A New Organic–Inorganic Hybrid Compound: Synthesis, crystal structure, Hirshfeld surface analysis, vibrational, optical, magnetic properties and theoretical study
[Display omitted] Renewable technologies represent a solution to reduce the energy demand and dependency on fossil fuels. Here, attention is focused on organic inorganic hybrids used in photovoltaic. The present work is the investigation of a new organic–inorganic hybrid C4H10Cl3NO2Sn that crystalli...
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| Veröffentlicht in: | Polyhedron 2022-05, Vol.217, p.115717, Article 115717 |
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| creator | Kaiba, A. Geesi, Mohammed H. Guionneau, P. |
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Renewable technologies represent a solution to reduce the energy demand and dependency on fossil fuels. Here, attention is focused on organic inorganic hybrids used in photovoltaic. The present work is the investigation of a new organic–inorganic hybrid C4H10Cl3NO2Sn that crystallizes in a monoclinic system with C2/c space group and unit cell parameters (a = 32.071(5) Å, b = 5.827(5) Å, c = 11.596(5) Å, β = 94.858(5) °, and Z = 4) at room temperature. The crystal structure exploration reveal the stabilization of the crystal packing is carried out by a complex network of hydrogen interactions that lead formation of layered organic- inorganic hybrid stacked along the a-axis. The intermolecular interactions were elucidated by Hirchfeld surface analysis and fingerprint plots. The vibration modes were probed by Micro-Raman spectroscopy. Also, the vibrating sample magnetometer (VSM) measurement shows the ferromagnetism aspect of the compound as well as the energy gap was estimated from UV–visible absorption spectroscopy. |
| doi_str_mv | 10.1016/j.poly.2022.115717 |
| format | Article |
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Renewable technologies represent a solution to reduce the energy demand and dependency on fossil fuels. Here, attention is focused on organic inorganic hybrids used in photovoltaic. The present work is the investigation of a new organic–inorganic hybrid C4H10Cl3NO2Sn that crystallizes in a monoclinic system with C2/c space group and unit cell parameters (a = 32.071(5) Å, b = 5.827(5) Å, c = 11.596(5) Å, β = 94.858(5) °, and Z = 4) at room temperature. The crystal structure exploration reveal the stabilization of the crystal packing is carried out by a complex network of hydrogen interactions that lead formation of layered organic- inorganic hybrid stacked along the a-axis. The intermolecular interactions were elucidated by Hirchfeld surface analysis and fingerprint plots. The vibration modes were probed by Micro-Raman spectroscopy. Also, the vibrating sample magnetometer (VSM) measurement shows the ferromagnetism aspect of the compound as well as the energy gap was estimated from UV–visible absorption spectroscopy.</description><identifier>ISSN: 0277-5387</identifier><identifier>EISSN: 0277-5387</identifier><identifier>DOI: 10.1016/j.poly.2022.115717</identifier><language>eng</language><publisher>Elsevier Ltd</publisher><subject>Chemical Sciences ; DFT ; Hirshfeld surface ; Material chemistry ; Organic- inorganic hybrid ; Raman spectroscopy ; VSM ; XRD</subject><ispartof>Polyhedron, 2022-05, Vol.217, p.115717, Article 115717</ispartof><rights>2022 Elsevier Ltd</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c334t-c9d5da30bad7d8f6694bb660c53198d6332cbe5463f1f5a945e00472e8a9082a3</citedby><cites>FETCH-LOGICAL-c334t-c9d5da30bad7d8f6694bb660c53198d6332cbe5463f1f5a945e00472e8a9082a3</cites><orcidid>0000-0002-5587-4675 ; 0000-0003-4693-7715</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0277538722000699$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>230,314,776,780,881,3537,27903,27904,65309</link.rule.ids><backlink>$$Uhttps://hal.science/hal-03602136$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Kaiba, A.</creatorcontrib><creatorcontrib>Geesi, Mohammed H.</creatorcontrib><creatorcontrib>Guionneau, P.</creatorcontrib><title>A New Organic–Inorganic Hybrid Compound: Synthesis, crystal structure, Hirshfeld surface analysis, vibrational, optical, magnetic properties and theoretical study</title><title>Polyhedron</title><description>[Display omitted]
Renewable technologies represent a solution to reduce the energy demand and dependency on fossil fuels. Here, attention is focused on organic inorganic hybrids used in photovoltaic. The present work is the investigation of a new organic–inorganic hybrid C4H10Cl3NO2Sn that crystallizes in a monoclinic system with C2/c space group and unit cell parameters (a = 32.071(5) Å, b = 5.827(5) Å, c = 11.596(5) Å, β = 94.858(5) °, and Z = 4) at room temperature. The crystal structure exploration reveal the stabilization of the crystal packing is carried out by a complex network of hydrogen interactions that lead formation of layered organic- inorganic hybrid stacked along the a-axis. The intermolecular interactions were elucidated by Hirchfeld surface analysis and fingerprint plots. The vibration modes were probed by Micro-Raman spectroscopy. Also, the vibrating sample magnetometer (VSM) measurement shows the ferromagnetism aspect of the compound as well as the energy gap was estimated from UV–visible absorption spectroscopy.</description><subject>Chemical Sciences</subject><subject>DFT</subject><subject>Hirshfeld surface</subject><subject>Material chemistry</subject><subject>Organic- inorganic hybrid</subject><subject>Raman spectroscopy</subject><subject>VSM</subject><subject>XRD</subject><issn>0277-5387</issn><issn>0277-5387</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNp9kU2O1DAQhSMEEsPABVh5i9Td-CdxEsSm1QJ6pBazANaWY1em3UrHUdnpUXbcgSvMyeYkOBOEWLGqp6f3Van0suwtoxtGmXx_2gy-mzaccr5hrChZ-Sy7orws14Woyuf_6JfZqxBONEE5E1fZw5Z8hXtyi3e6d-bx56-b3i-a7KcGnSU7fx782NsP5NvUxyMEF1bE4BSi7kiIOJo4IqzI3mE4ttBZEkZstQGie91NT_GLa1BH55OxIn6IzszirO96SJoM6AfA6CAkxpJ0xCM8hdKB0U6vsxet7gK8-TOvsx-fP33f7deH2y83u-1hbYTI49rUtrBa0Ebb0latlHXeNFJSUwhWV1YKwU0DRS5Fy9pC13kBlOYlh0rXtOJaXGfvlr1H3akB3VnjpLx2ar89qNmjQlLOhLywlOVL1qAPAaH9CzCq5k7USc2dqLkTtXSSoI8LBOmLiwNUwTjoDViHYKKy3v0P_w1lpZma</recordid><startdate>20220501</startdate><enddate>20220501</enddate><creator>Kaiba, A.</creator><creator>Geesi, Mohammed H.</creator><creator>Guionneau, P.</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>AAYXX</scope><scope>CITATION</scope><scope>1XC</scope><orcidid>https://orcid.org/0000-0002-5587-4675</orcidid><orcidid>https://orcid.org/0000-0003-4693-7715</orcidid></search><sort><creationdate>20220501</creationdate><title>A New Organic–Inorganic Hybrid Compound: Synthesis, crystal structure, Hirshfeld surface analysis, vibrational, optical, magnetic properties and theoretical study</title><author>Kaiba, A. ; Geesi, Mohammed H. ; Guionneau, P.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c334t-c9d5da30bad7d8f6694bb660c53198d6332cbe5463f1f5a945e00472e8a9082a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Chemical Sciences</topic><topic>DFT</topic><topic>Hirshfeld surface</topic><topic>Material chemistry</topic><topic>Organic- inorganic hybrid</topic><topic>Raman spectroscopy</topic><topic>VSM</topic><topic>XRD</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kaiba, A.</creatorcontrib><creatorcontrib>Geesi, Mohammed H.</creatorcontrib><creatorcontrib>Guionneau, P.</creatorcontrib><collection>CrossRef</collection><collection>Hyper Article en Ligne (HAL)</collection><jtitle>Polyhedron</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kaiba, A.</au><au>Geesi, Mohammed H.</au><au>Guionneau, P.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A New Organic–Inorganic Hybrid Compound: Synthesis, crystal structure, Hirshfeld surface analysis, vibrational, optical, magnetic properties and theoretical study</atitle><jtitle>Polyhedron</jtitle><date>2022-05-01</date><risdate>2022</risdate><volume>217</volume><spage>115717</spage><pages>115717-</pages><artnum>115717</artnum><issn>0277-5387</issn><eissn>0277-5387</eissn><abstract>[Display omitted]
Renewable technologies represent a solution to reduce the energy demand and dependency on fossil fuels. Here, attention is focused on organic inorganic hybrids used in photovoltaic. The present work is the investigation of a new organic–inorganic hybrid C4H10Cl3NO2Sn that crystallizes in a monoclinic system with C2/c space group and unit cell parameters (a = 32.071(5) Å, b = 5.827(5) Å, c = 11.596(5) Å, β = 94.858(5) °, and Z = 4) at room temperature. The crystal structure exploration reveal the stabilization of the crystal packing is carried out by a complex network of hydrogen interactions that lead formation of layered organic- inorganic hybrid stacked along the a-axis. The intermolecular interactions were elucidated by Hirchfeld surface analysis and fingerprint plots. The vibration modes were probed by Micro-Raman spectroscopy. Also, the vibrating sample magnetometer (VSM) measurement shows the ferromagnetism aspect of the compound as well as the energy gap was estimated from UV–visible absorption spectroscopy.</abstract><pub>Elsevier Ltd</pub><doi>10.1016/j.poly.2022.115717</doi><orcidid>https://orcid.org/0000-0002-5587-4675</orcidid><orcidid>https://orcid.org/0000-0003-4693-7715</orcidid></addata></record> |
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| source | Elsevier ScienceDirect Journals |
| subjects | Chemical Sciences DFT Hirshfeld surface Material chemistry Organic- inorganic hybrid Raman spectroscopy VSM XRD |
| title | A New Organic–Inorganic Hybrid Compound: Synthesis, crystal structure, Hirshfeld surface analysis, vibrational, optical, magnetic properties and theoretical study |
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