Heterogeneous Wide Range pH-sensing Materials Allowing Ratiometric Fluorescence Detection Based on Structurally Rigid Analogs of 2,6-distyrylpyridine
The new sensing materials based on the microsized silica gel powder with non-covalently immobilized structurally rigid analogs of 2,6-distyrylpyrydine ((3E,5E)-3,5-dibenzylidene-8-phenyl-1,2,3,5,6,7-hexahydrodicyclopenta[ b,e ]pyridines) were developed and tested. Most of the investigated compositio...
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| Veröffentlicht in: | Journal of fluorescence 2010, Vol.20 (1), p.115-124 |
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| container_title | Journal of fluorescence |
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| creator | Grygorovych, Oleksiy V. Moskalenko, Sofia M. Marekha, Bogdan A. Doroshenko, Andrey O. |
| description | The new sensing materials based on the microsized silica gel powder with non-covalently immobilized structurally rigid analogs of 2,6-distyrylpyrydine ((3E,5E)-3,5-dibenzylidene-8-phenyl-1,2,3,5,6,7-hexahydrodicyclopenta[
b,e
]pyridines) were developed and tested. Most of the investigated compositions demonstrate linear ratiometric fluorescence response on
pH
in the physiologically important interval (
pH
6–9). The compound with the greatest number of protolytic centers within the studied series demonstrated the widest
pH
sensitivity range, however in this case the analytical signal was the lowest. The prospects for the practical application of the investigated materials in the fiber optics sensing devices were outlined. |
| doi_str_mv | 10.1007/s10895-009-0529-0 |
| format | Article |
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b,e
]pyridines) were developed and tested. Most of the investigated compositions demonstrate linear ratiometric fluorescence response on
pH
in the physiologically important interval (
pH
6–9). The compound with the greatest number of protolytic centers within the studied series demonstrated the widest
pH
sensitivity range, however in this case the analytical signal was the lowest. The prospects for the practical application of the investigated materials in the fiber optics sensing devices were outlined.</description><identifier>ISSN: 1053-0509</identifier><identifier>EISSN: 1573-4994</identifier><identifier>DOI: 10.1007/s10895-009-0529-0</identifier><identifier>PMID: 19685176</identifier><language>eng</language><publisher>Boston: Springer US</publisher><subject>Analogs ; Analytical Chemistry ; Biochemistry ; Biological and Medical Physics ; Biomedical and Life Sciences ; Biomedicine ; Biophysics ; Biotechnology ; Chemical Sciences ; Electrons ; Fiber optics ; Fluorescence ; Fluorescent Dyes - chemistry ; Hydrogen-Ion Concentration ; Mathematical analysis ; Optical fibers ; or physical chemistry ; Original Paper ; Pyridines - chemistry ; Sensing devices ; Silica gel ; Silicon Dioxide - chemistry ; Solubility ; Spectrometry, Fluorescence ; Surface Properties ; Theoretical and</subject><ispartof>Journal of fluorescence, 2010, Vol.20 (1), p.115-124</ispartof><rights>Springer Science+Business Media, LLC 2009</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c409t-4eb6cddc2ff30cb97086a0b30b03e93013e7e4b686d543b17b3aeb97576dfe633</citedby><cites>FETCH-LOGICAL-c409t-4eb6cddc2ff30cb97086a0b30b03e93013e7e4b686d543b17b3aeb97576dfe633</cites><orcidid>0000-0003-3142-8029</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10895-009-0529-0$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10895-009-0529-0$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>230,314,780,784,885,27923,27924,41487,42556,51318</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/19685176$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink><backlink>$$Uhttps://hal.science/hal-04045620$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Grygorovych, Oleksiy V.</creatorcontrib><creatorcontrib>Moskalenko, Sofia M.</creatorcontrib><creatorcontrib>Marekha, Bogdan A.</creatorcontrib><creatorcontrib>Doroshenko, Andrey O.</creatorcontrib><title>Heterogeneous Wide Range pH-sensing Materials Allowing Ratiometric Fluorescence Detection Based on Structurally Rigid Analogs of 2,6-distyrylpyridine</title><title>Journal of fluorescence</title><addtitle>J Fluoresc</addtitle><addtitle>J Fluoresc</addtitle><description>The new sensing materials based on the microsized silica gel powder with non-covalently immobilized structurally rigid analogs of 2,6-distyrylpyrydine ((3E,5E)-3,5-dibenzylidene-8-phenyl-1,2,3,5,6,7-hexahydrodicyclopenta[
b,e
]pyridines) were developed and tested. Most of the investigated compositions demonstrate linear ratiometric fluorescence response on
pH
in the physiologically important interval (
pH
6–9). The compound with the greatest number of protolytic centers within the studied series demonstrated the widest
pH
sensitivity range, however in this case the analytical signal was the lowest. The prospects for the practical application of the investigated materials in the fiber optics sensing devices were outlined.</description><subject>Analogs</subject><subject>Analytical Chemistry</subject><subject>Biochemistry</subject><subject>Biological and Medical Physics</subject><subject>Biomedical and Life Sciences</subject><subject>Biomedicine</subject><subject>Biophysics</subject><subject>Biotechnology</subject><subject>Chemical Sciences</subject><subject>Electrons</subject><subject>Fiber optics</subject><subject>Fluorescence</subject><subject>Fluorescent Dyes - chemistry</subject><subject>Hydrogen-Ion Concentration</subject><subject>Mathematical analysis</subject><subject>Optical fibers</subject><subject>or physical chemistry</subject><subject>Original Paper</subject><subject>Pyridines - chemistry</subject><subject>Sensing devices</subject><subject>Silica gel</subject><subject>Silicon Dioxide - chemistry</subject><subject>Solubility</subject><subject>Spectrometry, Fluorescence</subject><subject>Surface Properties</subject><subject>Theoretical and</subject><issn>1053-0509</issn><issn>1573-4994</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2010</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqFkcGO1DAMhisEYpeFB-CCckNIFJwmTZvjsLAM0iCkAcQxShO3ZJVphqQF9UF4XzJ0BDe4JJb9-XfivygeU3hBAZqXiUIr6xJAllBX-bhTXNK6YSWXkt_NMdQsV0BeFA9SuoUMtry9X1xQKdqaNuKy-LnFCWMYcMQwJ_LFWSR7PQ5Ijtsy4ZjcOJD3OjNO-0Q23ocfp9ReTy4ccIrOkBs_h4jJ4GiQvM56JtdG8kontCQHH6c4m2mO2vuF7N3gLNmM2ochkdCT6rkorUvTEhd_XKKzbsSHxb0-j8NH5_uq-Hzz5tP1ttx9ePvuerMrDQc5lRw7Yaw1Vd8zMJ1soBUaOgYdMJQMKMMGeSdaYWvOOtp0TGPG6kbYHgVjV8WzVfer9uoY3UHHRQXt1HazU6cccOC1qOA7zezTlT3G8G3GNKmDy3_2Xv9enZKVYFULjP-XbBiraSV5k0m6kiaGlCL2fx5BQZ0sVqvFKjunThYryD1Pzupzd0D7t-PsaQaqFUi5lJ2M6jbMMS88_UP1FzegsxE</recordid><startdate>2010</startdate><enddate>2010</enddate><creator>Grygorovych, Oleksiy V.</creator><creator>Moskalenko, Sofia M.</creator><creator>Marekha, Bogdan A.</creator><creator>Doroshenko, Andrey O.</creator><general>Springer US</general><general>Springer Verlag</general><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope><scope>1XC</scope><orcidid>https://orcid.org/0000-0003-3142-8029</orcidid></search><sort><creationdate>2010</creationdate><title>Heterogeneous Wide Range pH-sensing Materials Allowing Ratiometric Fluorescence Detection Based on Structurally Rigid Analogs of 2,6-distyrylpyridine</title><author>Grygorovych, Oleksiy V. ; Moskalenko, Sofia M. ; Marekha, Bogdan A. ; Doroshenko, Andrey O.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c409t-4eb6cddc2ff30cb97086a0b30b03e93013e7e4b686d543b17b3aeb97576dfe633</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2010</creationdate><topic>Analogs</topic><topic>Analytical Chemistry</topic><topic>Biochemistry</topic><topic>Biological and Medical Physics</topic><topic>Biomedical and Life Sciences</topic><topic>Biomedicine</topic><topic>Biophysics</topic><topic>Biotechnology</topic><topic>Chemical Sciences</topic><topic>Electrons</topic><topic>Fiber optics</topic><topic>Fluorescence</topic><topic>Fluorescent Dyes - chemistry</topic><topic>Hydrogen-Ion Concentration</topic><topic>Mathematical analysis</topic><topic>Optical fibers</topic><topic>or physical chemistry</topic><topic>Original Paper</topic><topic>Pyridines - chemistry</topic><topic>Sensing devices</topic><topic>Silica gel</topic><topic>Silicon Dioxide - chemistry</topic><topic>Solubility</topic><topic>Spectrometry, Fluorescence</topic><topic>Surface Properties</topic><topic>Theoretical and</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Grygorovych, Oleksiy V.</creatorcontrib><creatorcontrib>Moskalenko, Sofia M.</creatorcontrib><creatorcontrib>Marekha, Bogdan A.</creatorcontrib><creatorcontrib>Doroshenko, Andrey O.</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Hyper Article en Ligne (HAL)</collection><jtitle>Journal of fluorescence</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Grygorovych, Oleksiy V.</au><au>Moskalenko, Sofia M.</au><au>Marekha, Bogdan A.</au><au>Doroshenko, Andrey O.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Heterogeneous Wide Range pH-sensing Materials Allowing Ratiometric Fluorescence Detection Based on Structurally Rigid Analogs of 2,6-distyrylpyridine</atitle><jtitle>Journal of fluorescence</jtitle><stitle>J Fluoresc</stitle><addtitle>J Fluoresc</addtitle><date>2010</date><risdate>2010</risdate><volume>20</volume><issue>1</issue><spage>115</spage><epage>124</epage><pages>115-124</pages><issn>1053-0509</issn><eissn>1573-4994</eissn><abstract>The new sensing materials based on the microsized silica gel powder with non-covalently immobilized structurally rigid analogs of 2,6-distyrylpyrydine ((3E,5E)-3,5-dibenzylidene-8-phenyl-1,2,3,5,6,7-hexahydrodicyclopenta[
b,e
]pyridines) were developed and tested. Most of the investigated compositions demonstrate linear ratiometric fluorescence response on
pH
in the physiologically important interval (
pH
6–9). The compound with the greatest number of protolytic centers within the studied series demonstrated the widest
pH
sensitivity range, however in this case the analytical signal was the lowest. The prospects for the practical application of the investigated materials in the fiber optics sensing devices were outlined.</abstract><cop>Boston</cop><pub>Springer US</pub><pmid>19685176</pmid><doi>10.1007/s10895-009-0529-0</doi><tpages>10</tpages><orcidid>https://orcid.org/0000-0003-3142-8029</orcidid></addata></record> |
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| subjects | Analogs Analytical Chemistry Biochemistry Biological and Medical Physics Biomedical and Life Sciences Biomedicine Biophysics Biotechnology Chemical Sciences Electrons Fiber optics Fluorescence Fluorescent Dyes - chemistry Hydrogen-Ion Concentration Mathematical analysis Optical fibers or physical chemistry Original Paper Pyridines - chemistry Sensing devices Silica gel Silicon Dioxide - chemistry Solubility Spectrometry, Fluorescence Surface Properties Theoretical and |
| title | Heterogeneous Wide Range pH-sensing Materials Allowing Ratiometric Fluorescence Detection Based on Structurally Rigid Analogs of 2,6-distyrylpyridine |
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