Structure of the new iron(II) oxalate potassium salt K2Fe[(C2O4)2(H2O)2]·0.18H2O
The discovery of a new FeII oxalate framework of composition K2Fe[(C2O4)2(H2O)2]·0.18H2O is reported. Its crystal structure was solved by means of single crystal and powder X‐ray diffraction. The new organic–inorganic hybrid compound crystallizes in the orthorhombic space group Pca21 with unit‐cell...
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| Veröffentlicht in: | Acta crystallographica Section B, Structural science, crystal engineering and materials Structural science, crystal engineering and materials, 2023-08, Vol.79 (4), p.263-270 |
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| container_title | Acta crystallographica Section B, Structural science, crystal engineering and materials |
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| creator | Amanchar, Sara Schweitzer, Thierry Mazet, Thomas Malaman, Bernard Diop, Leopold V. B Francois, Michel |
| description | The discovery of a new FeII oxalate framework of composition K2Fe[(C2O4)2(H2O)2]·0.18H2O is reported. Its crystal structure was solved by means of single crystal and powder X‐ray diffraction. The new organic–inorganic hybrid compound crystallizes in the orthorhombic space group Pca21 with unit‐cell parameters: a = 12.0351 (4) Å, b = 15.1265 (5) Å, c = 10.5562 (4) Å. This crystal structure, containing eight chemical formula, consists of a succession of FeO4(H2O)2 octahedra and K+ cations growing along b direction. Magnetization measurements indicate that the title compound is paramagnetic over the investigated temperature range (2–300 K). Both magnetization and 57Fe Mössbauer data indicate that Fe2+ is in a high‐spin state.
The crystal structure of a new FeII‐based metal organic framework of composition K2Fe[(C2O4)2(H2O)2]·0.18H2O is resolved using single crystal and powder X‐ray diffraction. |
| doi_str_mv | 10.1107/S2052520623004602 |
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The crystal structure of a new FeII‐based metal organic framework of composition K2Fe[(C2O4)2(H2O)2]·0.18H2O is resolved using single crystal and powder X‐ray diffraction.</description><identifier>ISSN: 2052-5206</identifier><identifier>ISSN: 2052-5192</identifier><identifier>EISSN: 2052-5206</identifier><identifier>DOI: 10.1107/S2052520623004602</identifier><language>eng</language><publisher>5 Abbey Square, Chester, Cheshire CH1 2HU, England: International Union of Crystallography</publisher><subject>Cations ; Chemical Sciences ; Cristallography ; Crystal structure ; iron(II) oxalate ; Magnetization ; Material chemistry ; metal–organic framework ; Potassium ; Potassium salts ; Single crystals</subject><ispartof>Acta crystallographica Section B, Structural science, crystal engineering and materials, 2023-08, Vol.79 (4), p.263-270</ispartof><rights>2023 Sara Amanchar et al. published by IUCr Journals.</rights><rights>Copyright Blackwell Publishing Ltd. Aug 2023</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><orcidid>0000-0001-8989-6955 ; 0000-0003-1077-7561 ; 0000-0002-6078-7023</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1107%2FS2052520623004602$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1107%2FS2052520623004602$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>230,314,780,784,885,1416,27923,27924,45573,45574</link.rule.ids><backlink>$$Uhttps://hal.science/hal-04185823$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Amanchar, Sara</creatorcontrib><creatorcontrib>Schweitzer, Thierry</creatorcontrib><creatorcontrib>Mazet, Thomas</creatorcontrib><creatorcontrib>Malaman, Bernard</creatorcontrib><creatorcontrib>Diop, Leopold V. B</creatorcontrib><creatorcontrib>Francois, Michel</creatorcontrib><title>Structure of the new iron(II) oxalate potassium salt K2Fe[(C2O4)2(H2O)2]·0.18H2O</title><title>Acta crystallographica Section B, Structural science, crystal engineering and materials</title><description>The discovery of a new FeII oxalate framework of composition K2Fe[(C2O4)2(H2O)2]·0.18H2O is reported. Its crystal structure was solved by means of single crystal and powder X‐ray diffraction. The new organic–inorganic hybrid compound crystallizes in the orthorhombic space group Pca21 with unit‐cell parameters: a = 12.0351 (4) Å, b = 15.1265 (5) Å, c = 10.5562 (4) Å. This crystal structure, containing eight chemical formula, consists of a succession of FeO4(H2O)2 octahedra and K+ cations growing along b direction. Magnetization measurements indicate that the title compound is paramagnetic over the investigated temperature range (2–300 K). Both magnetization and 57Fe Mössbauer data indicate that Fe2+ is in a high‐spin state.
The crystal structure of a new FeII‐based metal organic framework of composition K2Fe[(C2O4)2(H2O)2]·0.18H2O is resolved using single crystal and powder X‐ray diffraction.</description><subject>Cations</subject><subject>Chemical Sciences</subject><subject>Cristallography</subject><subject>Crystal structure</subject><subject>iron(II) oxalate</subject><subject>Magnetization</subject><subject>Material chemistry</subject><subject>metal–organic framework</subject><subject>Potassium</subject><subject>Potassium salts</subject><subject>Single crystals</subject><issn>2052-5206</issn><issn>2052-5192</issn><issn>2052-5206</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNplkcFKAzEQhoMoWGofwFvAy-6hmkx2k-xxLdYWC0WrBxEJ6ZrSLdtN3exa-2TefTKzVET0NMPPN__8wyB0Ssk5pURczIDEEAPhwAiJOIED1Gmlfqsd_uqPUc-5FSHEj8XAaQfdzuqqyeqmMtgucL00uDRbnFe2DMbjENt3Xeja4I2ttXN5s8ZOFzW-gaF5CgYwjUIIRjAN4fnzw4eRvj9BRwtdONP7rl30MLy6H4z6k-n1eJBO-ksWsaTPM6aNiBllfC59FE6J5i-ScCMo05RHsQQJQlC6YKDjjCVEA5F-JpkLlkSsi8K971IXalPla13tlNW5GqUT1WokotKbsDfq2WDPbir72hhXq3XuMlMUujS2ccpvkkIwCeDRsz_oyjZV6S_xVCR4BCJuDZM9tc0Ls_tZT4lqH6L-PUSlj5dwl8YUEvYFe214aw</recordid><startdate>202308</startdate><enddate>202308</enddate><creator>Amanchar, Sara</creator><creator>Schweitzer, Thierry</creator><creator>Mazet, Thomas</creator><creator>Malaman, Bernard</creator><creator>Diop, Leopold V. B</creator><creator>Francois, Michel</creator><general>International Union of Crystallography</general><general>Blackwell Publishing Ltd</general><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>7X8</scope><scope>1XC</scope><scope>VOOES</scope><orcidid>https://orcid.org/0000-0001-8989-6955</orcidid><orcidid>https://orcid.org/0000-0003-1077-7561</orcidid><orcidid>https://orcid.org/0000-0002-6078-7023</orcidid></search><sort><creationdate>202308</creationdate><title>Structure of the new iron(II) oxalate potassium salt K2Fe[(C2O4)2(H2O)2]·0.18H2O</title><author>Amanchar, Sara ; Schweitzer, Thierry ; Mazet, Thomas ; Malaman, Bernard ; Diop, Leopold V. 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B</creatorcontrib><creatorcontrib>Francois, Michel</creatorcontrib><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>MEDLINE - Academic</collection><collection>Hyper Article en Ligne (HAL)</collection><collection>Hyper Article en Ligne (HAL) (Open Access)</collection><jtitle>Acta crystallographica Section B, Structural science, crystal engineering and materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Amanchar, Sara</au><au>Schweitzer, Thierry</au><au>Mazet, Thomas</au><au>Malaman, Bernard</au><au>Diop, Leopold V. B</au><au>Francois, Michel</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Structure of the new iron(II) oxalate potassium salt K2Fe[(C2O4)2(H2O)2]·0.18H2O</atitle><jtitle>Acta crystallographica Section B, Structural science, crystal engineering and materials</jtitle><date>2023-08</date><risdate>2023</risdate><volume>79</volume><issue>4</issue><spage>263</spage><epage>270</epage><pages>263-270</pages><issn>2052-5206</issn><issn>2052-5192</issn><eissn>2052-5206</eissn><abstract>The discovery of a new FeII oxalate framework of composition K2Fe[(C2O4)2(H2O)2]·0.18H2O is reported. Its crystal structure was solved by means of single crystal and powder X‐ray diffraction. The new organic–inorganic hybrid compound crystallizes in the orthorhombic space group Pca21 with unit‐cell parameters: a = 12.0351 (4) Å, b = 15.1265 (5) Å, c = 10.5562 (4) Å. This crystal structure, containing eight chemical formula, consists of a succession of FeO4(H2O)2 octahedra and K+ cations growing along b direction. Magnetization measurements indicate that the title compound is paramagnetic over the investigated temperature range (2–300 K). Both magnetization and 57Fe Mössbauer data indicate that Fe2+ is in a high‐spin state.
The crystal structure of a new FeII‐based metal organic framework of composition K2Fe[(C2O4)2(H2O)2]·0.18H2O is resolved using single crystal and powder X‐ray diffraction.</abstract><cop>5 Abbey Square, Chester, Cheshire CH1 2HU, England</cop><pub>International Union of Crystallography</pub><doi>10.1107/S2052520623004602</doi><tpages>8</tpages><orcidid>https://orcid.org/0000-0001-8989-6955</orcidid><orcidid>https://orcid.org/0000-0003-1077-7561</orcidid><orcidid>https://orcid.org/0000-0002-6078-7023</orcidid><oa>free_for_read</oa></addata></record> |
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| subjects | Cations Chemical Sciences Cristallography Crystal structure iron(II) oxalate Magnetization Material chemistry metal–organic framework Potassium Potassium salts Single crystals |
| title | Structure of the new iron(II) oxalate potassium salt K2Fe[(C2O4)2(H2O)2]·0.18H2O |
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