Coordination Adaptable Networks: Introducing Vitrimer Properties Using Dynamic Coordination Bonds

Coordination adaptable networks (CooANs) may be obtained by combination of ligand‐functionalized polymers and metal ions or clusters when the crosslink migration by ligand exchange with available free ligands in the polymer matrix is facile. These materials may be called “coordination vitrimers” if...

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Veröffentlicht in:European journal of inorganic chemistry 2023-12, Vol.26 (36), p.n/a
Hauptverfasser: Murali, Meenu, Manoury, Eric, Poli, Rinaldo
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Manoury, Eric
Poli, Rinaldo
description Coordination adaptable networks (CooANs) may be obtained by combination of ligand‐functionalized polymers and metal ions or clusters when the crosslink migration by ligand exchange with available free ligands in the polymer matrix is facile. These materials may be called “coordination vitrimers” if proven to follow an associative ligand exchange mechanism. This review presents various types of CooANs, classified according to the nature of the metal‐binding functions, e. g. imine, imidazoles, pyridines as L‐type ligands; catecholates, thiolates, carboxylates as X‐type ligands. Particular attention is placed on the crosslink migration mechanism. Known Coordination Adaptable Networks (CooANs) have been classified by type of exchanging ligands; special attention has been devoted to the mechanism of ligand exchange responsible for crosslink migration, possibly allowing them to be considered as “coordination vitrimers”.
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subjects associative ligand exchange
Carboxylates
Chemical Sciences
Coordination
coordination adaptable networks
Crosslinking
dissociative ligand exchange
Imidazole
Ligands
Material chemistry
Pyridines
reshapable polymer materials
Vitrimers
title Coordination Adaptable Networks: Introducing Vitrimer Properties Using Dynamic Coordination Bonds
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