Magnetic 3d–4f Chiral Clusters Showing Multimetal Site Magneto-Chiral Dichroism

Here, we report the molecular self-assembly of hydroxido-bridged {Ln5Ni6} ((Ln3+ = Dy3+, Y3+) metal clusters by the reaction of enantiopure chiral ligands, namely, (R/S)-(2-hydroxy-3-methoxybenzyl)-serine), with NiII and LnIII precursors. Single-crystal diffraction analysis reveals that these compou...

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Veröffentlicht in:	Journal of the American Chemical Society 2022-05, Vol.144 (19), p.8837-8847
Hauptverfasser:	Wang, Xing, Wang, Shi-Qiang, Chen, Jia-Nan, Jia, Jian-Hua, Wang, Cheng, Paillot, Kevin, Breslavetz, Ivan, Long, La-Sheng, Zheng, Lansun, Rikken, Geert L. J. A., Train, Cyrille, Kong, Xiang-Jian, Atzori, Matteo
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemical Physics Chemical Sciences Coordination chemistry Crystallography, X-Ray Lanthanoid Series Elements - chemistry Magnetic Phenomena Magnetics Organometallic Compounds - chemistry Physics
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