Systematic assessment of adsorption-coupled electron transfer toward voltammetric discrimination between concerted and non-concerted mechanisms

The electron transfer and specific adsorption of a redox-active molecule are coupled in many important electrode reactions. Herein, we report a theoretical framework for the voltammetric discrimination of the concerted and non-concerted mechanisms of adsorption-coupled electron-transfer (ACET) react...

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Veröffentlicht in:	Electrochimica acta 2022-10, Vol.428, p.140912, Article 140912
Hauptverfasser:	Janda, Donald C., Barma, Kiran, Kurapati, Niraja, Klymenko, Oleksiy V., Oleinick, Alexander, Svir, Irina, Amatore, Christian, Amemiya, Shigeru
Format:	Artikel
Sprache:	eng
Schlagworte:	Adsorption-coupled electron transfer Chemical Sciences COMSOL Multiphysics Cyclic voltammetry Kinetic zone diagram Kissa-1D (version 1.2.2c) Other
Online-Zugang:	Volltext
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