MIL-101(Cr) MOF as an Effective Siloxane Sensor

MIL-101(Cr) MOF as an Effective Siloxane Sensor

Volatile methylsiloxanes (VMSs) are common silicone degradation byproducts that cause serious concern for the contamination of sensitive electronics and optics, among others. With the goal of fast, online detection of VMS, we herein highlight the mesoporous MIL-101­(Cr) MOF as a promising mass sensi...

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Veröffentlicht in:ACS applied materials & interfaces 2022-04, Vol.14 (15), p.17531-17538
Hauptverfasser: Iacomi, Paul, Gulcay-Ozcan, Ezgi, Pires Conti, Patrick, Biswas, Subharanjan, Steunou, Nathalie, Maurin, Guillaume, Rioland, Guillaume, Devautour-Vinot, Sabine
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Chemical Sciences
Energy, Environmental, and Catalysis Applications
Material chemistry
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container_end_page 17538
container_issue 15
container_start_page 17531
container_title ACS applied materials & interfaces
container_volume 14
creator Iacomi, Paul
Gulcay-Ozcan, Ezgi
Pires Conti, Patrick
Biswas, Subharanjan
Steunou, Nathalie
Maurin, Guillaume
Rioland, Guillaume
Devautour-Vinot, Sabine
description Volatile methylsiloxanes (VMSs) are common silicone degradation byproducts that cause serious concern for the contamination of sensitive electronics and optics, among others. With the goal of fast, online detection of VMS, we herein highlight the mesoporous MIL-101­(Cr) MOF as a promising mass sensing layer for integration with a quartz crystal microbalance (QCM), using an in-house modified gravimetric adsorption system capable of achieving extremely low concentrations of siloxane D4 (down to 0.04 ppm), targeting applications for monitoring in indoor spaces and spacecraft. Our developed MIL-101­(Cr)@QCM sensor achieves near-perfect reversibility with no hysteresis alongside excellent repeatability over cycling and fast response/recovery times under 1 min. We attribute this capability to optimum host/guest interactions as uncovered through molecular simulations.
doi_str_mv 10.1021/acsami.2c02607
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Material chemistry
title MIL-101(Cr) MOF as an Effective Siloxane Sensor
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