Single-ion nano-features formed by a Li-containing block copolymer synthesized via PISA
Single-ion block copolymer nanoparticles of (poly(ethylene glycol) monomethyl ether monomethacrylate- co -poly(3-((trifluoromethane)sulfonamidosulfonyl) propyl methacrylate))- b -polystyrene, (PEGMA- co -PLiTFSI)- b -PS, were prepared using an efficient RAFT-controlled aqueous emulsion polymerizatio...
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| Veröffentlicht in: | Polymer chemistry 2023-06, Vol.14 (25), p.2971-2978 |
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| container_title | Polymer chemistry |
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| creator | Chouirfa, Hamza Gomri, Chaimaa Benkhaled, Belkacem Tarek Chaix, Arnaud Aissou, Karim Semsarilar, Mona |
| description | Single-ion block copolymer nanoparticles of (poly(ethylene glycol) monomethyl ether monomethacrylate-
co
-poly(3-((trifluoromethane)sulfonamidosulfonyl) propyl methacrylate))-
b
-polystyrene, (PEGMA-
co
-PLiTFSI)-
b
-PS, were prepared using an efficient RAFT-controlled aqueous emulsion polymerization protocol. The macro-chain transfer agent (macroCTA) used, which stabilized the nanoparticles, is a lithium-ion based conductor that can be used for the formation of single-ion polymer electrolytes (SIPEs). This SIPE macroCTA was used as the stabilizer for the synthesis of PS under emulsion conditions at 70 °C, achieving near complete conversion. Kinetic studies revealed good control over the synthesis of the block copolymer (confirmed by NMR spectroscopy and GPC) and formation of spherical nanoparticles of different diameters depending on the length of the hydrophobic (PS) block (confirmed by DLS and TEM). The final high molecular weight diblock copolymer with narrow molecular weight distribution was used to prepare nanostructured films
via
combined solution-casting and solvent vapour annealing (SVA). Nanostructured films were characterised using AFM and GISAXS. |
| doi_str_mv | 10.1039/D3PY00284E |
| format | Article |
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co
-poly(3-((trifluoromethane)sulfonamidosulfonyl) propyl methacrylate))-
b
-polystyrene, (PEGMA-
co
-PLiTFSI)-
b
-PS, were prepared using an efficient RAFT-controlled aqueous emulsion polymerization protocol. The macro-chain transfer agent (macroCTA) used, which stabilized the nanoparticles, is a lithium-ion based conductor that can be used for the formation of single-ion polymer electrolytes (SIPEs). This SIPE macroCTA was used as the stabilizer for the synthesis of PS under emulsion conditions at 70 °C, achieving near complete conversion. Kinetic studies revealed good control over the synthesis of the block copolymer (confirmed by NMR spectroscopy and GPC) and formation of spherical nanoparticles of different diameters depending on the length of the hydrophobic (PS) block (confirmed by DLS and TEM). The final high molecular weight diblock copolymer with narrow molecular weight distribution was used to prepare nanostructured films
via
combined solution-casting and solvent vapour annealing (SVA). Nanostructured films were characterised using AFM and GISAXS.</description><identifier>ISSN: 1759-9954</identifier><identifier>EISSN: 1759-9962</identifier><identifier>DOI: 10.1039/D3PY00284E</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Block copolymers ; Chain transfer ; Chemical Sciences ; Chemical synthesis ; Electrolytes ; Emulsion polymerization ; Lithium ions ; Molecular weight distribution ; Nanoparticles ; Nanostructure ; NMR spectroscopy ; Polyethylene glycol monomethyl ether acrylate ; Polymer chemistry ; Polystyrene resins ; Stabilizers (agents) ; Trifluoromethane</subject><ispartof>Polymer chemistry, 2023-06, Vol.14 (25), p.2971-2978</ispartof><rights>Copyright Royal Society of Chemistry 2023</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c329t-eecdae1d74dc5b5e0ab77ac41a8a1be33aa2f2c3619607f0741c49d5652c81b3</citedby><cites>FETCH-LOGICAL-c329t-eecdae1d74dc5b5e0ab77ac41a8a1be33aa2f2c3619607f0741c49d5652c81b3</cites><orcidid>0000-0002-1544-1824</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,315,782,786,887,27931,27932</link.rule.ids><backlink>$$Uhttps://hal.umontpellier.fr/hal-04222504$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Chouirfa, Hamza</creatorcontrib><creatorcontrib>Gomri, Chaimaa</creatorcontrib><creatorcontrib>Benkhaled, Belkacem Tarek</creatorcontrib><creatorcontrib>Chaix, Arnaud</creatorcontrib><creatorcontrib>Aissou, Karim</creatorcontrib><creatorcontrib>Semsarilar, Mona</creatorcontrib><title>Single-ion nano-features formed by a Li-containing block copolymer synthesized via PISA</title><title>Polymer chemistry</title><description>Single-ion block copolymer nanoparticles of (poly(ethylene glycol) monomethyl ether monomethacrylate-
co
-poly(3-((trifluoromethane)sulfonamidosulfonyl) propyl methacrylate))-
b
-polystyrene, (PEGMA-
co
-PLiTFSI)-
b
-PS, were prepared using an efficient RAFT-controlled aqueous emulsion polymerization protocol. The macro-chain transfer agent (macroCTA) used, which stabilized the nanoparticles, is a lithium-ion based conductor that can be used for the formation of single-ion polymer electrolytes (SIPEs). This SIPE macroCTA was used as the stabilizer for the synthesis of PS under emulsion conditions at 70 °C, achieving near complete conversion. Kinetic studies revealed good control over the synthesis of the block copolymer (confirmed by NMR spectroscopy and GPC) and formation of spherical nanoparticles of different diameters depending on the length of the hydrophobic (PS) block (confirmed by DLS and TEM). The final high molecular weight diblock copolymer with narrow molecular weight distribution was used to prepare nanostructured films
via
combined solution-casting and solvent vapour annealing (SVA). Nanostructured films were characterised using AFM and GISAXS.</description><subject>Block copolymers</subject><subject>Chain transfer</subject><subject>Chemical Sciences</subject><subject>Chemical synthesis</subject><subject>Electrolytes</subject><subject>Emulsion polymerization</subject><subject>Lithium ions</subject><subject>Molecular weight distribution</subject><subject>Nanoparticles</subject><subject>Nanostructure</subject><subject>NMR spectroscopy</subject><subject>Polyethylene glycol monomethyl ether acrylate</subject><subject>Polymer chemistry</subject><subject>Polystyrene resins</subject><subject>Stabilizers (agents)</subject><subject>Trifluoromethane</subject><issn>1759-9954</issn><issn>1759-9962</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNpF0N9LwzAQB_AgCo65F_-CgE8K1fxq0zyOOd2g4GAD8Smkaeoyu2Qm3aD-9XZM5r3ccXw4ji8Atxg9YkTF0zNdfCBEcja9AAPMU5EIkZHL85yyazCKcYP6opgRmg3A-9K6z8Yk1jvolPNJbVS7DybC2oetqWDZQQULm2jvWmVdr2HZeP0Ftd_5ptuaAGPn2rWJ9qfnB6vgYr4c34CrWjXRjP76EKxepqvJLCneXueTcZFoSkSbGKMrZXDFWaXTMjVIlZwrzbDKFS4NpUqRmmiaYZEhXiPOsGaiSrOU6ByXdAjuT2fXqpG7YLcqdNIrK2fjQh53iBFCUsQOuLd3J7sL_ntvYis3fh9c_50kOREZ5yynvXo4KR18jMHU57MYyWPM8j9m-guWA26R</recordid><startdate>20230627</startdate><enddate>20230627</enddate><creator>Chouirfa, Hamza</creator><creator>Gomri, Chaimaa</creator><creator>Benkhaled, Belkacem Tarek</creator><creator>Chaix, Arnaud</creator><creator>Aissou, Karim</creator><creator>Semsarilar, Mona</creator><general>Royal Society of Chemistry</general><general>Royal Society of Chemistry - RSC</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope><scope>1XC</scope><scope>VOOES</scope><orcidid>https://orcid.org/0000-0002-1544-1824</orcidid></search><sort><creationdate>20230627</creationdate><title>Single-ion nano-features formed by a Li-containing block copolymer synthesized via PISA</title><author>Chouirfa, Hamza ; Gomri, Chaimaa ; Benkhaled, Belkacem Tarek ; Chaix, Arnaud ; Aissou, Karim ; Semsarilar, Mona</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c329t-eecdae1d74dc5b5e0ab77ac41a8a1be33aa2f2c3619607f0741c49d5652c81b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Block copolymers</topic><topic>Chain transfer</topic><topic>Chemical Sciences</topic><topic>Chemical synthesis</topic><topic>Electrolytes</topic><topic>Emulsion polymerization</topic><topic>Lithium ions</topic><topic>Molecular weight distribution</topic><topic>Nanoparticles</topic><topic>Nanostructure</topic><topic>NMR spectroscopy</topic><topic>Polyethylene glycol monomethyl ether acrylate</topic><topic>Polymer chemistry</topic><topic>Polystyrene resins</topic><topic>Stabilizers (agents)</topic><topic>Trifluoromethane</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Chouirfa, Hamza</creatorcontrib><creatorcontrib>Gomri, Chaimaa</creatorcontrib><creatorcontrib>Benkhaled, Belkacem Tarek</creatorcontrib><creatorcontrib>Chaix, Arnaud</creatorcontrib><creatorcontrib>Aissou, Karim</creatorcontrib><creatorcontrib>Semsarilar, Mona</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Hyper Article en Ligne (HAL)</collection><collection>Hyper Article en Ligne (HAL) (Open Access)</collection><jtitle>Polymer chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Chouirfa, Hamza</au><au>Gomri, Chaimaa</au><au>Benkhaled, Belkacem Tarek</au><au>Chaix, Arnaud</au><au>Aissou, Karim</au><au>Semsarilar, Mona</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Single-ion nano-features formed by a Li-containing block copolymer synthesized via PISA</atitle><jtitle>Polymer chemistry</jtitle><date>2023-06-27</date><risdate>2023</risdate><volume>14</volume><issue>25</issue><spage>2971</spage><epage>2978</epage><pages>2971-2978</pages><issn>1759-9954</issn><eissn>1759-9962</eissn><abstract>Single-ion block copolymer nanoparticles of (poly(ethylene glycol) monomethyl ether monomethacrylate-
co
-poly(3-((trifluoromethane)sulfonamidosulfonyl) propyl methacrylate))-
b
-polystyrene, (PEGMA-
co
-PLiTFSI)-
b
-PS, were prepared using an efficient RAFT-controlled aqueous emulsion polymerization protocol. The macro-chain transfer agent (macroCTA) used, which stabilized the nanoparticles, is a lithium-ion based conductor that can be used for the formation of single-ion polymer electrolytes (SIPEs). This SIPE macroCTA was used as the stabilizer for the synthesis of PS under emulsion conditions at 70 °C, achieving near complete conversion. Kinetic studies revealed good control over the synthesis of the block copolymer (confirmed by NMR spectroscopy and GPC) and formation of spherical nanoparticles of different diameters depending on the length of the hydrophobic (PS) block (confirmed by DLS and TEM). The final high molecular weight diblock copolymer with narrow molecular weight distribution was used to prepare nanostructured films
via
combined solution-casting and solvent vapour annealing (SVA). Nanostructured films were characterised using AFM and GISAXS.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/D3PY00284E</doi><tpages>8</tpages><orcidid>https://orcid.org/0000-0002-1544-1824</orcidid><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1759-9954 |
| ispartof | Polymer chemistry, 2023-06, Vol.14 (25), p.2971-2978 |
| issn | 1759-9954 1759-9962 |
| language | eng |
| recordid | cdi_hal_primary_oai_HAL_hal_04222504v1 |
| source | Royal Society Of Chemistry Journals |
| subjects | Block copolymers Chain transfer Chemical Sciences Chemical synthesis Electrolytes Emulsion polymerization Lithium ions Molecular weight distribution Nanoparticles Nanostructure NMR spectroscopy Polyethylene glycol monomethyl ether acrylate Polymer chemistry Polystyrene resins Stabilizers (agents) Trifluoromethane |
| title | Single-ion nano-features formed by a Li-containing block copolymer synthesized via PISA |
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