Selective population of triplet excited states in heavy-atom-free BODIPY-C60 based molecular assemblies
Photophysical studies on a BODIPY-fullerene-distyryl BODIPY triad (BDP-C 60 -DSBDP) and its reference dyads (BODIPY-fullerene; BDP-C 60 and distyryl BODIPY-fullerene; DSBDP-C 60 ) are presented herein. In the triad, the association of the two chromophore units linked by a fullerene moiety leads to s...
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| Veröffentlicht in: | Photochemical & photobiological sciences 2022-09, Vol.21 (9), p.1573-1584 |
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| creator | Fatima, Anam Rabah, Jad Allard, Emmanuel Fensterbank, Hélène Wright, Karen Burdzinski, Gotard Clavier, Gilles Sliwa, Michel Pino, Thomas Méallet-Renault, Rachel Steenkeste, Karine Ha-Thi, Minh-Huong |
| description | Photophysical studies on a BODIPY-fullerene-distyryl BODIPY triad (BDP-C
60
-DSBDP) and its reference dyads (BODIPY-fullerene; BDP-C
60
and distyryl BODIPY-fullerene; DSBDP-C
60
) are presented herein. In the triad, the association of the two chromophore units linked by a fullerene moiety leads to strong near UV–Visible light absorption from 300 to 700 nm. The triplet-excited state was observed upon visible excitation in all these assemblies, and shown to be localized on the C
60
or BODIPY moieties. Using quantitative nanosecond transient absorption, we provide a complete investigation on the lifetime and formation quantum yield of the triplet-excited state. In the BDP-C
60
dyad, the triplet excited state of C
60
(
τ
= 7 ± 1 μs) was obtained with a quantum yield of 40 ± 8%. For the DSBDP-C
60
dyad and BDP-C
60
-DSBDP triad, a longer-lived triplet excited state with a lifetime of around 250 ± 20 μs centered on the DSBDP moiety was formed, with respective quantum yields of 37 ± 8 and 20 ± 4%. Triplet–triplet annihilation up-conversion is characterized in the BDP-C
60
dyad and the bichromophoric triad in the presence of perylene and DSBDP-monomer as respective annihilators. The photo-induced formation of a long-lived
3
DSBDP* in the triad coupled with panchromatic light absorption offers potential applications as a heavy-atom-free organic triplet photosensitizer.
Graphical abstract |
| doi_str_mv | 10.1007/s43630-022-00241-z |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_hal_p</sourceid><recordid>TN_cdi_hal_primary_oai_HAL_hal_03698643v1</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2669502501</sourcerecordid><originalsourceid>FETCH-LOGICAL-c402t-f1b0ad109d1a6de745fcc720b9f5d6d097c39fa990b9f98663ca202948272c1e3</originalsourceid><addsrcrecordid>eNp9kctKxTAQhosoeH0BV13qIjpJ09Qs9XiFAwrqwlXISacaaZua5BzUp_FZfDJzrIgrVzMM3__D8GXZLoUDClAdBl6IAggwRgAYp-R9JdugvOJEgmSrf_b1bDOEZwBaclFtZPYWWzTRLjAf3DBvdbSuz12TR2-HFuPnB74aG7HOQ9QRQ277_An14o3o6DrSeMT85Pr06uaBTAR8fsx0SGznUmkq87kOAbtZazFsZ2uNbgPu_Myt7P787G5ySabXF1eT4ykxHFgkDZ2BrinImmpRY8XLxpiKwUw2ZS1qkJUpZKOlXF7kkRCF0QyY5EesYoZisZXtj71PulWDt532b8ppqy6Pp2p5g0KkHC8WNLF7Izt49zLHEFVng8G21T26eVBMCFkCK2GJshE13oXgsfntpqCWDtToQCUH6tuBek-hYgyFBPeP6NWzm_s-vf9f6gtyV4u4</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2669502501</pqid></control><display><type>article</type><title>Selective population of triplet excited states in heavy-atom-free BODIPY-C60 based molecular assemblies</title><source>Springer Nature - Complete Springer Journals</source><creator>Fatima, Anam ; Rabah, Jad ; Allard, Emmanuel ; Fensterbank, Hélène ; Wright, Karen ; Burdzinski, Gotard ; Clavier, Gilles ; Sliwa, Michel ; Pino, Thomas ; Méallet-Renault, Rachel ; Steenkeste, Karine ; Ha-Thi, Minh-Huong</creator><creatorcontrib>Fatima, Anam ; Rabah, Jad ; Allard, Emmanuel ; Fensterbank, Hélène ; Wright, Karen ; Burdzinski, Gotard ; Clavier, Gilles ; Sliwa, Michel ; Pino, Thomas ; Méallet-Renault, Rachel ; Steenkeste, Karine ; Ha-Thi, Minh-Huong</creatorcontrib><description>Photophysical studies on a BODIPY-fullerene-distyryl BODIPY triad (BDP-C
60
-DSBDP) and its reference dyads (BODIPY-fullerene; BDP-C
60
and distyryl BODIPY-fullerene; DSBDP-C
60
) are presented herein. In the triad, the association of the two chromophore units linked by a fullerene moiety leads to strong near UV–Visible light absorption from 300 to 700 nm. The triplet-excited state was observed upon visible excitation in all these assemblies, and shown to be localized on the C
60
or BODIPY moieties. Using quantitative nanosecond transient absorption, we provide a complete investigation on the lifetime and formation quantum yield of the triplet-excited state. In the BDP-C
60
dyad, the triplet excited state of C
60
(
τ
= 7 ± 1 μs) was obtained with a quantum yield of 40 ± 8%. For the DSBDP-C
60
dyad and BDP-C
60
-DSBDP triad, a longer-lived triplet excited state with a lifetime of around 250 ± 20 μs centered on the DSBDP moiety was formed, with respective quantum yields of 37 ± 8 and 20 ± 4%. Triplet–triplet annihilation up-conversion is characterized in the BDP-C
60
dyad and the bichromophoric triad in the presence of perylene and DSBDP-monomer as respective annihilators. The photo-induced formation of a long-lived
3
DSBDP* in the triad coupled with panchromatic light absorption offers potential applications as a heavy-atom-free organic triplet photosensitizer.
Graphical abstract</description><identifier>ISSN: 1474-9092</identifier><identifier>EISSN: 1474-9092</identifier><identifier>DOI: 10.1007/s43630-022-00241-z</identifier><language>eng</language><publisher>Cham: Springer International Publishing</publisher><subject>Biochemistry ; Biomaterials ; Chemical Sciences ; Chemistry ; Chemistry and Materials Science ; Original Papers ; Physical Chemistry ; Physics ; Plant Sciences</subject><ispartof>Photochemical & photobiological sciences, 2022-09, Vol.21 (9), p.1573-1584</ispartof><rights>The Author(s), under exclusive licence to European Photochemistry Association, European Society for Photobiology 2022</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c402t-f1b0ad109d1a6de745fcc720b9f5d6d097c39fa990b9f98663ca202948272c1e3</citedby><cites>FETCH-LOGICAL-c402t-f1b0ad109d1a6de745fcc720b9f5d6d097c39fa990b9f98663ca202948272c1e3</cites><orcidid>0000-0003-3276-1843 ; 0000-0002-3217-3876 ; 0000-0001-6842-0907 ; 0000-0002-7895-9954 ; 0000-0002-2947-1602</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s43630-022-00241-z$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s43630-022-00241-z$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>230,314,776,780,881,27901,27902,41464,42533,51294</link.rule.ids><backlink>$$Uhttps://hal.science/hal-03698643$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Fatima, Anam</creatorcontrib><creatorcontrib>Rabah, Jad</creatorcontrib><creatorcontrib>Allard, Emmanuel</creatorcontrib><creatorcontrib>Fensterbank, Hélène</creatorcontrib><creatorcontrib>Wright, Karen</creatorcontrib><creatorcontrib>Burdzinski, Gotard</creatorcontrib><creatorcontrib>Clavier, Gilles</creatorcontrib><creatorcontrib>Sliwa, Michel</creatorcontrib><creatorcontrib>Pino, Thomas</creatorcontrib><creatorcontrib>Méallet-Renault, Rachel</creatorcontrib><creatorcontrib>Steenkeste, Karine</creatorcontrib><creatorcontrib>Ha-Thi, Minh-Huong</creatorcontrib><title>Selective population of triplet excited states in heavy-atom-free BODIPY-C60 based molecular assemblies</title><title>Photochemical & photobiological sciences</title><addtitle>Photochem Photobiol Sci</addtitle><description>Photophysical studies on a BODIPY-fullerene-distyryl BODIPY triad (BDP-C
60
-DSBDP) and its reference dyads (BODIPY-fullerene; BDP-C
60
and distyryl BODIPY-fullerene; DSBDP-C
60
) are presented herein. In the triad, the association of the two chromophore units linked by a fullerene moiety leads to strong near UV–Visible light absorption from 300 to 700 nm. The triplet-excited state was observed upon visible excitation in all these assemblies, and shown to be localized on the C
60
or BODIPY moieties. Using quantitative nanosecond transient absorption, we provide a complete investigation on the lifetime and formation quantum yield of the triplet-excited state. In the BDP-C
60
dyad, the triplet excited state of C
60
(
τ
= 7 ± 1 μs) was obtained with a quantum yield of 40 ± 8%. For the DSBDP-C
60
dyad and BDP-C
60
-DSBDP triad, a longer-lived triplet excited state with a lifetime of around 250 ± 20 μs centered on the DSBDP moiety was formed, with respective quantum yields of 37 ± 8 and 20 ± 4%. Triplet–triplet annihilation up-conversion is characterized in the BDP-C
60
dyad and the bichromophoric triad in the presence of perylene and DSBDP-monomer as respective annihilators. The photo-induced formation of a long-lived
3
DSBDP* in the triad coupled with panchromatic light absorption offers potential applications as a heavy-atom-free organic triplet photosensitizer.
Graphical abstract</description><subject>Biochemistry</subject><subject>Biomaterials</subject><subject>Chemical Sciences</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Original Papers</subject><subject>Physical Chemistry</subject><subject>Physics</subject><subject>Plant Sciences</subject><issn>1474-9092</issn><issn>1474-9092</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNp9kctKxTAQhosoeH0BV13qIjpJ09Qs9XiFAwrqwlXISacaaZua5BzUp_FZfDJzrIgrVzMM3__D8GXZLoUDClAdBl6IAggwRgAYp-R9JdugvOJEgmSrf_b1bDOEZwBaclFtZPYWWzTRLjAf3DBvdbSuz12TR2-HFuPnB74aG7HOQ9QRQ277_An14o3o6DrSeMT85Pr06uaBTAR8fsx0SGznUmkq87kOAbtZazFsZ2uNbgPu_Myt7P787G5ySabXF1eT4ykxHFgkDZ2BrinImmpRY8XLxpiKwUw2ZS1qkJUpZKOlXF7kkRCF0QyY5EesYoZisZXtj71PulWDt532b8ppqy6Pp2p5g0KkHC8WNLF7Izt49zLHEFVng8G21T26eVBMCFkCK2GJshE13oXgsfntpqCWDtToQCUH6tuBek-hYgyFBPeP6NWzm_s-vf9f6gtyV4u4</recordid><startdate>20220901</startdate><enddate>20220901</enddate><creator>Fatima, Anam</creator><creator>Rabah, Jad</creator><creator>Allard, Emmanuel</creator><creator>Fensterbank, Hélène</creator><creator>Wright, Karen</creator><creator>Burdzinski, Gotard</creator><creator>Clavier, Gilles</creator><creator>Sliwa, Michel</creator><creator>Pino, Thomas</creator><creator>Méallet-Renault, Rachel</creator><creator>Steenkeste, Karine</creator><creator>Ha-Thi, Minh-Huong</creator><general>Springer International Publishing</general><general>Springer</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>1XC</scope><scope>VOOES</scope><orcidid>https://orcid.org/0000-0003-3276-1843</orcidid><orcidid>https://orcid.org/0000-0002-3217-3876</orcidid><orcidid>https://orcid.org/0000-0001-6842-0907</orcidid><orcidid>https://orcid.org/0000-0002-7895-9954</orcidid><orcidid>https://orcid.org/0000-0002-2947-1602</orcidid></search><sort><creationdate>20220901</creationdate><title>Selective population of triplet excited states in heavy-atom-free BODIPY-C60 based molecular assemblies</title><author>Fatima, Anam ; Rabah, Jad ; Allard, Emmanuel ; Fensterbank, Hélène ; Wright, Karen ; Burdzinski, Gotard ; Clavier, Gilles ; Sliwa, Michel ; Pino, Thomas ; Méallet-Renault, Rachel ; Steenkeste, Karine ; Ha-Thi, Minh-Huong</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c402t-f1b0ad109d1a6de745fcc720b9f5d6d097c39fa990b9f98663ca202948272c1e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Biochemistry</topic><topic>Biomaterials</topic><topic>Chemical Sciences</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Original Papers</topic><topic>Physical Chemistry</topic><topic>Physics</topic><topic>Plant Sciences</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Fatima, Anam</creatorcontrib><creatorcontrib>Rabah, Jad</creatorcontrib><creatorcontrib>Allard, Emmanuel</creatorcontrib><creatorcontrib>Fensterbank, Hélène</creatorcontrib><creatorcontrib>Wright, Karen</creatorcontrib><creatorcontrib>Burdzinski, Gotard</creatorcontrib><creatorcontrib>Clavier, Gilles</creatorcontrib><creatorcontrib>Sliwa, Michel</creatorcontrib><creatorcontrib>Pino, Thomas</creatorcontrib><creatorcontrib>Méallet-Renault, Rachel</creatorcontrib><creatorcontrib>Steenkeste, Karine</creatorcontrib><creatorcontrib>Ha-Thi, Minh-Huong</creatorcontrib><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>Hyper Article en Ligne (HAL)</collection><collection>Hyper Article en Ligne (HAL) (Open Access)</collection><jtitle>Photochemical & photobiological sciences</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Fatima, Anam</au><au>Rabah, Jad</au><au>Allard, Emmanuel</au><au>Fensterbank, Hélène</au><au>Wright, Karen</au><au>Burdzinski, Gotard</au><au>Clavier, Gilles</au><au>Sliwa, Michel</au><au>Pino, Thomas</au><au>Méallet-Renault, Rachel</au><au>Steenkeste, Karine</au><au>Ha-Thi, Minh-Huong</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Selective population of triplet excited states in heavy-atom-free BODIPY-C60 based molecular assemblies</atitle><jtitle>Photochemical & photobiological sciences</jtitle><stitle>Photochem Photobiol Sci</stitle><date>2022-09-01</date><risdate>2022</risdate><volume>21</volume><issue>9</issue><spage>1573</spage><epage>1584</epage><pages>1573-1584</pages><issn>1474-9092</issn><eissn>1474-9092</eissn><abstract>Photophysical studies on a BODIPY-fullerene-distyryl BODIPY triad (BDP-C
60
-DSBDP) and its reference dyads (BODIPY-fullerene; BDP-C
60
and distyryl BODIPY-fullerene; DSBDP-C
60
) are presented herein. In the triad, the association of the two chromophore units linked by a fullerene moiety leads to strong near UV–Visible light absorption from 300 to 700 nm. The triplet-excited state was observed upon visible excitation in all these assemblies, and shown to be localized on the C
60
or BODIPY moieties. Using quantitative nanosecond transient absorption, we provide a complete investigation on the lifetime and formation quantum yield of the triplet-excited state. In the BDP-C
60
dyad, the triplet excited state of C
60
(
τ
= 7 ± 1 μs) was obtained with a quantum yield of 40 ± 8%. For the DSBDP-C
60
dyad and BDP-C
60
-DSBDP triad, a longer-lived triplet excited state with a lifetime of around 250 ± 20 μs centered on the DSBDP moiety was formed, with respective quantum yields of 37 ± 8 and 20 ± 4%. Triplet–triplet annihilation up-conversion is characterized in the BDP-C
60
dyad and the bichromophoric triad in the presence of perylene and DSBDP-monomer as respective annihilators. The photo-induced formation of a long-lived
3
DSBDP* in the triad coupled with panchromatic light absorption offers potential applications as a heavy-atom-free organic triplet photosensitizer.
Graphical abstract</abstract><cop>Cham</cop><pub>Springer International Publishing</pub><doi>10.1007/s43630-022-00241-z</doi><tpages>12</tpages><orcidid>https://orcid.org/0000-0003-3276-1843</orcidid><orcidid>https://orcid.org/0000-0002-3217-3876</orcidid><orcidid>https://orcid.org/0000-0001-6842-0907</orcidid><orcidid>https://orcid.org/0000-0002-7895-9954</orcidid><orcidid>https://orcid.org/0000-0002-2947-1602</orcidid><oa>free_for_read</oa></addata></record> |
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| source | Springer Nature - Complete Springer Journals |
| subjects | Biochemistry Biomaterials Chemical Sciences Chemistry Chemistry and Materials Science Original Papers Physical Chemistry Physics Plant Sciences |
| title | Selective population of triplet excited states in heavy-atom-free BODIPY-C60 based molecular assemblies |
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