://orcid.org/0000-0001-7991-8890</orcidid></search><sort><creationdate>20231220</creationdate><title>Coordination Adaptable Networks: Introducing Vitrimer Properties Using Dynamic Coordination Bonds</title><author>Murali, Meenu ; Manoury, Eric ; Poli, Rinaldo</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3514-2c955129359cf2ab68f51e8ce7e3c372123a593bb11cc101aa46886bb7db3dae3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>associative ligand exchange</topic><topic>Carboxylates</topic><topic>Chemical Sciences</topic><topic>Coordination</topic><topic>coordination adaptable networks</topic><topic>Crosslinking</topic><topic>dissociative ligand exchange</topic><topic>Imidazole</topic><topic>Ligands</topic><topic>Material chemistry</topic><topic>Pyridines</topic><topic>reshapable polymer materials</topic><topic>Vitrimers</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Murali, Meenu</creatorcontrib><creatorcontrib>Manoury, Eric</creatorcontrib><creatorcontrib>Poli, Rinaldo</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Hyper Article en Ligne (HAL)</collection><collection>Hyper Article en Ligne (HAL) (Open Access)</collection><jtitle>European journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Murali, Meenu</au><au>Manoury, Eric</au><au>Poli, Rinaldo</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Coordination Adaptable Networks: Introducing Vitrimer Properties Using Dynamic Coordination Bonds</atitle><jtitle>European journal of inorganic chemistry</jtitle><date>2023-12-20</date><risdate>2023</risdate><volume>26</volume><issue>36</issue><epage>n/a</epage><issn>1434-1948</issn><eissn>1099-0682</eissn><abstract>Coordination adaptable networks (CooANs) may be obtained by combination of ligand‐functionalized polymers and metal ions or clusters when the crosslink migration by ligand exchange with available free ligands in the polymer matrix is facile. These materials may be called “coordination vitrimers” if proven to follow an associative ligand exchange mechanism. This review presents various types of CooANs, classified according to the nature of the metal‐binding functions, e. g. imine, imidazoles, pyridines as L‐type ligands; catecholates, thiolates, carboxylates as X‐type ligands. Particular attention is placed on the crosslink migration mechanism.
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subjects | associative ligand exchange Carboxylates Chemical Sciences Coordination coordination adaptable networks Crosslinking dissociative ligand exchange Imidazole Ligands Material chemistry Pyridines reshapable polymer materials Vitrimers |
title | Coordination Adaptable Networks: Introducing Vitrimer Properties Using Dynamic Coordination Bonds |
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