A 3D electropolymerized thin film based on an isoporphyrin and on a pyridine end-decorated molybdenum(II) halide cluster: Photoelectrochemical and impedance properties
•Formation of original and innovative hybrid copolymers obtained by electropolymerization from molybdenum(II) halide cluster and porphyrins.•Good photoelectrocatalytical properties.•Good correlation between impedance and photovoltaic performances under visible-NIR illumination.•Best photocurrent gen...
Gespeichert in:
| Veröffentlicht in: | Electrochimica acta 2021-08, Vol.388, p.138493, Article 138493 |
|---|---|
| Hauptverfasser: | , , , , , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | |
|---|---|
| container_issue | |
| container_start_page | 138493 |
| container_title | Electrochimica acta |
| container_volume | 388 |
| creator | Liang, Yiming Sokolov, Maxim N. Mikhaylov, Maxim A. Ibrahim, Helen Goldmann, Michel Choua, Sylvie Breton, Nolwenn Le Boudon, Corinne Badets, Vasilica Bonnefont, Antoine Ruhlmann, Laurent |
| description | •Formation of original and innovative hybrid copolymers obtained by electropolymerization from molybdenum(II) halide cluster and porphyrins.•Good photoelectrocatalytical properties.•Good correlation between impedance and photovoltaic performances under visible-NIR illumination.•Best photocurrent generation efficiency for molybdenum(II) halide cluster photosensitized (with porphyrin) hybrid reported up to now.
Herein, the first example of formation of a 3D hybrid organic-inorganic copolymer based on an isoporphyrin and on a pyridine end-decorated molybdenum(II) halide cluster. The isoporphyrin copolymer thin film was obtained by electropolymerization of zinc-5,15-bis(p-tolyl)porphyrin in the presence of polyiodometalate with 6 pendant pyridyl ligands (((Bu4N)2[{Mo6I8}(OOC-C5H4N)6]). Electrogenerated porphyrin radical cation is a powerful electrophile which can rapidly react with the pyridine end-decorated Mo(II) halide cluster as nucleophile to form 3D copolymer containing stable isoporphyrin.
The electropolymerization was monitored by electrochemical quartz crystal microbalance (EQCM). The copolymer was characterized by UV-Vis-NIR spectroscopy, X-ray photoelectron spectroscopy (XPS), electrochemistry, and atomic force microscopy (AFM). The existence of the radical of the isoporphyrin copolymer was proved by electron spin resonance spectroscopy (EPR).
Interestingly, the UV-Vis-NIR spectra of the copolymer exhibited broadening and splitting of the Soret band as well as one additional band in the NIR between 750 nm and 1000 nm.
The photoelectrochemical properties have been studied by electrochemical impedance spectroscopy and by photocurrent transient measurements under visible-NIR light irradiation.
The 3D copolymer containing stable isoporphyrin radical exhibits interesting photocurrent response even under only NIR illumination.
In the solid state, the 3D copolymer could be stored for over several months and even one year without any degradation under ambient conditions in air.
First example of formation of a 3D hybrid organic-inorganic copolymer based on an isoporphyrin and on a pyridine end-decorated molybdenum(II) halide cluster. The photoelectrochemical properties have been investigated under visible-NIR light irradiation. [Display omitted] |
| doi_str_mv | 10.1016/j.electacta.2021.138493 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_hal_p</sourceid><recordid>TN_cdi_hal_primary_oai_HAL_hal_03692812v1</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S0013468621007830</els_id><sourcerecordid>2551713837</sourcerecordid><originalsourceid>FETCH-LOGICAL-c426t-120ad3bd04498436f6d0350ff0e0804ddc9cd6fde877badb11c15db81975bf1e3</originalsourceid><addsrcrecordid>eNqFUcFq3DAUFKWFbtN-QwW9NAdvJcuW5N6WpG0WFtpDexay3jPWYluu5A1sfqi_WW0ccg0IxDxm5o00hHzkbMsZl1-OWxzQLTafbclKvuVCV414RTZcK1EIXTevyYYxLopKavmWvEvpyBhTUrEN-bej4pY-OsQwh-E8YvQPCHTp_UQ7P4y0tSnjMFE7UZ8yKc79OfoLXsd0zhD8hBQnKABdiHbJkjHbtYDTafy831_T3g4ekLrhlBaMX-mvPizhabPrcfTODo-efpwR7OSQzjkTxsVjek_edHZI-OHpviJ_vn_7fXNXHH7-2N_sDoWrSrkUvGQWRAusqhpdCdlJYKJmXceQaVYBuMaB7AC1Uq2FlnPHa2g1b1TddhzFFblefXNaM0c_2ng2wXpztzuYy4wJ2ZSal_c8cz-t3Bzz7wnTYo7hFKccz5R1zVUuQqjMUivLxZBSxO7ZljNzadAczXOD5tKgWRvMyt2qxPzge4_RJOcx_wv4mPkGgn_R4z8d5auC</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2551713837</pqid></control><display><type>article</type><title>A 3D electropolymerized thin film based on an isoporphyrin and on a pyridine end-decorated molybdenum(II) halide cluster: Photoelectrochemical and impedance properties</title><source>ScienceDirect Journals (5 years ago - present)</source><creator>Liang, Yiming ; Sokolov, Maxim N. ; Mikhaylov, Maxim A. ; Ibrahim, Helen ; Goldmann, Michel ; Choua, Sylvie ; Breton, Nolwenn Le ; Boudon, Corinne ; Badets, Vasilica ; Bonnefont, Antoine ; Ruhlmann, Laurent</creator><creatorcontrib>Liang, Yiming ; Sokolov, Maxim N. ; Mikhaylov, Maxim A. ; Ibrahim, Helen ; Goldmann, Michel ; Choua, Sylvie ; Breton, Nolwenn Le ; Boudon, Corinne ; Badets, Vasilica ; Bonnefont, Antoine ; Ruhlmann, Laurent</creatorcontrib><description>•Formation of original and innovative hybrid copolymers obtained by electropolymerization from molybdenum(II) halide cluster and porphyrins.•Good photoelectrocatalytical properties.•Good correlation between impedance and photovoltaic performances under visible-NIR illumination.•Best photocurrent generation efficiency for molybdenum(II) halide cluster photosensitized (with porphyrin) hybrid reported up to now.
Herein, the first example of formation of a 3D hybrid organic-inorganic copolymer based on an isoporphyrin and on a pyridine end-decorated molybdenum(II) halide cluster. The isoporphyrin copolymer thin film was obtained by electropolymerization of zinc-5,15-bis(p-tolyl)porphyrin in the presence of polyiodometalate with 6 pendant pyridyl ligands (((Bu4N)2[{Mo6I8}(OOC-C5H4N)6]). Electrogenerated porphyrin radical cation is a powerful electrophile which can rapidly react with the pyridine end-decorated Mo(II) halide cluster as nucleophile to form 3D copolymer containing stable isoporphyrin.
The electropolymerization was monitored by electrochemical quartz crystal microbalance (EQCM). The copolymer was characterized by UV-Vis-NIR spectroscopy, X-ray photoelectron spectroscopy (XPS), electrochemistry, and atomic force microscopy (AFM). The existence of the radical of the isoporphyrin copolymer was proved by electron spin resonance spectroscopy (EPR).
Interestingly, the UV-Vis-NIR spectra of the copolymer exhibited broadening and splitting of the Soret band as well as one additional band in the NIR between 750 nm and 1000 nm.
The photoelectrochemical properties have been studied by electrochemical impedance spectroscopy and by photocurrent transient measurements under visible-NIR light irradiation.
The 3D copolymer containing stable isoporphyrin radical exhibits interesting photocurrent response even under only NIR illumination.
In the solid state, the 3D copolymer could be stored for over several months and even one year without any degradation under ambient conditions in air.
First example of formation of a 3D hybrid organic-inorganic copolymer based on an isoporphyrin and on a pyridine end-decorated molybdenum(II) halide cluster. The photoelectrochemical properties have been investigated under visible-NIR light irradiation. [Display omitted]</description><identifier>ISSN: 0013-4686</identifier><identifier>EISSN: 1873-3859</identifier><identifier>DOI: 10.1016/j.electacta.2021.138493</identifier><language>eng</language><publisher>Oxford: Elsevier Ltd</publisher><subject>Atomic force microscopy ; Chemical Sciences ; Clusters ; Coordination chemistry ; Copolymers ; Decoration ; Electrochemical impedance spectroscopy ; Electrochemistry ; Electron paramagnetic resonance ; Electron spin ; Electrons ; Electropolymerization ; Isoporphyrin ; Light irradiation ; Microbalances ; Molybdenum ; Molybdenum(II) halide cluster ; Organic–inorganic hybrid composites ; Photocurrent generation ; Photoelectric effect ; Photoelectric emission ; Photoelectrons ; Polymerization ; Polymers ; Porphyrinoids ; Porphyrins ; Quartz crystals ; Spectrum analysis ; Spin resonance ; Thin films ; X ray photoelectron spectroscopy</subject><ispartof>Electrochimica acta, 2021-08, Vol.388, p.138493, Article 138493</ispartof><rights>2021</rights><rights>Copyright Elsevier BV Aug 20, 2021</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c426t-120ad3bd04498436f6d0350ff0e0804ddc9cd6fde877badb11c15db81975bf1e3</citedby><cites>FETCH-LOGICAL-c426t-120ad3bd04498436f6d0350ff0e0804ddc9cd6fde877badb11c15db81975bf1e3</cites><orcidid>0000-0002-1103-2927 ; 0000-0002-8587-5644 ; 0000-0003-1005-3555 ; 0000-0002-5566-3712 ; 0000-0003-1154-2422 ; 0000-0003-4640-0475</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.electacta.2021.138493$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>230,314,778,782,883,3539,27911,27912,45982</link.rule.ids><backlink>$$Uhttps://hal.science/hal-03692812$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Liang, Yiming</creatorcontrib><creatorcontrib>Sokolov, Maxim N.</creatorcontrib><creatorcontrib>Mikhaylov, Maxim A.</creatorcontrib><creatorcontrib>Ibrahim, Helen</creatorcontrib><creatorcontrib>Goldmann, Michel</creatorcontrib><creatorcontrib>Choua, Sylvie</creatorcontrib><creatorcontrib>Breton, Nolwenn Le</creatorcontrib><creatorcontrib>Boudon, Corinne</creatorcontrib><creatorcontrib>Badets, Vasilica</creatorcontrib><creatorcontrib>Bonnefont, Antoine</creatorcontrib><creatorcontrib>Ruhlmann, Laurent</creatorcontrib><title>A 3D electropolymerized thin film based on an isoporphyrin and on a pyridine end-decorated molybdenum(II) halide cluster: Photoelectrochemical and impedance properties</title><title>Electrochimica acta</title><description>•Formation of original and innovative hybrid copolymers obtained by electropolymerization from molybdenum(II) halide cluster and porphyrins.•Good photoelectrocatalytical properties.•Good correlation between impedance and photovoltaic performances under visible-NIR illumination.•Best photocurrent generation efficiency for molybdenum(II) halide cluster photosensitized (with porphyrin) hybrid reported up to now.
Herein, the first example of formation of a 3D hybrid organic-inorganic copolymer based on an isoporphyrin and on a pyridine end-decorated molybdenum(II) halide cluster. The isoporphyrin copolymer thin film was obtained by electropolymerization of zinc-5,15-bis(p-tolyl)porphyrin in the presence of polyiodometalate with 6 pendant pyridyl ligands (((Bu4N)2[{Mo6I8}(OOC-C5H4N)6]). Electrogenerated porphyrin radical cation is a powerful electrophile which can rapidly react with the pyridine end-decorated Mo(II) halide cluster as nucleophile to form 3D copolymer containing stable isoporphyrin.
The electropolymerization was monitored by electrochemical quartz crystal microbalance (EQCM). The copolymer was characterized by UV-Vis-NIR spectroscopy, X-ray photoelectron spectroscopy (XPS), electrochemistry, and atomic force microscopy (AFM). The existence of the radical of the isoporphyrin copolymer was proved by electron spin resonance spectroscopy (EPR).
Interestingly, the UV-Vis-NIR spectra of the copolymer exhibited broadening and splitting of the Soret band as well as one additional band in the NIR between 750 nm and 1000 nm.
The photoelectrochemical properties have been studied by electrochemical impedance spectroscopy and by photocurrent transient measurements under visible-NIR light irradiation.
The 3D copolymer containing stable isoporphyrin radical exhibits interesting photocurrent response even under only NIR illumination.
In the solid state, the 3D copolymer could be stored for over several months and even one year without any degradation under ambient conditions in air.
First example of formation of a 3D hybrid organic-inorganic copolymer based on an isoporphyrin and on a pyridine end-decorated molybdenum(II) halide cluster. The photoelectrochemical properties have been investigated under visible-NIR light irradiation. [Display omitted]</description><subject>Atomic force microscopy</subject><subject>Chemical Sciences</subject><subject>Clusters</subject><subject>Coordination chemistry</subject><subject>Copolymers</subject><subject>Decoration</subject><subject>Electrochemical impedance spectroscopy</subject><subject>Electrochemistry</subject><subject>Electron paramagnetic resonance</subject><subject>Electron spin</subject><subject>Electrons</subject><subject>Electropolymerization</subject><subject>Isoporphyrin</subject><subject>Light irradiation</subject><subject>Microbalances</subject><subject>Molybdenum</subject><subject>Molybdenum(II) halide cluster</subject><subject>Organic–inorganic hybrid composites</subject><subject>Photocurrent generation</subject><subject>Photoelectric effect</subject><subject>Photoelectric emission</subject><subject>Photoelectrons</subject><subject>Polymerization</subject><subject>Polymers</subject><subject>Porphyrinoids</subject><subject>Porphyrins</subject><subject>Quartz crystals</subject><subject>Spectrum analysis</subject><subject>Spin resonance</subject><subject>Thin films</subject><subject>X ray photoelectron spectroscopy</subject><issn>0013-4686</issn><issn>1873-3859</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNqFUcFq3DAUFKWFbtN-QwW9NAdvJcuW5N6WpG0WFtpDexay3jPWYluu5A1sfqi_WW0ccg0IxDxm5o00hHzkbMsZl1-OWxzQLTafbclKvuVCV414RTZcK1EIXTevyYYxLopKavmWvEvpyBhTUrEN-bej4pY-OsQwh-E8YvQPCHTp_UQ7P4y0tSnjMFE7UZ8yKc79OfoLXsd0zhD8hBQnKABdiHbJkjHbtYDTafy831_T3g4ekLrhlBaMX-mvPizhabPrcfTODo-efpwR7OSQzjkTxsVjek_edHZI-OHpviJ_vn_7fXNXHH7-2N_sDoWrSrkUvGQWRAusqhpdCdlJYKJmXceQaVYBuMaB7AC1Uq2FlnPHa2g1b1TddhzFFblefXNaM0c_2ng2wXpztzuYy4wJ2ZSal_c8cz-t3Bzz7wnTYo7hFKccz5R1zVUuQqjMUivLxZBSxO7ZljNzadAczXOD5tKgWRvMyt2qxPzge4_RJOcx_wv4mPkGgn_R4z8d5auC</recordid><startdate>20210820</startdate><enddate>20210820</enddate><creator>Liang, Yiming</creator><creator>Sokolov, Maxim N.</creator><creator>Mikhaylov, Maxim A.</creator><creator>Ibrahim, Helen</creator><creator>Goldmann, Michel</creator><creator>Choua, Sylvie</creator><creator>Breton, Nolwenn Le</creator><creator>Boudon, Corinne</creator><creator>Badets, Vasilica</creator><creator>Bonnefont, Antoine</creator><creator>Ruhlmann, Laurent</creator><general>Elsevier Ltd</general><general>Elsevier BV</general><general>Elsevier</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>1XC</scope><scope>VOOES</scope><orcidid>https://orcid.org/0000-0002-1103-2927</orcidid><orcidid>https://orcid.org/0000-0002-8587-5644</orcidid><orcidid>https://orcid.org/0000-0003-1005-3555</orcidid><orcidid>https://orcid.org/0000-0002-5566-3712</orcidid><orcidid>https://orcid.org/0000-0003-1154-2422</orcidid><orcidid>https://orcid.org/0000-0003-4640-0475</orcidid></search><sort><creationdate>20210820</creationdate><title>A 3D electropolymerized thin film based on an isoporphyrin and on a pyridine end-decorated molybdenum(II) halide cluster: Photoelectrochemical and impedance properties</title><author>Liang, Yiming ; Sokolov, Maxim N. ; Mikhaylov, Maxim A. ; Ibrahim, Helen ; Goldmann, Michel ; Choua, Sylvie ; Breton, Nolwenn Le ; Boudon, Corinne ; Badets, Vasilica ; Bonnefont, Antoine ; Ruhlmann, Laurent</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c426t-120ad3bd04498436f6d0350ff0e0804ddc9cd6fde877badb11c15db81975bf1e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Atomic force microscopy</topic><topic>Chemical Sciences</topic><topic>Clusters</topic><topic>Coordination chemistry</topic><topic>Copolymers</topic><topic>Decoration</topic><topic>Electrochemical impedance spectroscopy</topic><topic>Electrochemistry</topic><topic>Electron paramagnetic resonance</topic><topic>Electron spin</topic><topic>Electrons</topic><topic>Electropolymerization</topic><topic>Isoporphyrin</topic><topic>Light irradiation</topic><topic>Microbalances</topic><topic>Molybdenum</topic><topic>Molybdenum(II) halide cluster</topic><topic>Organic–inorganic hybrid composites</topic><topic>Photocurrent generation</topic><topic>Photoelectric effect</topic><topic>Photoelectric emission</topic><topic>Photoelectrons</topic><topic>Polymerization</topic><topic>Polymers</topic><topic>Porphyrinoids</topic><topic>Porphyrins</topic><topic>Quartz crystals</topic><topic>Spectrum analysis</topic><topic>Spin resonance</topic><topic>Thin films</topic><topic>X ray photoelectron spectroscopy</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Liang, Yiming</creatorcontrib><creatorcontrib>Sokolov, Maxim N.</creatorcontrib><creatorcontrib>Mikhaylov, Maxim A.</creatorcontrib><creatorcontrib>Ibrahim, Helen</creatorcontrib><creatorcontrib>Goldmann, Michel</creatorcontrib><creatorcontrib>Choua, Sylvie</creatorcontrib><creatorcontrib>Breton, Nolwenn Le</creatorcontrib><creatorcontrib>Boudon, Corinne</creatorcontrib><creatorcontrib>Badets, Vasilica</creatorcontrib><creatorcontrib>Bonnefont, Antoine</creatorcontrib><creatorcontrib>Ruhlmann, Laurent</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Hyper Article en Ligne (HAL)</collection><collection>Hyper Article en Ligne (HAL) (Open Access)</collection><jtitle>Electrochimica acta</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Liang, Yiming</au><au>Sokolov, Maxim N.</au><au>Mikhaylov, Maxim A.</au><au>Ibrahim, Helen</au><au>Goldmann, Michel</au><au>Choua, Sylvie</au><au>Breton, Nolwenn Le</au><au>Boudon, Corinne</au><au>Badets, Vasilica</au><au>Bonnefont, Antoine</au><au>Ruhlmann, Laurent</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A 3D electropolymerized thin film based on an isoporphyrin and on a pyridine end-decorated molybdenum(II) halide cluster: Photoelectrochemical and impedance properties</atitle><jtitle>Electrochimica acta</jtitle><date>2021-08-20</date><risdate>2021</risdate><volume>388</volume><spage>138493</spage><pages>138493-</pages><artnum>138493</artnum><issn>0013-4686</issn><eissn>1873-3859</eissn><abstract>•Formation of original and innovative hybrid copolymers obtained by electropolymerization from molybdenum(II) halide cluster and porphyrins.•Good photoelectrocatalytical properties.•Good correlation between impedance and photovoltaic performances under visible-NIR illumination.•Best photocurrent generation efficiency for molybdenum(II) halide cluster photosensitized (with porphyrin) hybrid reported up to now.
Herein, the first example of formation of a 3D hybrid organic-inorganic copolymer based on an isoporphyrin and on a pyridine end-decorated molybdenum(II) halide cluster. The isoporphyrin copolymer thin film was obtained by electropolymerization of zinc-5,15-bis(p-tolyl)porphyrin in the presence of polyiodometalate with 6 pendant pyridyl ligands (((Bu4N)2[{Mo6I8}(OOC-C5H4N)6]). Electrogenerated porphyrin radical cation is a powerful electrophile which can rapidly react with the pyridine end-decorated Mo(II) halide cluster as nucleophile to form 3D copolymer containing stable isoporphyrin.
The electropolymerization was monitored by electrochemical quartz crystal microbalance (EQCM). The copolymer was characterized by UV-Vis-NIR spectroscopy, X-ray photoelectron spectroscopy (XPS), electrochemistry, and atomic force microscopy (AFM). The existence of the radical of the isoporphyrin copolymer was proved by electron spin resonance spectroscopy (EPR).
Interestingly, the UV-Vis-NIR spectra of the copolymer exhibited broadening and splitting of the Soret band as well as one additional band in the NIR between 750 nm and 1000 nm.
The photoelectrochemical properties have been studied by electrochemical impedance spectroscopy and by photocurrent transient measurements under visible-NIR light irradiation.
The 3D copolymer containing stable isoporphyrin radical exhibits interesting photocurrent response even under only NIR illumination.
In the solid state, the 3D copolymer could be stored for over several months and even one year without any degradation under ambient conditions in air.
First example of formation of a 3D hybrid organic-inorganic copolymer based on an isoporphyrin and on a pyridine end-decorated molybdenum(II) halide cluster. The photoelectrochemical properties have been investigated under visible-NIR light irradiation. [Display omitted]</abstract><cop>Oxford</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.electacta.2021.138493</doi><orcidid>https://orcid.org/0000-0002-1103-2927</orcidid><orcidid>https://orcid.org/0000-0002-8587-5644</orcidid><orcidid>https://orcid.org/0000-0003-1005-3555</orcidid><orcidid>https://orcid.org/0000-0002-5566-3712</orcidid><orcidid>https://orcid.org/0000-0003-1154-2422</orcidid><orcidid>https://orcid.org/0000-0003-4640-0475</orcidid><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0013-4686 |
| ispartof | Electrochimica acta, 2021-08, Vol.388, p.138493, Article 138493 |
| issn | 0013-4686 1873-3859 |
| language | eng |
| recordid | cdi_hal_primary_oai_HAL_hal_03692812v1 |
| source | ScienceDirect Journals (5 years ago - present) |
| subjects | Atomic force microscopy Chemical Sciences Clusters Coordination chemistry Copolymers Decoration Electrochemical impedance spectroscopy Electrochemistry Electron paramagnetic resonance Electron spin Electrons Electropolymerization Isoporphyrin Light irradiation Microbalances Molybdenum Molybdenum(II) halide cluster Organic–inorganic hybrid composites Photocurrent generation Photoelectric effect Photoelectric emission Photoelectrons Polymerization Polymers Porphyrinoids Porphyrins Quartz crystals Spectrum analysis Spin resonance Thin films X ray photoelectron spectroscopy |
| title | A 3D electropolymerized thin film based on an isoporphyrin and on a pyridine end-decorated molybdenum(II) halide cluster: Photoelectrochemical and impedance properties |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-15T20%3A26%3A53IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_hal_p&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=A%203D%20electropolymerized%20thin%20film%20based%20on%20an%20isoporphyrin%20and%20on%20a%20pyridine%20end-decorated%20molybdenum(II)%20halide%20cluster:%20Photoelectrochemical%20and%20impedance%20properties&rft.jtitle=Electrochimica%20acta&rft.au=Liang,%20Yiming&rft.date=2021-08-20&rft.volume=388&rft.spage=138493&rft.pages=138493-&rft.artnum=138493&rft.issn=0013-4686&rft.eissn=1873-3859&rft_id=info:doi/10.1016/j.electacta.2021.138493&rft_dat=%3Cproquest_hal_p%3E2551713837%3C/proquest_hal_p%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2551713837&rft_id=info:pmid/&rft_els_id=S0013468621007830&rfr_iscdi=true |