Methane dry reforming on supported cobalt nanoparticles promoted by boron

[Display omitted] •B impurities on Co drastically affect dry reforming of methane (DRM) performance.•DFT simulations show that B remained only in interstitial cavities of Co.•Incorporation of B into Co induced acceleration of both CH4 and CO2 activation.•The resultant kinetic balance between surface...

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Veröffentlicht in:	Journal of catalysis 2020-12, Vol.392, p.126-134
Hauptverfasser:	Al Abdulghani, Abdullah J., Park, Jung-Hyun, Kozlov, Sergey M., Kang, Dong-Chang, AlSabban, Bedour, Pedireddy, Srikanth, Aguilar-Tapia, Antonio, Ould-Chikh, Samy, Hazemann, Jean-Louis, Basset, Jean-Marie, Cavallo, Luigi, Takanabe, Kazuhiro
Format:	Artikel
Sprache:	eng
Schlagworte:	Boron Carbon deposition Cobalt Density functional theory Dry reforming of methane Metal oxidation Physics
Online-Zugang:	Volltext
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