Films from soft-core/hard-shell hydrophobic latexes: Structure and thermomechanical properties
Structured latexes provide a promising route to hard coatings without the use of coalescing aids. We studied the thermomechanical properties of films from structured soft‐core/hard‐shell hydrophobic latexes. We found that the mechanical properties of these films were closely related to their very pa...
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| Veröffentlicht in: | Journal of polymer science. Part B, Polymer physics Polymer physics, 2000-12, Vol.38 (23), p.2989-3000 |
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| container_issue | 23 |
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| container_title | Journal of polymer science. Part B, Polymer physics |
| container_volume | 38 |
| creator | Domingues Dos Santos, Fabrice Fabre, Pascale Drujon, Xavier Meunier, Gilles Leibler, Ludwik |
| description | Structured latexes provide a promising route to hard coatings without the use of coalescing aids. We studied the thermomechanical properties of films from structured soft‐core/hard‐shell hydrophobic latexes. We found that the mechanical properties of these films were closely related to their very particular organization. When the rigid phase was continuous, whatever its volume fraction, the films exhibited a high elastic modulus. An analysis of the viscoelastic properties of the films provided a good method for obtaining information about the interphase between the hard shell and soft core of the latex particles. By varying the film structure through annealing or the particle composition (core/shell ratio, core crosslinking, etc.), we were able to tune the mechanical properties of the films. © 2000 John Wiley & Sons, Inc. J Polym Sci B: Polym Phys 38: 2989–3000, 2000 |
| doi_str_mv | 10.1002/1099-0488(20001201)38:23<2989::AID-POLB10>3.0.CO;2-D |
| format | Article |
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We studied the thermomechanical properties of films from structured soft‐core/hard‐shell hydrophobic latexes. We found that the mechanical properties of these films were closely related to their very particular organization. When the rigid phase was continuous, whatever its volume fraction, the films exhibited a high elastic modulus. An analysis of the viscoelastic properties of the films provided a good method for obtaining information about the interphase between the hard shell and soft core of the latex particles. By varying the film structure through annealing or the particle composition (core/shell ratio, core crosslinking, etc.), we were able to tune the mechanical properties of the films. © 2000 John Wiley & Sons, Inc. 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J Polym Sci B: Polym Phys 38: 2989–3000, 2000</description><subject>Applied sciences</subject><subject>core-shell</subject><subject>Exact sciences and technology</subject><subject>Forms of application and semi-finished materials</subject><subject>interphase</subject><subject>latex films</subject><subject>Physics</subject><subject>Polymer industry, paints, wood</subject><subject>Sheets and films</subject><subject>structure</subject><subject>Technology of polymers</subject><subject>thermomechanical properties</subject><issn>0887-6266</issn><issn>1099-0488</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2000</creationdate><recordtype>article</recordtype><recordid>eNqVkV1v0zAUhiMEEmXwHyJxwy7cHdu1Y5cJqWvZh1S1aBvqHUdO4iiGpKnsDOi_x1FGr7hBsmTr6D3PsR8nySWFKQVgFxS0JjBT6gMDAMqAnnM1Z_ySaaXn88XdinzZrq8ofOJTmC63HxlZvUgmp7aXyQSUyohkUr5O3oTwPWK0FnqSfLt2TRvSyndtGrqqJ0Xn7UVtfElCbZsmrY-l7w51l7sibUxvf9swTx96_1T0T96mZl-mfW1927W2qM3eFaZJD7HD-t7Z8DZ5VZkm2HfP-1ny9frz4_KWrLc3d8vFmhSz-MJ4MYirFHRWMiW5zGxZZpRLyCnNJTCtdWYMU0BzLijLbFUCt1kOludCVIqfJecjtzYNHrxrjT9iZxzeLtY41IALIThTP2nMPo7ZwncheFudGijg4BsHcTiIw7--kcczx8E3YvSNo2_kCLjcIsNVxL4fsQcTooTKm33hwomdaaBUxNRuTP1yjT3-5-R_Dn6uRDIZyS7EXzqRjf-BMuOZwN3mBq82q939w0biPf8DOBKs-g</recordid><startdate>20001201</startdate><enddate>20001201</enddate><creator>Domingues Dos Santos, Fabrice</creator><creator>Fabre, Pascale</creator><creator>Drujon, Xavier</creator><creator>Meunier, Gilles</creator><creator>Leibler, Ludwik</creator><general>John Wiley & Sons, Inc</general><general>Wiley</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>1XC</scope></search><sort><creationdate>20001201</creationdate><title>Films from soft-core/hard-shell hydrophobic latexes: Structure and thermomechanical properties</title><author>Domingues Dos Santos, Fabrice ; Fabre, Pascale ; Drujon, Xavier ; Meunier, Gilles ; Leibler, Ludwik</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4100-620620d514d286367edd71360b11b6029997aa2801b35127efd03e7b0e3b55f83</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2000</creationdate><topic>Applied sciences</topic><topic>core-shell</topic><topic>Exact sciences and technology</topic><topic>Forms of application and semi-finished materials</topic><topic>interphase</topic><topic>latex films</topic><topic>Physics</topic><topic>Polymer industry, paints, wood</topic><topic>Sheets and films</topic><topic>structure</topic><topic>Technology of polymers</topic><topic>thermomechanical properties</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Domingues Dos Santos, Fabrice</creatorcontrib><creatorcontrib>Fabre, Pascale</creatorcontrib><creatorcontrib>Drujon, Xavier</creatorcontrib><creatorcontrib>Meunier, Gilles</creatorcontrib><creatorcontrib>Leibler, Ludwik</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Hyper Article en Ligne (HAL)</collection><jtitle>Journal of polymer science. Part B, Polymer physics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Domingues Dos Santos, Fabrice</au><au>Fabre, Pascale</au><au>Drujon, Xavier</au><au>Meunier, Gilles</au><au>Leibler, Ludwik</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Films from soft-core/hard-shell hydrophobic latexes: Structure and thermomechanical properties</atitle><jtitle>Journal of polymer science. Part B, Polymer physics</jtitle><addtitle>J. Polym. Sci. B Polym. Phys</addtitle><date>2000-12-01</date><risdate>2000</risdate><volume>38</volume><issue>23</issue><spage>2989</spage><epage>3000</epage><pages>2989-3000</pages><issn>0887-6266</issn><eissn>1099-0488</eissn><coden>JPLPAY</coden><abstract>Structured latexes provide a promising route to hard coatings without the use of coalescing aids. We studied the thermomechanical properties of films from structured soft‐core/hard‐shell hydrophobic latexes. We found that the mechanical properties of these films were closely related to their very particular organization. When the rigid phase was continuous, whatever its volume fraction, the films exhibited a high elastic modulus. An analysis of the viscoelastic properties of the films provided a good method for obtaining information about the interphase between the hard shell and soft core of the latex particles. By varying the film structure through annealing or the particle composition (core/shell ratio, core crosslinking, etc.), we were able to tune the mechanical properties of the films. © 2000 John Wiley & Sons, Inc. J Polym Sci B: Polym Phys 38: 2989–3000, 2000</abstract><cop>New York</cop><pub>John Wiley & Sons, Inc</pub><doi>10.1002/1099-0488(20001201)38:23<2989::AID-POLB10>3.0.CO;2-D</doi><tpages>12</tpages></addata></record> |
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| identifier | ISSN: 0887-6266 |
| ispartof | Journal of polymer science. Part B, Polymer physics, 2000-12, Vol.38 (23), p.2989-3000 |
| issn | 0887-6266 1099-0488 |
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| source | Wiley Journals |
| subjects | Applied sciences core-shell Exact sciences and technology Forms of application and semi-finished materials interphase latex films Physics Polymer industry, paints, wood Sheets and films structure Technology of polymers thermomechanical properties |
| title | Films from soft-core/hard-shell hydrophobic latexes: Structure and thermomechanical properties |
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