Ultrafast time-resolved spectroscopy elucidating photo-driven electron and energy transfer processes in a broadband light-absorbing BODIPY-C60-distyryl BODIPY triad
Photoinduced electron and energy transfer pathways are elucidated in a panchromatic light-absorbing, covalently linked triad (BODIPY-C 60 -distyryl BODIPY, noted as BDP-C 60 -DSBDP) along with the two reference dyads: BODIPY-C 60 (BDP-C 60 ) and distyryl-BODIPY-C 60 (DSBDP-C 60 ). The flexible linke...
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| Veröffentlicht in: | The European physical journal. ST, Special topics Special topics, 2023-09, Vol.232 (13), p.2131-2144 |
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| creator | Fatima, A. Rabah, J. Allard, E. Fensterbank, H. Wright, K. Burdzinski, G. Miomandre, F. Pham, J. Clavier, G. Sliwa, M. Pino, T. Méallet-Renault, R. Steenkeste, K. Ha-Thi, M. H. |
| description | Photoinduced electron and energy transfer pathways are elucidated in a panchromatic light-absorbing, covalently linked triad (BODIPY-C
60
-distyryl BODIPY, noted as BDP-C
60
-DSBDP) along with the two reference dyads: BODIPY-C
60
(BDP-C
60
) and distyryl-BODIPY-C
60
(DSBDP-C
60
). The flexible linker between the BODIPY and C
60
units leads to different possible conformations with varying donor–acceptor distances. Ultrafast transient absorption along with the time-resolved emission spectroscopies revealed the occurrence of different photoinduced electron/energy transfer processes in these conformers. Photoexcitation of the BODIPY units in the two reference dyads leads to one electron and two energy transfer steps from BODIPY to C
60
. However, in the BDP-C
60
-DSBDP triad, additional energy transfer processes from BDP to DSBDP were evidenced upon photoexcitation of the BDP unit. The singlet excited state of DSBDP in the triad then follows the same relaxation route as that of the DSBDP-C
60
dyad. The intricate photophysics, particularly the formation of radical ion pairs in these flexible covalently linked donor–acceptor systems contribute to our fundamental understanding of electron and energy transfer mechanisms, which is important to build donor–acceptor assemblies for energy applications.
Graphical abstract |
| doi_str_mv | 10.1140/epjs/s11734-022-00670-y |
| format | Article |
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60
-distyryl BODIPY, noted as BDP-C
60
-DSBDP) along with the two reference dyads: BODIPY-C
60
(BDP-C
60
) and distyryl-BODIPY-C
60
(DSBDP-C
60
). The flexible linker between the BODIPY and C
60
units leads to different possible conformations with varying donor–acceptor distances. Ultrafast transient absorption along with the time-resolved emission spectroscopies revealed the occurrence of different photoinduced electron/energy transfer processes in these conformers. Photoexcitation of the BODIPY units in the two reference dyads leads to one electron and two energy transfer steps from BODIPY to C
60
. However, in the BDP-C
60
-DSBDP triad, additional energy transfer processes from BDP to DSBDP were evidenced upon photoexcitation of the BDP unit. The singlet excited state of DSBDP in the triad then follows the same relaxation route as that of the DSBDP-C
60
dyad. The intricate photophysics, particularly the formation of radical ion pairs in these flexible covalently linked donor–acceptor systems contribute to our fundamental understanding of electron and energy transfer mechanisms, which is important to build donor–acceptor assemblies for energy applications.
Graphical abstract</description><identifier>ISSN: 1951-6355</identifier><identifier>EISSN: 1951-6401</identifier><identifier>DOI: 10.1140/epjs/s11734-022-00670-y</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Atomic ; Broadband ; Chemical Sciences ; Classical and Continuum Physics ; Condensed Matter Physics ; Construction standards ; Electromagnetic absorption ; Energy ; Energy transfer ; Ion pairs ; Materials Science ; Measurement Science and Instrumentation ; Molecular ; Optical and Plasma Physics ; Photoexcitation ; Physics ; Physics and Astronomy ; Regular Article ; Ultrafast Phenomena from attosecond to picosecond timescales: theory and experiments</subject><ispartof>The European physical journal. ST, Special topics, 2023-09, Vol.232 (13), p.2131-2144</ispartof><rights>The Author(s), under exclusive licence to EDP Sciences, Springer-Verlag GmbH Germany, part of Springer Nature 2022. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c417t-95dbcfa8186646ca713b96de4f925d3b1fe22043ca2ddbdbbc0ecf73152e034a3</citedby><cites>FETCH-LOGICAL-c417t-95dbcfa8186646ca713b96de4f925d3b1fe22043ca2ddbdbbc0ecf73152e034a3</cites><orcidid>0000-0003-3276-1843 ; 0000-0001-7301-8082 ; 0000-0001-6842-0907 ; 0000-0002-1083-6288 ; 0000-0002-2947-1602 ; 0000-0002-3217-3876 ; 0000-0002-5073-8180 ; 0000-0002-1646-7866 ; 0000-0002-7895-9954 ; 0000-0003-2001-9473 ; 0000-0001-7175-7236 ; 0000-0002-2890-6328</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1140/epjs/s11734-022-00670-y$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1140/epjs/s11734-022-00670-y$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>230,314,780,784,885,27924,27925,41488,42557,51319</link.rule.ids><backlink>$$Uhttps://hal.science/hal-03840392$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Fatima, A.</creatorcontrib><creatorcontrib>Rabah, J.</creatorcontrib><creatorcontrib>Allard, E.</creatorcontrib><creatorcontrib>Fensterbank, H.</creatorcontrib><creatorcontrib>Wright, K.</creatorcontrib><creatorcontrib>Burdzinski, G.</creatorcontrib><creatorcontrib>Miomandre, F.</creatorcontrib><creatorcontrib>Pham, J.</creatorcontrib><creatorcontrib>Clavier, G.</creatorcontrib><creatorcontrib>Sliwa, M.</creatorcontrib><creatorcontrib>Pino, T.</creatorcontrib><creatorcontrib>Méallet-Renault, R.</creatorcontrib><creatorcontrib>Steenkeste, K.</creatorcontrib><creatorcontrib>Ha-Thi, M. H.</creatorcontrib><title>Ultrafast time-resolved spectroscopy elucidating photo-driven electron and energy transfer processes in a broadband light-absorbing BODIPY-C60-distyryl BODIPY triad</title><title>The European physical journal. ST, Special topics</title><addtitle>Eur. Phys. J. Spec. Top</addtitle><description>Photoinduced electron and energy transfer pathways are elucidated in a panchromatic light-absorbing, covalently linked triad (BODIPY-C
60
-distyryl BODIPY, noted as BDP-C
60
-DSBDP) along with the two reference dyads: BODIPY-C
60
(BDP-C
60
) and distyryl-BODIPY-C
60
(DSBDP-C
60
). The flexible linker between the BODIPY and C
60
units leads to different possible conformations with varying donor–acceptor distances. Ultrafast transient absorption along with the time-resolved emission spectroscopies revealed the occurrence of different photoinduced electron/energy transfer processes in these conformers. Photoexcitation of the BODIPY units in the two reference dyads leads to one electron and two energy transfer steps from BODIPY to C
60
. However, in the BDP-C
60
-DSBDP triad, additional energy transfer processes from BDP to DSBDP were evidenced upon photoexcitation of the BDP unit. The singlet excited state of DSBDP in the triad then follows the same relaxation route as that of the DSBDP-C
60
dyad. The intricate photophysics, particularly the formation of radical ion pairs in these flexible covalently linked donor–acceptor systems contribute to our fundamental understanding of electron and energy transfer mechanisms, which is important to build donor–acceptor assemblies for energy applications.
Graphical abstract</description><subject>Atomic</subject><subject>Broadband</subject><subject>Chemical Sciences</subject><subject>Classical and Continuum Physics</subject><subject>Condensed Matter Physics</subject><subject>Construction standards</subject><subject>Electromagnetic absorption</subject><subject>Energy</subject><subject>Energy transfer</subject><subject>Ion pairs</subject><subject>Materials Science</subject><subject>Measurement Science and Instrumentation</subject><subject>Molecular</subject><subject>Optical and Plasma Physics</subject><subject>Photoexcitation</subject><subject>Physics</subject><subject>Physics and Astronomy</subject><subject>Regular Article</subject><subject>Ultrafast Phenomena from attosecond to picosecond timescales: theory and experiments</subject><issn>1951-6355</issn><issn>1951-6401</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNqFkctu1DAUhiMEEqXtM2CJFQtTX3NZluHSSiO1C7royvLlZMajNA62Z6S8Dw-K0xRYsrJ1_P2fbP9V9Z6ST5QKcgXTIV0lShsuMGEME1I3BM-vqjPaSYprQejrP3su5dvqXUoHQmTNOn5W_XoYctS9Thll_wQ4QgrDCRxKE9gcQ7JhmhEMR-udzn7coWkfcsAu-hOM5eCZGpEeHYIR4m5GxTemHiKaYrCQEiTkC4BMDNqZBRz8bp-xNilEsyg_3325vX_Em5pg51Oe4zy8zIrMa3dRven1kODyZT2vHr59_bG5wdu777eb6y22gjYZd9IZ2-uWtnUtaqsbyk1XOxB9x6TjhvbAGBHcauacccZYArZvOJUMCBean1cfV-9eD2qK_knHWQXt1c31Vi0zwltBeMdOtLAfVra88ucRUlaHcIxjuZ5ibSOF7NpuoZqVsuUrU4T-r5YStdSnlvrUWp8q9ann-tRcku2aTCUx7iD-8_8v-hs4yaVp</recordid><startdate>20230901</startdate><enddate>20230901</enddate><creator>Fatima, A.</creator><creator>Rabah, J.</creator><creator>Allard, E.</creator><creator>Fensterbank, H.</creator><creator>Wright, K.</creator><creator>Burdzinski, G.</creator><creator>Miomandre, F.</creator><creator>Pham, J.</creator><creator>Clavier, G.</creator><creator>Sliwa, M.</creator><creator>Pino, T.</creator><creator>Méallet-Renault, R.</creator><creator>Steenkeste, K.</creator><creator>Ha-Thi, M. H.</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><general>EDP Sciences</general><scope>AAYXX</scope><scope>CITATION</scope><scope>1XC</scope><scope>VOOES</scope><orcidid>https://orcid.org/0000-0003-3276-1843</orcidid><orcidid>https://orcid.org/0000-0001-7301-8082</orcidid><orcidid>https://orcid.org/0000-0001-6842-0907</orcidid><orcidid>https://orcid.org/0000-0002-1083-6288</orcidid><orcidid>https://orcid.org/0000-0002-2947-1602</orcidid><orcidid>https://orcid.org/0000-0002-3217-3876</orcidid><orcidid>https://orcid.org/0000-0002-5073-8180</orcidid><orcidid>https://orcid.org/0000-0002-1646-7866</orcidid><orcidid>https://orcid.org/0000-0002-7895-9954</orcidid><orcidid>https://orcid.org/0000-0003-2001-9473</orcidid><orcidid>https://orcid.org/0000-0001-7175-7236</orcidid><orcidid>https://orcid.org/0000-0002-2890-6328</orcidid></search><sort><creationdate>20230901</creationdate><title>Ultrafast time-resolved spectroscopy elucidating photo-driven electron and energy transfer processes in a broadband light-absorbing BODIPY-C60-distyryl BODIPY triad</title><author>Fatima, A. ; Rabah, J. ; Allard, E. ; Fensterbank, H. ; Wright, K. ; Burdzinski, G. ; Miomandre, F. ; Pham, J. ; Clavier, G. ; Sliwa, M. ; Pino, T. ; Méallet-Renault, R. ; Steenkeste, K. ; Ha-Thi, M. H.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c417t-95dbcfa8186646ca713b96de4f925d3b1fe22043ca2ddbdbbc0ecf73152e034a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Atomic</topic><topic>Broadband</topic><topic>Chemical Sciences</topic><topic>Classical and Continuum Physics</topic><topic>Condensed Matter Physics</topic><topic>Construction standards</topic><topic>Electromagnetic absorption</topic><topic>Energy</topic><topic>Energy transfer</topic><topic>Ion pairs</topic><topic>Materials Science</topic><topic>Measurement Science and Instrumentation</topic><topic>Molecular</topic><topic>Optical and Plasma Physics</topic><topic>Photoexcitation</topic><topic>Physics</topic><topic>Physics and Astronomy</topic><topic>Regular Article</topic><topic>Ultrafast Phenomena from attosecond to picosecond timescales: theory and experiments</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Fatima, A.</creatorcontrib><creatorcontrib>Rabah, J.</creatorcontrib><creatorcontrib>Allard, E.</creatorcontrib><creatorcontrib>Fensterbank, H.</creatorcontrib><creatorcontrib>Wright, K.</creatorcontrib><creatorcontrib>Burdzinski, G.</creatorcontrib><creatorcontrib>Miomandre, F.</creatorcontrib><creatorcontrib>Pham, J.</creatorcontrib><creatorcontrib>Clavier, G.</creatorcontrib><creatorcontrib>Sliwa, M.</creatorcontrib><creatorcontrib>Pino, T.</creatorcontrib><creatorcontrib>Méallet-Renault, R.</creatorcontrib><creatorcontrib>Steenkeste, K.</creatorcontrib><creatorcontrib>Ha-Thi, M. H.</creatorcontrib><collection>CrossRef</collection><collection>Hyper Article en Ligne (HAL)</collection><collection>Hyper Article en Ligne (HAL) (Open Access)</collection><jtitle>The European physical journal. ST, Special topics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Fatima, A.</au><au>Rabah, J.</au><au>Allard, E.</au><au>Fensterbank, H.</au><au>Wright, K.</au><au>Burdzinski, G.</au><au>Miomandre, F.</au><au>Pham, J.</au><au>Clavier, G.</au><au>Sliwa, M.</au><au>Pino, T.</au><au>Méallet-Renault, R.</au><au>Steenkeste, K.</au><au>Ha-Thi, M. H.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Ultrafast time-resolved spectroscopy elucidating photo-driven electron and energy transfer processes in a broadband light-absorbing BODIPY-C60-distyryl BODIPY triad</atitle><jtitle>The European physical journal. ST, Special topics</jtitle><stitle>Eur. Phys. J. Spec. Top</stitle><date>2023-09-01</date><risdate>2023</risdate><volume>232</volume><issue>13</issue><spage>2131</spage><epage>2144</epage><pages>2131-2144</pages><issn>1951-6355</issn><eissn>1951-6401</eissn><abstract>Photoinduced electron and energy transfer pathways are elucidated in a panchromatic light-absorbing, covalently linked triad (BODIPY-C
60
-distyryl BODIPY, noted as BDP-C
60
-DSBDP) along with the two reference dyads: BODIPY-C
60
(BDP-C
60
) and distyryl-BODIPY-C
60
(DSBDP-C
60
). The flexible linker between the BODIPY and C
60
units leads to different possible conformations with varying donor–acceptor distances. Ultrafast transient absorption along with the time-resolved emission spectroscopies revealed the occurrence of different photoinduced electron/energy transfer processes in these conformers. Photoexcitation of the BODIPY units in the two reference dyads leads to one electron and two energy transfer steps from BODIPY to C
60
. However, in the BDP-C
60
-DSBDP triad, additional energy transfer processes from BDP to DSBDP were evidenced upon photoexcitation of the BDP unit. The singlet excited state of DSBDP in the triad then follows the same relaxation route as that of the DSBDP-C
60
dyad. The intricate photophysics, particularly the formation of radical ion pairs in these flexible covalently linked donor–acceptor systems contribute to our fundamental understanding of electron and energy transfer mechanisms, which is important to build donor–acceptor assemblies for energy applications.
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| ispartof | The European physical journal. ST, Special topics, 2023-09, Vol.232 (13), p.2131-2144 |
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| source | SpringerLink Journals |
| subjects | Atomic Broadband Chemical Sciences Classical and Continuum Physics Condensed Matter Physics Construction standards Electromagnetic absorption Energy Energy transfer Ion pairs Materials Science Measurement Science and Instrumentation Molecular Optical and Plasma Physics Photoexcitation Physics Physics and Astronomy Regular Article Ultrafast Phenomena from attosecond to picosecond timescales: theory and experiments |
| title | Ultrafast time-resolved spectroscopy elucidating photo-driven electron and energy transfer processes in a broadband light-absorbing BODIPY-C60-distyryl BODIPY triad |
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