Atropochiral (C,C)-chelating NHC-ylide ligands: synthesis and resolution of palladium(II) complexes thereof

Atropochiral NHC-phosphonium ylides based on the naphthyl-benzimidazolyl core are targeted as strongly sigma-donor C,C-chelating ligands of transition metals. The ligand core is shown to act in either a monodentate (through the carbene center) or bidentate (through the carbene and the ylide centers)...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2009-01, Vol.35 (35), p.7196-7202
Hauptverfasser:	Abdellah, Ibrahim, Debono, Nathalie, Canac, Yves, Duhayon, Carine, Chauvin, Remi
Format:	Artikel
Sprache:	eng
Schlagworte:	Chelating Agents - chemistry Chemical Sciences Coordination chemistry Crystallography, X-Ray Heterocyclic Compounds - chemistry Ligands Methane - analogs & derivatives Methane - chemistry Models, Molecular Molecular Structure Organometallic Compounds - chemical synthesis Organometallic Compounds - chemistry Palladium - chemistry Stereoisomerism
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