Low-Temperature Magnetic Force Microscopy on Single Molecule Magnet-Based Microarrays
The magnetic properties of some single molecule magnets (SMM) on surfaces can be strongly modified by the molecular packing in nanometric films/aggregates or by interactions with the substrate, which affect the molecular orientation and geometry. Detailed investigations of the magnetism of thin SMM...
Gespeichert in:
| Veröffentlicht in: | Nano letters 2017-03, Vol.17 (3), p.1899-1905 |
|---|---|
| Hauptverfasser: | , , , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 1905 |
|---|---|
| container_issue | 3 |
| container_start_page | 1899 |
| container_title | Nano letters |
| container_volume | 17 |
| creator | Serri, Michele Mannini, Matteo Poggini, Lorenzo Vélez-Fort, Emilio Cortigiani, Brunetto Sainctavit, Philippe Rovai, Donella Caneschi, Andrea Sessoli, Roberta |
| description | The magnetic properties of some single molecule magnets (SMM) on surfaces can be strongly modified by the molecular packing in nanometric films/aggregates or by interactions with the substrate, which affect the molecular orientation and geometry. Detailed investigations of the magnetism of thin SMM films and nanostructures are necessary for the development of spin-based molecular devices, however this task is challenged by the limited sensitivity of laboratory-based magnetometric techniques and often requires access to synchrotron light sources to perform surface sensitive X-ray magnetic circular dichroism (XMCD) investigations. Here we show that low-temperature magnetic force microscopy is an alternative powerful laboratory tool able to extract the field dependence of the magnetization and to identify areas of in-plane and perpendicular magnetic anisotropy in microarrays of the SMM terbium(III) bis-phthalocyaninato (TbPc2) neutral complex grown as nanosized films on SiO2 and perylene-3,4,9,10-tetracarboxylic dianhydride (PTCDA), and this is in agreement with data extracted from nonlocal XMCD measurements performed on homogeneous TbPc2/PTCDA films. |
| doi_str_mv | 10.1021/acs.nanolett.6b05208 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_hal_p</sourceid><recordid>TN_cdi_hal_primary_oai_HAL_hal_03989116v1</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1888966836</sourcerecordid><originalsourceid>FETCH-LOGICAL-a560t-fb40ff8c5eab3494caa9036526539b0070d1e317a7378e914c7957f6dfadde393</originalsourceid><addsrcrecordid>eNqNkctOwzAQRS0EoqXwBwh1CYuUcZw49rJUvKQiFpS1NXEcSJXGxU5A_Xtcpe0SsZqHzp0ZzSXkksKEQkxvUftJg42tTdtOeA5pDOKIDGnKIOJSxseHXCQDcub9EgAkS-GUDGJBeRonckje5_YnWpjV2jhsO2fGL_jRmLbS4wfrdCgr7azXdr0Z22b8VjUfdWiGpbqr93B0h94UPYrO4cafk5MSa28udnFE3h_uF7OnaP76-DybziNMObRRmSdQlkKnBnOWyEQjSmDhMp4ymQNkUFDDaIYZy4SRNNGZTLOSFyUWhWGSjchNP_cTa7V21QrdRlms1NN0rrY9YFJISvk3Dex1z66d_eqMb9Wq8trUNTbGdl5RIZkQmcjgH6gQknPBeECTHt2-yTtTHs6goLY-qeCT2vukdj4F2dVuQ5evTHEQ7Y0JAPTAVr60nWvCH_-e-QvkcqFk</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1888966836</pqid></control><display><type>article</type><title>Low-Temperature Magnetic Force Microscopy on Single Molecule Magnet-Based Microarrays</title><source>ACS Publications</source><creator>Serri, Michele ; Mannini, Matteo ; Poggini, Lorenzo ; Vélez-Fort, Emilio ; Cortigiani, Brunetto ; Sainctavit, Philippe ; Rovai, Donella ; Caneschi, Andrea ; Sessoli, Roberta</creator><creatorcontrib>Serri, Michele ; Mannini, Matteo ; Poggini, Lorenzo ; Vélez-Fort, Emilio ; Cortigiani, Brunetto ; Sainctavit, Philippe ; Rovai, Donella ; Caneschi, Andrea ; Sessoli, Roberta</creatorcontrib><description>The magnetic properties of some single molecule magnets (SMM) on surfaces can be strongly modified by the molecular packing in nanometric films/aggregates or by interactions with the substrate, which affect the molecular orientation and geometry. Detailed investigations of the magnetism of thin SMM films and nanostructures are necessary for the development of spin-based molecular devices, however this task is challenged by the limited sensitivity of laboratory-based magnetometric techniques and often requires access to synchrotron light sources to perform surface sensitive X-ray magnetic circular dichroism (XMCD) investigations. Here we show that low-temperature magnetic force microscopy is an alternative powerful laboratory tool able to extract the field dependence of the magnetization and to identify areas of in-plane and perpendicular magnetic anisotropy in microarrays of the SMM terbium(III) bis-phthalocyaninato (TbPc2) neutral complex grown as nanosized films on SiO2 and perylene-3,4,9,10-tetracarboxylic dianhydride (PTCDA), and this is in agreement with data extracted from nonlocal XMCD measurements performed on homogeneous TbPc2/PTCDA films.</description><identifier>ISSN: 1530-6984</identifier><identifier>EISSN: 1530-6992</identifier><identifier>DOI: 10.1021/acs.nanolett.6b05208</identifier><identifier>PMID: 28165249</identifier><language>eng</language><publisher>United States: American Chemical Society</publisher><subject>Condensed Matter ; Devices ; Engineering Sciences ; Magnetic anisotropy ; Magnetic fields ; Magnetism ; Magnetization ; Micro and nanotechnologies ; Microelectronics ; Microscopy ; Nanostructure ; Patterning ; Physics</subject><ispartof>Nano letters, 2017-03, Vol.17 (3), p.1899-1905</ispartof><rights>Copyright © 2017 American Chemical Society</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a560t-fb40ff8c5eab3494caa9036526539b0070d1e317a7378e914c7957f6dfadde393</citedby><cites>FETCH-LOGICAL-a560t-fb40ff8c5eab3494caa9036526539b0070d1e317a7378e914c7957f6dfadde393</cites><orcidid>0000-0003-3783-2700 ; 0000-0001-7549-2124 ; 0000-0002-6018-5284</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/acs.nanolett.6b05208$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/acs.nanolett.6b05208$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>230,314,780,784,885,2765,27076,27924,27925,56738,56788</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/28165249$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink><backlink>$$Uhttps://cnrs.hal.science/hal-03989116$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Serri, Michele</creatorcontrib><creatorcontrib>Mannini, Matteo</creatorcontrib><creatorcontrib>Poggini, Lorenzo</creatorcontrib><creatorcontrib>Vélez-Fort, Emilio</creatorcontrib><creatorcontrib>Cortigiani, Brunetto</creatorcontrib><creatorcontrib>Sainctavit, Philippe</creatorcontrib><creatorcontrib>Rovai, Donella</creatorcontrib><creatorcontrib>Caneschi, Andrea</creatorcontrib><creatorcontrib>Sessoli, Roberta</creatorcontrib><title>Low-Temperature Magnetic Force Microscopy on Single Molecule Magnet-Based Microarrays</title><title>Nano letters</title><addtitle>Nano Lett</addtitle><description>The magnetic properties of some single molecule magnets (SMM) on surfaces can be strongly modified by the molecular packing in nanometric films/aggregates or by interactions with the substrate, which affect the molecular orientation and geometry. Detailed investigations of the magnetism of thin SMM films and nanostructures are necessary for the development of spin-based molecular devices, however this task is challenged by the limited sensitivity of laboratory-based magnetometric techniques and often requires access to synchrotron light sources to perform surface sensitive X-ray magnetic circular dichroism (XMCD) investigations. Here we show that low-temperature magnetic force microscopy is an alternative powerful laboratory tool able to extract the field dependence of the magnetization and to identify areas of in-plane and perpendicular magnetic anisotropy in microarrays of the SMM terbium(III) bis-phthalocyaninato (TbPc2) neutral complex grown as nanosized films on SiO2 and perylene-3,4,9,10-tetracarboxylic dianhydride (PTCDA), and this is in agreement with data extracted from nonlocal XMCD measurements performed on homogeneous TbPc2/PTCDA films.</description><subject>Condensed Matter</subject><subject>Devices</subject><subject>Engineering Sciences</subject><subject>Magnetic anisotropy</subject><subject>Magnetic fields</subject><subject>Magnetism</subject><subject>Magnetization</subject><subject>Micro and nanotechnologies</subject><subject>Microelectronics</subject><subject>Microscopy</subject><subject>Nanostructure</subject><subject>Patterning</subject><subject>Physics</subject><issn>1530-6984</issn><issn>1530-6992</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNqNkctOwzAQRS0EoqXwBwh1CYuUcZw49rJUvKQiFpS1NXEcSJXGxU5A_Xtcpe0SsZqHzp0ZzSXkksKEQkxvUftJg42tTdtOeA5pDOKIDGnKIOJSxseHXCQDcub9EgAkS-GUDGJBeRonckje5_YnWpjV2jhsO2fGL_jRmLbS4wfrdCgr7azXdr0Z22b8VjUfdWiGpbqr93B0h94UPYrO4cafk5MSa28udnFE3h_uF7OnaP76-DybziNMObRRmSdQlkKnBnOWyEQjSmDhMp4ymQNkUFDDaIYZy4SRNNGZTLOSFyUWhWGSjchNP_cTa7V21QrdRlms1NN0rrY9YFJISvk3Dex1z66d_eqMb9Wq8trUNTbGdl5RIZkQmcjgH6gQknPBeECTHt2-yTtTHs6goLY-qeCT2vukdj4F2dVuQ5evTHEQ7Y0JAPTAVr60nWvCH_-e-QvkcqFk</recordid><startdate>20170308</startdate><enddate>20170308</enddate><creator>Serri, Michele</creator><creator>Mannini, Matteo</creator><creator>Poggini, Lorenzo</creator><creator>Vélez-Fort, Emilio</creator><creator>Cortigiani, Brunetto</creator><creator>Sainctavit, Philippe</creator><creator>Rovai, Donella</creator><creator>Caneschi, Andrea</creator><creator>Sessoli, Roberta</creator><general>American Chemical Society</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QO</scope><scope>8FD</scope><scope>FR3</scope><scope>P64</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>JG9</scope><scope>L7M</scope><scope>1XC</scope><scope>VOOES</scope><orcidid>https://orcid.org/0000-0003-3783-2700</orcidid><orcidid>https://orcid.org/0000-0001-7549-2124</orcidid><orcidid>https://orcid.org/0000-0002-6018-5284</orcidid></search><sort><creationdate>20170308</creationdate><title>Low-Temperature Magnetic Force Microscopy on Single Molecule Magnet-Based Microarrays</title><author>Serri, Michele ; Mannini, Matteo ; Poggini, Lorenzo ; Vélez-Fort, Emilio ; Cortigiani, Brunetto ; Sainctavit, Philippe ; Rovai, Donella ; Caneschi, Andrea ; Sessoli, Roberta</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a560t-fb40ff8c5eab3494caa9036526539b0070d1e317a7378e914c7957f6dfadde393</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Condensed Matter</topic><topic>Devices</topic><topic>Engineering Sciences</topic><topic>Magnetic anisotropy</topic><topic>Magnetic fields</topic><topic>Magnetism</topic><topic>Magnetization</topic><topic>Micro and nanotechnologies</topic><topic>Microelectronics</topic><topic>Microscopy</topic><topic>Nanostructure</topic><topic>Patterning</topic><topic>Physics</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Serri, Michele</creatorcontrib><creatorcontrib>Mannini, Matteo</creatorcontrib><creatorcontrib>Poggini, Lorenzo</creatorcontrib><creatorcontrib>Vélez-Fort, Emilio</creatorcontrib><creatorcontrib>Cortigiani, Brunetto</creatorcontrib><creatorcontrib>Sainctavit, Philippe</creatorcontrib><creatorcontrib>Rovai, Donella</creatorcontrib><creatorcontrib>Caneschi, Andrea</creatorcontrib><creatorcontrib>Sessoli, Roberta</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Biotechnology Research Abstracts</collection><collection>Technology Research Database</collection><collection>Engineering Research Database</collection><collection>Biotechnology and BioEngineering Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Hyper Article en Ligne (HAL)</collection><collection>Hyper Article en Ligne (HAL) (Open Access)</collection><jtitle>Nano letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Serri, Michele</au><au>Mannini, Matteo</au><au>Poggini, Lorenzo</au><au>Vélez-Fort, Emilio</au><au>Cortigiani, Brunetto</au><au>Sainctavit, Philippe</au><au>Rovai, Donella</au><au>Caneschi, Andrea</au><au>Sessoli, Roberta</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Low-Temperature Magnetic Force Microscopy on Single Molecule Magnet-Based Microarrays</atitle><jtitle>Nano letters</jtitle><addtitle>Nano Lett</addtitle><date>2017-03-08</date><risdate>2017</risdate><volume>17</volume><issue>3</issue><spage>1899</spage><epage>1905</epage><pages>1899-1905</pages><issn>1530-6984</issn><eissn>1530-6992</eissn><abstract>The magnetic properties of some single molecule magnets (SMM) on surfaces can be strongly modified by the molecular packing in nanometric films/aggregates or by interactions with the substrate, which affect the molecular orientation and geometry. Detailed investigations of the magnetism of thin SMM films and nanostructures are necessary for the development of spin-based molecular devices, however this task is challenged by the limited sensitivity of laboratory-based magnetometric techniques and often requires access to synchrotron light sources to perform surface sensitive X-ray magnetic circular dichroism (XMCD) investigations. Here we show that low-temperature magnetic force microscopy is an alternative powerful laboratory tool able to extract the field dependence of the magnetization and to identify areas of in-plane and perpendicular magnetic anisotropy in microarrays of the SMM terbium(III) bis-phthalocyaninato (TbPc2) neutral complex grown as nanosized films on SiO2 and perylene-3,4,9,10-tetracarboxylic dianhydride (PTCDA), and this is in agreement with data extracted from nonlocal XMCD measurements performed on homogeneous TbPc2/PTCDA films.</abstract><cop>United States</cop><pub>American Chemical Society</pub><pmid>28165249</pmid><doi>10.1021/acs.nanolett.6b05208</doi><tpages>7</tpages><orcidid>https://orcid.org/0000-0003-3783-2700</orcidid><orcidid>https://orcid.org/0000-0001-7549-2124</orcidid><orcidid>https://orcid.org/0000-0002-6018-5284</orcidid><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1530-6984 |
| ispartof | Nano letters, 2017-03, Vol.17 (3), p.1899-1905 |
| issn | 1530-6984 1530-6992 |
| language | eng |
| recordid | cdi_hal_primary_oai_HAL_hal_03989116v1 |
| source | ACS Publications |
| subjects | Condensed Matter Devices Engineering Sciences Magnetic anisotropy Magnetic fields Magnetism Magnetization Micro and nanotechnologies Microelectronics Microscopy Nanostructure Patterning Physics |
| title | Low-Temperature Magnetic Force Microscopy on Single Molecule Magnet-Based Microarrays |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-07T02%3A21%3A34IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_hal_p&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Low-Temperature%20Magnetic%20Force%20Microscopy%20on%20Single%20Molecule%20Magnet-Based%20Microarrays&rft.jtitle=Nano%20letters&rft.au=Serri,%20Michele&rft.date=2017-03-08&rft.volume=17&rft.issue=3&rft.spage=1899&rft.epage=1905&rft.pages=1899-1905&rft.issn=1530-6984&rft.eissn=1530-6992&rft_id=info:doi/10.1021/acs.nanolett.6b05208&rft_dat=%3Cproquest_hal_p%3E1888966836%3C/proquest_hal_p%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1888966836&rft_id=info:pmid/28165249&rfr_iscdi=true |