Bioinspired Heterobimetallic Photocatalyst (RuII chrom−FeIII cat ) for Visible-Light-Driven C–H Oxidation of Organic Substrates via Dioxygen Activation

We report a bioinspired heterobimetallic photocatalyst Ru II chrom –Fe III cat and its relevant applications toward visible-light-driven C–H bond oxidation of a series of hydrocarbons using O2 as the O-atom source. The RuII center absorbs visible light near 460 nm and triggers a cascade of electrons...

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Veröffentlicht in:	Inorganic chemistry 2021-11, Vol.60 (21), p.16059-16064
Hauptverfasser:	Singh, Siddhant, Nautiyal, Divyanshu, Thetiot, Franck, Le Poul, Nicolas, Goswami, Tapas, Kumar, Arun, Kumar, Sushil
Format:	Artikel
Sprache:	eng
Schlagworte:	Catalysis Chemical Sciences Chromium - chemistry Coordination chemistry Coordination Complexes - chemical synthesis Coordination Complexes - chemistry Hydrocarbons - chemistry Light Molecular Structure Organic chemistry Oxidation-Reduction Oxygen - chemistry Photochemical Processes Ruthenium - chemistry
Online-Zugang:	Volltext
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