Deaggregation of Zinc Dihydride by Lewis Acids Including Carbon Dioxide in the Presence of Nitrogen Donors

Thermally sensitive polymeric zinc dihydride [ZnH2] n can conveniently be prepared by the reaction of ZnEt2 with [AlH3(NEt3)]. When reacted with CO2 (1 bar) in the presence of chelating N-donor ligands L n = N,N,N′,N′-tetramethylethylenediamine (TMEDA), N,N,N′,N′-tetramethyl-1,3-propanediamine (TMPD...

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Veröffentlicht in:	Inorganic chemistry 2021-10, Vol.60 (20), p.15583-15592
Hauptverfasser:	Ritter, Florian, Morris, Louis J, McCabe, Karl N, Spaniol, Thomas P, Maron, Laurent, Okuda, Jun
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemical Physics Physics
Online-Zugang:	Volltext
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