Vapor phase surface functionalization under ultra violet activation of parylene thin films grown by chemical vapor deposition

Various reactive gas phase treatments have been investigated as surface functionalization dry processes with the goal to improve the wettability of parylene C films, keeping good optical properties in the visible range. The films were grown on different substrates by chemical vapor deposition with t...

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Veröffentlicht in:Thin solid films 2010, Vol.518 (6), p.1675-1681
Hauptverfasser: Santucci, Virginie, Maury, Francis, Senocq, François
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creator Santucci, Virginie
Maury, Francis
Senocq, François
description Various reactive gas phase treatments have been investigated as surface functionalization dry processes with the goal to improve the wettability of parylene C films, keeping good optical properties in the visible range. The films were grown on different substrates by chemical vapor deposition with thicknesses ranging from 300 to 1630 nm. The polymer surface was treated under ultra violet (UV) irradiation at 254 nm in reactive atmospheres including He, H 2O, H 2O 2, O 2 and ambient air. The UV/O 2 treatment is the most efficient since the water contact angle decreases from 100° to 6° while the transmittance is maintained at 90% in the visible wavelengths. Furthermore it exhibits long life stability. The functionalization mechanism is discussed in relation with previous reports.
doi_str_mv 10.1016/j.tsf.2009.11.064
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subjects Aging
Chemical vapor deposition (including plasma-enhanced cvd, mocvd, etc.)
Condensed matter: electronic structure, electrical, magnetic, and optical properties
Condensed matter: structure, mechanical and thermal properties
Cross-disciplinary physics: materials science
rheology
Engineering Sciences
Exact sciences and technology
Materials
Materials science
Methods of deposition of films and coatings
film growth and epitaxy
Optical coatings
Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation
Optical properties of specific thin films
Parylene films
Physical radiation effects, radiation damage
Physics
Solid-fluid interfaces
Structure of solids and liquids
crystallography
Surface composition
Surface functionalization
Surfaces and interfaces
thin films and whiskers (structure and nonelectronic properties)
UV irradiation
Wetting
title Vapor phase surface functionalization under ultra violet activation of parylene thin films grown by chemical vapor deposition
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