Electrochemical performance of catalyst couples M/stainless steel 430 (M: Ni, Co, and Cu) for the hydrogen production in KOH electrolyte
In this work, three catalysts (nickel, cobalt, copper) are electrochemically deposited on stainless steel substrates AISI 430 and their performances as cathodes in the hydrogen evolution reaction (HER) are investigated. The electrodes, characterized by scanning electron microscopy (SEM) and X-ray di...
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| Veröffentlicht in: | Journal of solid state electrochemistry 2019-10, Vol.23 (10), p.2961-2968 |
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| container_title | Journal of solid state electrochemistry |
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| creator | Amrouche, A. Messaoud, F. Boutarek-Zaourar, N. David, P. Mossang, E. Mansour, S. Slimane, M. Trari, M. |
| description | In this work, three catalysts (nickel, cobalt, copper) are electrochemically deposited on stainless steel substrates AISI 430 and their performances as cathodes in the hydrogen evolution reaction (HER) are investigated. The electrodes, characterized by scanning electron microscopy (SEM) and X-ray diffraction (XRD), have been the subject of a study of their electrocatalytic efficiency in KOH (1 M) solution at 298 K through HER, stability, polarization curves, and electrochemical impedance spectroscopy. The results showed that the developed electrodes have a catalytic activity superior to that of untreated stainless steel AISI 430. The nickel coating exhibits the best HER performance. In addition, the rough Ni coating proved to be more efficient than smooth Ni-electrode, resulting in 320% reduction in the energy consumption of the electrolysis cell relative to the uncoated steel cathode. |
| doi_str_mv | 10.1007/s10008-019-04395-2 |
| format | Article |
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The electrodes, characterized by scanning electron microscopy (SEM) and X-ray diffraction (XRD), have been the subject of a study of their electrocatalytic efficiency in KOH (1 M) solution at 298 K through HER, stability, polarization curves, and electrochemical impedance spectroscopy. The results showed that the developed electrodes have a catalytic activity superior to that of untreated stainless steel AISI 430. The nickel coating exhibits the best HER performance. In addition, the rough Ni coating proved to be more efficient than smooth Ni-electrode, resulting in 320% reduction in the energy consumption of the electrolysis cell relative to the uncoated steel cathode.</description><identifier>ISSN: 1432-8488</identifier><identifier>EISSN: 1433-0768</identifier><identifier>DOI: 10.1007/s10008-019-04395-2</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Analytical Chemistry ; Catalysts ; Catalytic activity ; Cathodes ; Characterization and Evaluation of Materials ; Chemistry ; Chemistry and Materials Science ; Coated electrodes ; Condensed Matter Physics ; Copper ; Electrochemical analysis ; Electrochemical impedance spectroscopy ; Electrochemistry ; Electrode polarization ; Electrolysis ; Energy consumption ; Energy Storage ; Hydrogen evolution reactions ; Hydrogen production ; Nickel ; Nickel coatings ; Original Paper ; Physical Chemistry ; Physics ; Stainless steel ; Stainless steels ; Substrates</subject><ispartof>Journal of solid state electrochemistry, 2019-10, Vol.23 (10), p.2961-2968</ispartof><rights>Springer-Verlag GmbH Germany, part of Springer Nature 2019</rights><rights>Copyright Springer Nature B.V. 2019</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c390t-fe93277ed3741cc105a9c01bcb94fe4aa50db82df636e9464e087b2a41cc69b93</citedby><cites>FETCH-LOGICAL-c390t-fe93277ed3741cc105a9c01bcb94fe4aa50db82df636e9464e087b2a41cc69b93</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10008-019-04395-2$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10008-019-04395-2$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>230,314,776,780,881,27903,27904,41467,42536,51297</link.rule.ids><backlink>$$Uhttps://cnrs.hal.science/hal-04126189$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Amrouche, A.</creatorcontrib><creatorcontrib>Messaoud, F.</creatorcontrib><creatorcontrib>Boutarek-Zaourar, N.</creatorcontrib><creatorcontrib>David, P.</creatorcontrib><creatorcontrib>Mossang, E.</creatorcontrib><creatorcontrib>Mansour, S.</creatorcontrib><creatorcontrib>Slimane, M.</creatorcontrib><creatorcontrib>Trari, M.</creatorcontrib><title>Electrochemical performance of catalyst couples M/stainless steel 430 (M: Ni, Co, and Cu) for the hydrogen production in KOH electrolyte</title><title>Journal of solid state electrochemistry</title><addtitle>J Solid State Electrochem</addtitle><description>In this work, three catalysts (nickel, cobalt, copper) are electrochemically deposited on stainless steel substrates AISI 430 and their performances as cathodes in the hydrogen evolution reaction (HER) are investigated. The electrodes, characterized by scanning electron microscopy (SEM) and X-ray diffraction (XRD), have been the subject of a study of their electrocatalytic efficiency in KOH (1 M) solution at 298 K through HER, stability, polarization curves, and electrochemical impedance spectroscopy. The results showed that the developed electrodes have a catalytic activity superior to that of untreated stainless steel AISI 430. The nickel coating exhibits the best HER performance. In addition, the rough Ni coating proved to be more efficient than smooth Ni-electrode, resulting in 320% reduction in the energy consumption of the electrolysis cell relative to the uncoated steel cathode.</description><subject>Analytical Chemistry</subject><subject>Catalysts</subject><subject>Catalytic activity</subject><subject>Cathodes</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Coated electrodes</subject><subject>Condensed Matter Physics</subject><subject>Copper</subject><subject>Electrochemical analysis</subject><subject>Electrochemical impedance spectroscopy</subject><subject>Electrochemistry</subject><subject>Electrode polarization</subject><subject>Electrolysis</subject><subject>Energy consumption</subject><subject>Energy Storage</subject><subject>Hydrogen evolution reactions</subject><subject>Hydrogen production</subject><subject>Nickel</subject><subject>Nickel coatings</subject><subject>Original Paper</subject><subject>Physical Chemistry</subject><subject>Physics</subject><subject>Stainless steel</subject><subject>Stainless steels</subject><subject>Substrates</subject><issn>1432-8488</issn><issn>1433-0768</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNp9kcFq3DAQhkVpoem2L9DTQC8NxM3I0lpWb2FJsyGb5JKehSyPsw5eayvJgX2DPHa1cWlvvUiD-P5PAz9jnzl-44jqPOYT6wK5LlAKvSzKN-yESyEKVFX99nUui1rW9Xv2IcYnRK4qjifs5XIgl4J3W9r1zg6wp9D5sLOjI_AdOJvscIgJnJ_2A0W4PY_J9mMeI8RENIAUCF9vv8NdfwYrfwZ2bGE1nULWQNoSbA9t8I80wj74dnKp9yP0I9zcr4Hmz4dDoo_sXWeHSJ_-3Av288flw2pdbO6vrlcXm8IJjanoSItSKWqFktw5jkurHfLGNVp2JK1dYtvUZdtVoiItK0lYq6a0R7jSjRYLdjp7t3Yw-9DvbDgYb3uzvtiY4xtKXla81s88s19mNm_-a6KYzJOfwpjXM6VAJaVQ4mgsZ8oFH2Og7q-Wozm2Y-Z2TG7HvLaT0wsm5lDM8PhI4Z_6P6nfqM2RZQ</recordid><startdate>20191001</startdate><enddate>20191001</enddate><creator>Amrouche, A.</creator><creator>Messaoud, F.</creator><creator>Boutarek-Zaourar, N.</creator><creator>David, P.</creator><creator>Mossang, E.</creator><creator>Mansour, S.</creator><creator>Slimane, M.</creator><creator>Trari, M.</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><general>Springer Verlag</general><scope>AAYXX</scope><scope>CITATION</scope><scope>1XC</scope></search><sort><creationdate>20191001</creationdate><title>Electrochemical performance of catalyst couples M/stainless steel 430 (M: Ni, Co, and Cu) for the hydrogen production in KOH electrolyte</title><author>Amrouche, A. ; Messaoud, F. ; Boutarek-Zaourar, N. ; David, P. ; Mossang, E. ; Mansour, S. ; Slimane, M. ; Trari, M.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c390t-fe93277ed3741cc105a9c01bcb94fe4aa50db82df636e9464e087b2a41cc69b93</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Analytical Chemistry</topic><topic>Catalysts</topic><topic>Catalytic activity</topic><topic>Cathodes</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Coated electrodes</topic><topic>Condensed Matter Physics</topic><topic>Copper</topic><topic>Electrochemical analysis</topic><topic>Electrochemical impedance spectroscopy</topic><topic>Electrochemistry</topic><topic>Electrode polarization</topic><topic>Electrolysis</topic><topic>Energy consumption</topic><topic>Energy Storage</topic><topic>Hydrogen evolution reactions</topic><topic>Hydrogen production</topic><topic>Nickel</topic><topic>Nickel coatings</topic><topic>Original Paper</topic><topic>Physical Chemistry</topic><topic>Physics</topic><topic>Stainless steel</topic><topic>Stainless steels</topic><topic>Substrates</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Amrouche, A.</creatorcontrib><creatorcontrib>Messaoud, F.</creatorcontrib><creatorcontrib>Boutarek-Zaourar, N.</creatorcontrib><creatorcontrib>David, P.</creatorcontrib><creatorcontrib>Mossang, E.</creatorcontrib><creatorcontrib>Mansour, S.</creatorcontrib><creatorcontrib>Slimane, M.</creatorcontrib><creatorcontrib>Trari, M.</creatorcontrib><collection>CrossRef</collection><collection>Hyper Article en Ligne (HAL)</collection><jtitle>Journal of solid state electrochemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Amrouche, A.</au><au>Messaoud, F.</au><au>Boutarek-Zaourar, N.</au><au>David, P.</au><au>Mossang, E.</au><au>Mansour, S.</au><au>Slimane, M.</au><au>Trari, M.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Electrochemical performance of catalyst couples M/stainless steel 430 (M: Ni, Co, and Cu) for the hydrogen production in KOH electrolyte</atitle><jtitle>Journal of solid state electrochemistry</jtitle><stitle>J Solid State Electrochem</stitle><date>2019-10-01</date><risdate>2019</risdate><volume>23</volume><issue>10</issue><spage>2961</spage><epage>2968</epage><pages>2961-2968</pages><issn>1432-8488</issn><eissn>1433-0768</eissn><abstract>In this work, three catalysts (nickel, cobalt, copper) are electrochemically deposited on stainless steel substrates AISI 430 and their performances as cathodes in the hydrogen evolution reaction (HER) are investigated. The electrodes, characterized by scanning electron microscopy (SEM) and X-ray diffraction (XRD), have been the subject of a study of their electrocatalytic efficiency in KOH (1 M) solution at 298 K through HER, stability, polarization curves, and electrochemical impedance spectroscopy. The results showed that the developed electrodes have a catalytic activity superior to that of untreated stainless steel AISI 430. The nickel coating exhibits the best HER performance. In addition, the rough Ni coating proved to be more efficient than smooth Ni-electrode, resulting in 320% reduction in the energy consumption of the electrolysis cell relative to the uncoated steel cathode.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s10008-019-04395-2</doi><tpages>8</tpages></addata></record> |
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| subjects | Analytical Chemistry Catalysts Catalytic activity Cathodes Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Coated electrodes Condensed Matter Physics Copper Electrochemical analysis Electrochemical impedance spectroscopy Electrochemistry Electrode polarization Electrolysis Energy consumption Energy Storage Hydrogen evolution reactions Hydrogen production Nickel Nickel coatings Original Paper Physical Chemistry Physics Stainless steel Stainless steels Substrates |
| title | Electrochemical performance of catalyst couples M/stainless steel 430 (M: Ni, Co, and Cu) for the hydrogen production in KOH electrolyte |
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