Phenoxy-Amidine Ligands: Toward Lactic Acid-Tolerant Catalysts for Lactide Ring-Opening Polymerization

The replacement of the imine functionality in the ubiquitous phenoxy-imine (FI) ligands by a more robust and donor N,N,N′-trisubstituted amidine function was examined and gave rise to the synthesis of five new phenoxy-amidine (FA) ligands (L1–L5). The solid-state structure of four proligands has bee...

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Veröffentlicht in:Organometallics 2022-11, Vol.41 (21), p.2920-2932
Hauptverfasser: Vaillant-Coindard, Valentin, Théron, Benjamin, Printz, Gaël, Chotard, Florian, Balan, Cédric, Rousselin, Yoann, Richard, Philippe, Tolbatov, Iogann, Fleurat-Lessard, Paul, Bodio, Ewen, Malacea-Kabbara, Raluca, Bayardon, Jérôme, Dagorne, Samuel, Le Gendre, Pierre
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Sprache:eng
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