Sulfur-Cured Natural Rubber Elastomer Networks: Correlating Cross-Link Density, Chain Orientation, and Mechanical Response by Combined Techniques
We present a combination of independent techniques in order to characterize vulcanized natural rubber elastomer networks. We combine solid state proton multiple-quantum NMR, equilibrium swelling, mechanical experiments, and in-situ tensile X-ray scattering measurements, all of them giving access to...
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| Veröffentlicht in: | Macromolecules 2013-02, Vol.46 (3), p.889-899 |
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| container_title | Macromolecules |
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| creator | Vieyres, Arnaud Pérez-Aparicio, Roberto Albouy, Pierre-Antoine Sanseau, Olivier Saalwächter, Kay Long, Didier R Sotta, Paul |
| description | We present a combination of independent techniques in order to characterize vulcanized natural rubber elastomer networks. We combine solid state proton multiple-quantum NMR, equilibrium swelling, mechanical experiments, and in-situ tensile X-ray scattering measurements, all of them giving access to the segmental orientation effects in relation to the cross-linking of the systems. By means of the combination of these techniques, we investigate a set of unfilled natural rubber networks with different levels of cross-linking. The relevance of this work is the application of this approach in order to study the reinforcement effect in filled elastomers with nanoparticles in a following work. |
| doi_str_mv | 10.1021/ma302563z |
| format | Article |
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| source | ACS Publications |
| subjects | Applied sciences Exact sciences and technology Natural polymers Natural rubber Physicochemistry of polymers Physics |
| title | Sulfur-Cured Natural Rubber Elastomer Networks: Correlating Cross-Link Density, Chain Orientation, and Mechanical Response by Combined Techniques |
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