Rational design of mixed-matrix metal-organic framework membranes for molecular separations
Conventional separation technologies to separate valuable commodities are energy intensive, consuming 15% of the worldwide energy. Mixed-matrix membranes, combining processable polymers and selective adsorbents, offer the potential to deploy adsorbent distinct separation properties into processable...
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| Veröffentlicht in: | Science (American Association for the Advancement of Science) 2022-06, Vol.376 (6597), p.1080-1087 |
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| creator | Datta, Shuvo Jit Mayoral, Alvaro Murthy Srivatsa Bettahalli, Narasimha Bhatt, Prashant M Karunakaran, Madhavan Carja, Ionela Daniela Fan, Dong Graziane M Mileo, Paulo Semino, Rocio Maurin, Guillaume Terasaki, Osamu Eddaoudi, Mohamed |
| description | Conventional separation technologies to separate valuable commodities are energy intensive, consuming 15% of the worldwide energy. Mixed-matrix membranes, combining processable polymers and selective adsorbents, offer the potential to deploy adsorbent distinct separation properties into processable matrix. We report the rational design and construction of a highly efficient, mixed-matrix metal-organic framework membrane based on three interlocked criteria: (i) a fluorinated metal-organic framework, AlFFIVE-1-Ni, as a molecular sieve adsorbent that selectively enhances hydrogen sulfide and carbon dioxide diffusion while excluding methane; (ii) tailoring crystal morphology into nanosheets with maximally exposed (001) facets; and (iii) in-plane alignment of (001) nanosheets in polymer matrix and attainment of [001]-oriented membrane. The membrane demonstrated exceptionally high hydrogen sulfide and carbon dioxide separation from natural gas under practical working conditions. This approach offers great potential to translate other key adsorbents into processable matrix. |
| doi_str_mv | 10.1126/science.abe0192 |
| format | Article |
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Mixed-matrix membranes, combining processable polymers and selective adsorbents, offer the potential to deploy adsorbent distinct separation properties into processable matrix. We report the rational design and construction of a highly efficient, mixed-matrix metal-organic framework membrane based on three interlocked criteria: (i) a fluorinated metal-organic framework, AlFFIVE-1-Ni, as a molecular sieve adsorbent that selectively enhances hydrogen sulfide and carbon dioxide diffusion while excluding methane; (ii) tailoring crystal morphology into nanosheets with maximally exposed (001) facets; and (iii) in-plane alignment of (001) nanosheets in polymer matrix and attainment of [001]-oriented membrane. The membrane demonstrated exceptionally high hydrogen sulfide and carbon dioxide separation from natural gas under practical working conditions. 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This approach offers great potential to translate other key adsorbents into processable matrix.</description><subject>Carbon dioxide</subject><subject>Carbon fiber reinforced plastics</subject><subject>Chemical Sciences</subject><subject>Embedding</subject><subject>Gas streams</subject><subject>Hydrogen sulfide</subject><subject>Membranes</subject><subject>Metal sheets</subject><subject>Metal-organic 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| subjects | Carbon dioxide Carbon fiber reinforced plastics Chemical Sciences Embedding Gas streams Hydrogen sulfide Membranes Metal sheets Metal-organic frameworks Nanoparticles Nanostructure Polymers Selectivity Synthesis |
| title | Rational design of mixed-matrix metal-organic framework membranes for molecular separations |
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