Adsorption mechanism of quaternary ammonium corrosion inhibitor on carbon steel surface using ToF-SIMS and XPS
ToF-SIMS and XPS are combined to study the adsorption of tetradecyl-benzyldimethyl-ammonium (BDA-C14) bromide corrosion inhibitor on carbon steel surface. BDA-C14 forms a protective layer with N-containing polar head group interacting with carbon steel surface. The adsorbed inhibitor surface coverag...
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| Veröffentlicht in: | Corrosion science 2023-04, Vol.213, p.110952, Article 110952 |
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| container_title | Corrosion science |
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| creator | Wang, Luntao Wang, Huiru Seyeux, Antoine Zanna, Sandrine Pailleret, Alain Nesic, Srdjan Marcus, Philippe |
| description | ToF-SIMS and XPS are combined to study the adsorption of tetradecyl-benzyldimethyl-ammonium (BDA-C14) bromide corrosion inhibitor on carbon steel surface. BDA-C14 forms a protective layer with N-containing polar head group interacting with carbon steel surface. The adsorbed inhibitor surface coverage strongly depends on immersion time and inhibitor concentration. A maximum and uniform coverage is found for sufficiently long exposure times at a critical inhibitor concentration of about 25 ppmw. The uniform adsorbed inhibitor layer formed on the surface mitigates the formation of iron chloride/hydroxide intermediates and thus enhances the corrosion protection of carbon steel in aggressive environment.
•The adsorption of BDA-C14 corrosion inhibitor on carbon steel surface was studied by ToF-SIMS and XPS.•The inhibitor forms a protective layer with N-containing polar head group interacting with carbon steel surface.•The adsorbed inhibitor surface coverage strongly depends on immersion time and inhibitor concentration.•The critical concentration for a maximum and uniformed inhibitor coverage on carbon steel is determined.•The uniform adsorbed inhibitor layer on carbon steel can mitigate the formation of iron chloride/hydroxide intermediates. |
| doi_str_mv | 10.1016/j.corsci.2022.110952 |
| format | Article |
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•The adsorption of BDA-C14 corrosion inhibitor on carbon steel surface was studied by ToF-SIMS and XPS.•The inhibitor forms a protective layer with N-containing polar head group interacting with carbon steel surface.•The adsorbed inhibitor surface coverage strongly depends on immersion time and inhibitor concentration.•The critical concentration for a maximum and uniformed inhibitor coverage on carbon steel is determined.•The uniform adsorbed inhibitor layer on carbon steel can mitigate the formation of iron chloride/hydroxide intermediates.</description><identifier>ISSN: 0010-938X</identifier><identifier>EISSN: 1879-0496</identifier><identifier>DOI: 10.1016/j.corsci.2022.110952</identifier><language>eng</language><publisher>Elsevier Ltd</publisher><subject>Carbon steel ; Chemical Sciences ; CO2 corrosion ; Corrosion inhibitor ; Quaternary ammonium ; ToF-SIMS ; XPS</subject><ispartof>Corrosion science, 2023-04, Vol.213, p.110952, Article 110952</ispartof><rights>2023 Elsevier Ltd</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c386t-2e4007888aa6ccb1549194862bcdef18a7224717a766aad1b096c44323db63a3</citedby><cites>FETCH-LOGICAL-c386t-2e4007888aa6ccb1549194862bcdef18a7224717a766aad1b096c44323db63a3</cites><orcidid>0000-0002-9140-0047 ; 0000-0002-4296-4188 ; 0000-0002-3062-8961</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0010938X22008708$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>230,314,776,780,881,3537,27901,27902,65306</link.rule.ids><backlink>$$Uhttps://cnrs.hal.science/hal-03969214$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Wang, Luntao</creatorcontrib><creatorcontrib>Wang, Huiru</creatorcontrib><creatorcontrib>Seyeux, Antoine</creatorcontrib><creatorcontrib>Zanna, Sandrine</creatorcontrib><creatorcontrib>Pailleret, Alain</creatorcontrib><creatorcontrib>Nesic, Srdjan</creatorcontrib><creatorcontrib>Marcus, Philippe</creatorcontrib><title>Adsorption mechanism of quaternary ammonium corrosion inhibitor on carbon steel surface using ToF-SIMS and XPS</title><title>Corrosion science</title><description>ToF-SIMS and XPS are combined to study the adsorption of tetradecyl-benzyldimethyl-ammonium (BDA-C14) bromide corrosion inhibitor on carbon steel surface. BDA-C14 forms a protective layer with N-containing polar head group interacting with carbon steel surface. The adsorbed inhibitor surface coverage strongly depends on immersion time and inhibitor concentration. A maximum and uniform coverage is found for sufficiently long exposure times at a critical inhibitor concentration of about 25 ppmw. The uniform adsorbed inhibitor layer formed on the surface mitigates the formation of iron chloride/hydroxide intermediates and thus enhances the corrosion protection of carbon steel in aggressive environment.
•The adsorption of BDA-C14 corrosion inhibitor on carbon steel surface was studied by ToF-SIMS and XPS.•The inhibitor forms a protective layer with N-containing polar head group interacting with carbon steel surface.•The adsorbed inhibitor surface coverage strongly depends on immersion time and inhibitor concentration.•The critical concentration for a maximum and uniformed inhibitor coverage on carbon steel is determined.•The uniform adsorbed inhibitor layer on carbon steel can mitigate the formation of iron chloride/hydroxide intermediates.</description><subject>Carbon steel</subject><subject>Chemical Sciences</subject><subject>CO2 corrosion</subject><subject>Corrosion inhibitor</subject><subject>Quaternary ammonium</subject><subject>ToF-SIMS</subject><subject>XPS</subject><issn>0010-938X</issn><issn>1879-0496</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNp9UMFKAzEUDKJgrf6Bh1w9bE2yaXZzEUpRW6gotIfewtts1qZ0k5rsFvx7U1Y8ehreMDOPGYTuKZlQQsXjfqJ9iNpOGGFsQimRU3aBRrQsZEa4FJdoRAglmczL7TW6iXFPCGGJGSE3q6MPx856h1ujd-BsbLFv8FcPnQkOwjeGtvXO9i1OX4KPZ6l1O1vZzgecDg2hShA7Yw449qEBbXAfrfvEG_-SrZdvawyuxtuP9S26auAQzd0vjtHm5XkzX2Sr99flfLbKdF6KLmOGE1KUZQkgtK7olEsqeSlYpWvT0BIKxnhBCyiEAKhpRaTQnOcsryuRQz5GD0PsDg7qGGybaigPVi1mK3XmSC6FZJSfaNLyQatTtxhM82egRJ3nVXs1zKvO86ph3mR7Gmwm1ThZE1RSGKdNbYPRnaq9_T_gB-AbhaA</recordid><startdate>20230401</startdate><enddate>20230401</enddate><creator>Wang, Luntao</creator><creator>Wang, Huiru</creator><creator>Seyeux, Antoine</creator><creator>Zanna, Sandrine</creator><creator>Pailleret, Alain</creator><creator>Nesic, Srdjan</creator><creator>Marcus, Philippe</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>AAYXX</scope><scope>CITATION</scope><scope>1XC</scope><scope>VOOES</scope><orcidid>https://orcid.org/0000-0002-9140-0047</orcidid><orcidid>https://orcid.org/0000-0002-4296-4188</orcidid><orcidid>https://orcid.org/0000-0002-3062-8961</orcidid></search><sort><creationdate>20230401</creationdate><title>Adsorption mechanism of quaternary ammonium corrosion inhibitor on carbon steel surface using ToF-SIMS and XPS</title><author>Wang, Luntao ; Wang, Huiru ; Seyeux, Antoine ; Zanna, Sandrine ; Pailleret, Alain ; Nesic, Srdjan ; Marcus, Philippe</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c386t-2e4007888aa6ccb1549194862bcdef18a7224717a766aad1b096c44323db63a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Carbon steel</topic><topic>Chemical Sciences</topic><topic>CO2 corrosion</topic><topic>Corrosion inhibitor</topic><topic>Quaternary ammonium</topic><topic>ToF-SIMS</topic><topic>XPS</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wang, Luntao</creatorcontrib><creatorcontrib>Wang, Huiru</creatorcontrib><creatorcontrib>Seyeux, Antoine</creatorcontrib><creatorcontrib>Zanna, Sandrine</creatorcontrib><creatorcontrib>Pailleret, Alain</creatorcontrib><creatorcontrib>Nesic, Srdjan</creatorcontrib><creatorcontrib>Marcus, Philippe</creatorcontrib><collection>CrossRef</collection><collection>Hyper Article en Ligne (HAL)</collection><collection>Hyper Article en Ligne (HAL) (Open Access)</collection><jtitle>Corrosion science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wang, Luntao</au><au>Wang, Huiru</au><au>Seyeux, Antoine</au><au>Zanna, Sandrine</au><au>Pailleret, Alain</au><au>Nesic, Srdjan</au><au>Marcus, Philippe</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Adsorption mechanism of quaternary ammonium corrosion inhibitor on carbon steel surface using ToF-SIMS and XPS</atitle><jtitle>Corrosion science</jtitle><date>2023-04-01</date><risdate>2023</risdate><volume>213</volume><spage>110952</spage><pages>110952-</pages><artnum>110952</artnum><issn>0010-938X</issn><eissn>1879-0496</eissn><abstract>ToF-SIMS and XPS are combined to study the adsorption of tetradecyl-benzyldimethyl-ammonium (BDA-C14) bromide corrosion inhibitor on carbon steel surface. BDA-C14 forms a protective layer with N-containing polar head group interacting with carbon steel surface. The adsorbed inhibitor surface coverage strongly depends on immersion time and inhibitor concentration. A maximum and uniform coverage is found for sufficiently long exposure times at a critical inhibitor concentration of about 25 ppmw. The uniform adsorbed inhibitor layer formed on the surface mitigates the formation of iron chloride/hydroxide intermediates and thus enhances the corrosion protection of carbon steel in aggressive environment.
•The adsorption of BDA-C14 corrosion inhibitor on carbon steel surface was studied by ToF-SIMS and XPS.•The inhibitor forms a protective layer with N-containing polar head group interacting with carbon steel surface.•The adsorbed inhibitor surface coverage strongly depends on immersion time and inhibitor concentration.•The critical concentration for a maximum and uniformed inhibitor coverage on carbon steel is determined.•The uniform adsorbed inhibitor layer on carbon steel can mitigate the formation of iron chloride/hydroxide intermediates.</abstract><pub>Elsevier Ltd</pub><doi>10.1016/j.corsci.2022.110952</doi><orcidid>https://orcid.org/0000-0002-9140-0047</orcidid><orcidid>https://orcid.org/0000-0002-4296-4188</orcidid><orcidid>https://orcid.org/0000-0002-3062-8961</orcidid><oa>free_for_read</oa></addata></record> |
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| subjects | Carbon steel Chemical Sciences CO2 corrosion Corrosion inhibitor Quaternary ammonium ToF-SIMS XPS |
| title | Adsorption mechanism of quaternary ammonium corrosion inhibitor on carbon steel surface using ToF-SIMS and XPS |
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