Simple and highly sensitive 2-hydroxy-1,4-naphthoquinone/glassy carbon sensor for the electrochemical detection of [Ni(CN)4]2− in metallurgical industry wastewater
The pollution generated by the metallurgical industry effluents represents a serious issue for human health and the environment where the presence of cyanide species is particularly dangerous even at low concentration. In this context, we have developed an electrochemical sensor based on a glassy ca...
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| Veröffentlicht in: | Journal of applied electrochemistry 2022-07, Vol.52 (7), p.1053-1065 |
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| creator | Cardenas-Riojas, Andy A. Muedas-Taipe, Golfer La Rosa-Toro, Adolfo Sotomayor, Maria D. P. T. Ponce-Vargas, Miguel Baena-Moncada, Angélica M. |
| description | The pollution generated by the metallurgical industry effluents represents a serious issue for human health and the environment where the presence of cyanide species is particularly dangerous even at low concentration. In this context, we have developed an electrochemical sensor based on a glassy carbon (GC) electrode modified with 2-hydroxy-1,4-naphthoquinone (HNFQ) for the detection of the
[
Ni
(
CN
)
4
]
(
aq
)
2
-
complex ion from galvanic wastewater. It was characterized by physicochemical techniques such as Raman spectroscopy, electrochemical spectroscopy impedance, and UV–Visible spectroscopy. The electrochemical detection of the complex ion
[
Ni
(
CN
)
4
]
(
aq
)
2
-
was carried out by the square-wave voltammetry electrochemical technique. The GC/HNFQ electrochemical sensor features a wide linear range of 1.28 × 10
–5
–1.63 × 10
–3
mol L
−1
with a determination coefficient
R
2
of 0.9993, a limit of detection (LOD) of 3.31 ± 2.21 µmol L
−1
, and a limit of quantification (LOQ) of 10.93 ± 7.31 µmol L
−1
. Moreover, the proposed sensor displays excellent selectivity to the interfering ions (
K
+
,
Na
+
,
Cl
-
,
NO
3
-
,
SO
4
2
-
,
and
HCO
3
-
). Finally, in order to investigate the molecular interplay between the involved species at the electrode-solution interface, a computational study in the framework of DFT has been conducted, which suggests a parallel orientation of a formed Ni(II)-bis(2-hydroxy-1,4-naphthoquinonate) complex and a graphitic domain of the glassy carbon surface.
Graphical abstract |
| doi_str_mv | 10.1007/s10800-022-01691-0 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_hal_p</sourceid><recordid>TN_cdi_hal_primary_oai_HAL_hal_03627773v1</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2667248496</sourcerecordid><originalsourceid>FETCH-LOGICAL-c283t-ea0efda001f48fa13414113d77f47595fb470330f719d9af2190c1fb414a7a8b3</originalsourceid><addsrcrecordid>eNp9kcGKFDEURYMo2Lb-gKuAGweM816SrlQth0YdoRkXKggiRboq6cpQnbRJesb6A9f-gz_ml5jpEt25eAQu5973yCXkKcJLBFDnCaEGYMA5A6waZHCPLHClOKtrUd8nCwCOrG7w00PyKKVrAGh4JRfk53u3P4yGat_Twe2GcaLJ-OSyuzGUs2HqY_g2MXwhmdeHIQ_h69H54M35btQpTbTTcRv8yRQitWXyYKgZTZdj6Aazd50eaW9yEVwBg6Wfr9zz9dWZ_MJ_ff9Bnad7k_U4HuPuxDrfH1OOE73VKZtbnU18TB5YPSbz5M-7JB9fv_qwvmSbd2_eri82rOO1yMxoMLbXAGhlbTUKiRJR9EpZqVbNym6lAiHAKmz6RluODXRYVJRa6XorluRszh302B6i2-s4tUG79vJi095pICqulBI3WNhnM3uI5U9Myu11OEZfzmt5VSkua9lUheIz1cWQUjT2byxCe1ddO1fXluraU3Vlx5KI2ZQK7Hcm_ov-j-s3h9Sevw</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2667248496</pqid></control><display><type>article</type><title>Simple and highly sensitive 2-hydroxy-1,4-naphthoquinone/glassy carbon sensor for the electrochemical detection of [Ni(CN)4]2− in metallurgical industry wastewater</title><source>SpringerNature Journals</source><creator>Cardenas-Riojas, Andy A. ; Muedas-Taipe, Golfer ; La Rosa-Toro, Adolfo ; Sotomayor, Maria D. P. T. ; Ponce-Vargas, Miguel ; Baena-Moncada, Angélica M.</creator><creatorcontrib>Cardenas-Riojas, Andy A. ; Muedas-Taipe, Golfer ; La Rosa-Toro, Adolfo ; Sotomayor, Maria D. P. T. ; Ponce-Vargas, Miguel ; Baena-Moncada, Angélica M.</creatorcontrib><description>The pollution generated by the metallurgical industry effluents represents a serious issue for human health and the environment where the presence of cyanide species is particularly dangerous even at low concentration. In this context, we have developed an electrochemical sensor based on a glassy carbon (GC) electrode modified with 2-hydroxy-1,4-naphthoquinone (HNFQ) for the detection of the
[
Ni
(
CN
)
4
]
(
aq
)
2
-
complex ion from galvanic wastewater. It was characterized by physicochemical techniques such as Raman spectroscopy, electrochemical spectroscopy impedance, and UV–Visible spectroscopy. The electrochemical detection of the complex ion
[
Ni
(
CN
)
4
]
(
aq
)
2
-
was carried out by the square-wave voltammetry electrochemical technique. The GC/HNFQ electrochemical sensor features a wide linear range of 1.28 × 10
–5
–1.63 × 10
–3
mol L
−1
with a determination coefficient
R
2
of 0.9993, a limit of detection (LOD) of 3.31 ± 2.21 µmol L
−1
, and a limit of quantification (LOQ) of 10.93 ± 7.31 µmol L
−1
. Moreover, the proposed sensor displays excellent selectivity to the interfering ions (
K
+
,
Na
+
,
Cl
-
,
NO
3
-
,
SO
4
2
-
,
and
HCO
3
-
). Finally, in order to investigate the molecular interplay between the involved species at the electrode-solution interface, a computational study in the framework of DFT has been conducted, which suggests a parallel orientation of a formed Ni(II)-bis(2-hydroxy-1,4-naphthoquinonate) complex and a graphitic domain of the glassy carbon surface.
Graphical abstract</description><identifier>ISSN: 0021-891X</identifier><identifier>EISSN: 1572-8838</identifier><identifier>DOI: 10.1007/s10800-022-01691-0</identifier><language>eng</language><publisher>Dordrecht: Springer Netherlands</publisher><subject>Carbon ; Chemical Sciences ; Chemical sensors ; Chemistry ; Chemistry and Materials Science ; Electrochemical analysis ; Electrochemistry ; Electrodes ; Glassy carbon ; Industrial Chemistry/Chemical Engineering ; Industrial effluents ; Metallurgy ; Physical Chemistry ; Raman spectroscopy ; Research Article ; Selectivity ; Sensors ; Spectrum analysis ; Wastewater</subject><ispartof>Journal of applied electrochemistry, 2022-07, Vol.52 (7), p.1053-1065</ispartof><rights>The Author(s), under exclusive licence to Springer Nature B.V. 2022</rights><rights>The Author(s), under exclusive licence to Springer Nature B.V. 2022.</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c283t-ea0efda001f48fa13414113d77f47595fb470330f719d9af2190c1fb414a7a8b3</citedby><cites>FETCH-LOGICAL-c283t-ea0efda001f48fa13414113d77f47595fb470330f719d9af2190c1fb414a7a8b3</cites><orcidid>0000-0002-2896-4392</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10800-022-01691-0$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10800-022-01691-0$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>230,315,782,786,887,27933,27934,41497,42566,51328</link.rule.ids><backlink>$$Uhttps://hal.univ-reims.fr/hal-03627773$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Cardenas-Riojas, Andy A.</creatorcontrib><creatorcontrib>Muedas-Taipe, Golfer</creatorcontrib><creatorcontrib>La Rosa-Toro, Adolfo</creatorcontrib><creatorcontrib>Sotomayor, Maria D. P. T.</creatorcontrib><creatorcontrib>Ponce-Vargas, Miguel</creatorcontrib><creatorcontrib>Baena-Moncada, Angélica M.</creatorcontrib><title>Simple and highly sensitive 2-hydroxy-1,4-naphthoquinone/glassy carbon sensor for the electrochemical detection of [Ni(CN)4]2− in metallurgical industry wastewater</title><title>Journal of applied electrochemistry</title><addtitle>J Appl Electrochem</addtitle><description>The pollution generated by the metallurgical industry effluents represents a serious issue for human health and the environment where the presence of cyanide species is particularly dangerous even at low concentration. In this context, we have developed an electrochemical sensor based on a glassy carbon (GC) electrode modified with 2-hydroxy-1,4-naphthoquinone (HNFQ) for the detection of the
[
Ni
(
CN
)
4
]
(
aq
)
2
-
complex ion from galvanic wastewater. It was characterized by physicochemical techniques such as Raman spectroscopy, electrochemical spectroscopy impedance, and UV–Visible spectroscopy. The electrochemical detection of the complex ion
[
Ni
(
CN
)
4
]
(
aq
)
2
-
was carried out by the square-wave voltammetry electrochemical technique. The GC/HNFQ electrochemical sensor features a wide linear range of 1.28 × 10
–5
–1.63 × 10
–3
mol L
−1
with a determination coefficient
R
2
of 0.9993, a limit of detection (LOD) of 3.31 ± 2.21 µmol L
−1
, and a limit of quantification (LOQ) of 10.93 ± 7.31 µmol L
−1
. Moreover, the proposed sensor displays excellent selectivity to the interfering ions (
K
+
,
Na
+
,
Cl
-
,
NO
3
-
,
SO
4
2
-
,
and
HCO
3
-
). Finally, in order to investigate the molecular interplay between the involved species at the electrode-solution interface, a computational study in the framework of DFT has been conducted, which suggests a parallel orientation of a formed Ni(II)-bis(2-hydroxy-1,4-naphthoquinonate) complex and a graphitic domain of the glassy carbon surface.
Graphical abstract</description><subject>Carbon</subject><subject>Chemical Sciences</subject><subject>Chemical sensors</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Electrochemical analysis</subject><subject>Electrochemistry</subject><subject>Electrodes</subject><subject>Glassy carbon</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Industrial effluents</subject><subject>Metallurgy</subject><subject>Physical Chemistry</subject><subject>Raman spectroscopy</subject><subject>Research Article</subject><subject>Selectivity</subject><subject>Sensors</subject><subject>Spectrum analysis</subject><subject>Wastewater</subject><issn>0021-891X</issn><issn>1572-8838</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNp9kcGKFDEURYMo2Lb-gKuAGweM816SrlQth0YdoRkXKggiRboq6cpQnbRJesb6A9f-gz_ml5jpEt25eAQu5973yCXkKcJLBFDnCaEGYMA5A6waZHCPLHClOKtrUd8nCwCOrG7w00PyKKVrAGh4JRfk53u3P4yGat_Twe2GcaLJ-OSyuzGUs2HqY_g2MXwhmdeHIQ_h69H54M35btQpTbTTcRv8yRQitWXyYKgZTZdj6Aazd50eaW9yEVwBg6Wfr9zz9dWZ_MJ_ff9Bnad7k_U4HuPuxDrfH1OOE73VKZtbnU18TB5YPSbz5M-7JB9fv_qwvmSbd2_eri82rOO1yMxoMLbXAGhlbTUKiRJR9EpZqVbNym6lAiHAKmz6RluODXRYVJRa6XorluRszh302B6i2-s4tUG79vJi095pICqulBI3WNhnM3uI5U9Myu11OEZfzmt5VSkua9lUheIz1cWQUjT2byxCe1ddO1fXluraU3Vlx5KI2ZQK7Hcm_ov-j-s3h9Sevw</recordid><startdate>20220701</startdate><enddate>20220701</enddate><creator>Cardenas-Riojas, Andy A.</creator><creator>Muedas-Taipe, Golfer</creator><creator>La Rosa-Toro, Adolfo</creator><creator>Sotomayor, Maria D. P. T.</creator><creator>Ponce-Vargas, Miguel</creator><creator>Baena-Moncada, Angélica M.</creator><general>Springer Netherlands</general><general>Springer Nature B.V</general><general>Springer Verlag</general><scope>AAYXX</scope><scope>CITATION</scope><scope>1XC</scope><orcidid>https://orcid.org/0000-0002-2896-4392</orcidid></search><sort><creationdate>20220701</creationdate><title>Simple and highly sensitive 2-hydroxy-1,4-naphthoquinone/glassy carbon sensor for the electrochemical detection of [Ni(CN)4]2− in metallurgical industry wastewater</title><author>Cardenas-Riojas, Andy A. ; Muedas-Taipe, Golfer ; La Rosa-Toro, Adolfo ; Sotomayor, Maria D. P. T. ; Ponce-Vargas, Miguel ; Baena-Moncada, Angélica M.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c283t-ea0efda001f48fa13414113d77f47595fb470330f719d9af2190c1fb414a7a8b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Carbon</topic><topic>Chemical Sciences</topic><topic>Chemical sensors</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Electrochemical analysis</topic><topic>Electrochemistry</topic><topic>Electrodes</topic><topic>Glassy carbon</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Industrial effluents</topic><topic>Metallurgy</topic><topic>Physical Chemistry</topic><topic>Raman spectroscopy</topic><topic>Research Article</topic><topic>Selectivity</topic><topic>Sensors</topic><topic>Spectrum analysis</topic><topic>Wastewater</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Cardenas-Riojas, Andy A.</creatorcontrib><creatorcontrib>Muedas-Taipe, Golfer</creatorcontrib><creatorcontrib>La Rosa-Toro, Adolfo</creatorcontrib><creatorcontrib>Sotomayor, Maria D. P. T.</creatorcontrib><creatorcontrib>Ponce-Vargas, Miguel</creatorcontrib><creatorcontrib>Baena-Moncada, Angélica M.</creatorcontrib><collection>CrossRef</collection><collection>Hyper Article en Ligne (HAL)</collection><jtitle>Journal of applied electrochemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Cardenas-Riojas, Andy A.</au><au>Muedas-Taipe, Golfer</au><au>La Rosa-Toro, Adolfo</au><au>Sotomayor, Maria D. P. T.</au><au>Ponce-Vargas, Miguel</au><au>Baena-Moncada, Angélica M.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Simple and highly sensitive 2-hydroxy-1,4-naphthoquinone/glassy carbon sensor for the electrochemical detection of [Ni(CN)4]2− in metallurgical industry wastewater</atitle><jtitle>Journal of applied electrochemistry</jtitle><stitle>J Appl Electrochem</stitle><date>2022-07-01</date><risdate>2022</risdate><volume>52</volume><issue>7</issue><spage>1053</spage><epage>1065</epage><pages>1053-1065</pages><issn>0021-891X</issn><eissn>1572-8838</eissn><abstract>The pollution generated by the metallurgical industry effluents represents a serious issue for human health and the environment where the presence of cyanide species is particularly dangerous even at low concentration. In this context, we have developed an electrochemical sensor based on a glassy carbon (GC) electrode modified with 2-hydroxy-1,4-naphthoquinone (HNFQ) for the detection of the
[
Ni
(
CN
)
4
]
(
aq
)
2
-
complex ion from galvanic wastewater. It was characterized by physicochemical techniques such as Raman spectroscopy, electrochemical spectroscopy impedance, and UV–Visible spectroscopy. The electrochemical detection of the complex ion
[
Ni
(
CN
)
4
]
(
aq
)
2
-
was carried out by the square-wave voltammetry electrochemical technique. The GC/HNFQ electrochemical sensor features a wide linear range of 1.28 × 10
–5
–1.63 × 10
–3
mol L
−1
with a determination coefficient
R
2
of 0.9993, a limit of detection (LOD) of 3.31 ± 2.21 µmol L
−1
, and a limit of quantification (LOQ) of 10.93 ± 7.31 µmol L
−1
. Moreover, the proposed sensor displays excellent selectivity to the interfering ions (
K
+
,
Na
+
,
Cl
-
,
NO
3
-
,
SO
4
2
-
,
and
HCO
3
-
). Finally, in order to investigate the molecular interplay between the involved species at the electrode-solution interface, a computational study in the framework of DFT has been conducted, which suggests a parallel orientation of a formed Ni(II)-bis(2-hydroxy-1,4-naphthoquinonate) complex and a graphitic domain of the glassy carbon surface.
Graphical abstract</abstract><cop>Dordrecht</cop><pub>Springer Netherlands</pub><doi>10.1007/s10800-022-01691-0</doi><tpages>13</tpages><orcidid>https://orcid.org/0000-0002-2896-4392</orcidid></addata></record> |
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| ispartof | Journal of applied electrochemistry, 2022-07, Vol.52 (7), p.1053-1065 |
| issn | 0021-891X 1572-8838 |
| language | eng |
| recordid | cdi_hal_primary_oai_HAL_hal_03627773v1 |
| source | SpringerNature Journals |
| subjects | Carbon Chemical Sciences Chemical sensors Chemistry Chemistry and Materials Science Electrochemical analysis Electrochemistry Electrodes Glassy carbon Industrial Chemistry/Chemical Engineering Industrial effluents Metallurgy Physical Chemistry Raman spectroscopy Research Article Selectivity Sensors Spectrum analysis Wastewater |
| title | Simple and highly sensitive 2-hydroxy-1,4-naphthoquinone/glassy carbon sensor for the electrochemical detection of [Ni(CN)4]2− in metallurgical industry wastewater |
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