Quantification of the hydride donor abilities of NADH, NADPH, and BH 3 CN - in water
The nucleophilic reactivities of the hydride donors NADH, NADPH, and BH CN in water were quantified using kinetic measurements with benzhydrylium ions as reference electrophiles. All three hydride donors were found to possess almost identical nucleophilic reactivities, providing a potential explanat...
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| Veröffentlicht in: | Organic & biomolecular chemistry 2022-12, Vol.21 (1), p.85-88 |
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| container_title | Organic & biomolecular chemistry |
| container_volume | 21 |
| creator | Mayer, Robert J Moran, Joseph |
| description | The nucleophilic reactivities of the hydride donors NADH, NADPH, and BH
CN
in water were quantified using kinetic measurements with benzhydrylium ions as reference electrophiles. All three hydride donors were found to possess almost identical nucleophilic reactivities, providing a potential explanation for why they are involved in similar transformations in biochemistry and organic synthesis, respectively. |
| doi_str_mv | 10.1039/d2ob02041f |
| format | Article |
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| fulltext | fulltext |
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| ispartof | Organic & biomolecular chemistry, 2022-12, Vol.21 (1), p.85-88 |
| issn | 1477-0520 1477-0539 |
| language | eng |
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| source | MEDLINE; Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Chemical Sciences Ions Kinetics NAD NADP - metabolism Organic chemistry Water |
| title | Quantification of the hydride donor abilities of NADH, NADPH, and BH 3 CN - in water |
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