Corrosion behaviour of mechanically polished AA7075-T6 aluminium alloy

In the present study, the effects of mechanical polishing on the microstructure and corrosion behaviour of AA7075 aluminium alloy are investigated. It was found that a nano‐grained, near‐surface deformed layer, up to 400 nm thickness, is developed due to significant surface shear stress during mecha...

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Veröffentlicht in:Surface and interface analysis 2010-04, Vol.42 (4), p.185-188
Hauptverfasser: Liu, Y., Laurino, A., Hashimoto, T., Zhou, X., Skeldon, P., Thompson, G. E., Scamans, G. M., Blanc, C., Rainforth, W. M., Frolish, M. F.
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container_end_page 188
container_issue 4
container_start_page 185
container_title Surface and interface analysis
container_volume 42
creator Liu, Y.
Laurino, A.
Hashimoto, T.
Zhou, X.
Skeldon, P.
Thompson, G. E.
Scamans, G. M.
Blanc, C.
Rainforth, W. M.
Frolish, M. F.
description In the present study, the effects of mechanical polishing on the microstructure and corrosion behaviour of AA7075 aluminium alloy are investigated. It was found that a nano‐grained, near‐surface deformed layer, up to 400 nm thickness, is developed due to significant surface shear stress during mechanically polishing. Within the near‐surface deformed layer, the alloying elements have been redistributed and the microstructure of the alloy is modified; in particular, the normal MgZn2 particles for T6 are absent. However, segregation bands, approximately 10‐nm thick, containing mainly zinc, are found at the grain boundaries within the near‐surface deformed layer. The presence of such segregation bands promoted localised corrosion along the grain boundaries within the near‐surface deformed layer due to microgalvanic action. During anodic polarisation of mechanically polished alloy in sodium chloride solution, two breakdown potentials were observed at −750 mV and −700 mV, respectively. The first breakdown potential is associated with an increased electrochemical activity of the near‐surface deformed layer, and the second breakdown potential is associated with typical pitting of the bulk alloy. Copyright © 2009 John Wiley & Sons, Ltd.
doi_str_mv 10.1002/sia.3136
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The presence of such segregation bands promoted localised corrosion along the grain boundaries within the near‐surface deformed layer due to microgalvanic action. During anodic polarisation of mechanically polished alloy in sodium chloride solution, two breakdown potentials were observed at −750 mV and −700 mV, respectively. The first breakdown potential is associated with an increased electrochemical activity of the near‐surface deformed layer, and the second breakdown potential is associated with typical pitting of the bulk alloy. 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F.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Corrosion behaviour of mechanically polished AA7075-T6 aluminium alloy</atitle><jtitle>Surface and interface analysis</jtitle><addtitle>Surf. Interface Anal</addtitle><date>2010-04</date><risdate>2010</risdate><volume>42</volume><issue>4</issue><spage>185</spage><epage>188</epage><pages>185-188</pages><issn>0142-2421</issn><issn>1096-9918</issn><eissn>1096-9918</eissn><coden>SIANDQ</coden><abstract>In the present study, the effects of mechanical polishing on the microstructure and corrosion behaviour of AA7075 aluminium alloy are investigated. It was found that a nano‐grained, near‐surface deformed layer, up to 400 nm thickness, is developed due to significant surface shear stress during mechanically polishing. Within the near‐surface deformed layer, the alloying elements have been redistributed and the microstructure of the alloy is modified; in particular, the normal MgZn2 particles for T6 are absent. However, segregation bands, approximately 10‐nm thick, containing mainly zinc, are found at the grain boundaries within the near‐surface deformed layer. The presence of such segregation bands promoted localised corrosion along the grain boundaries within the near‐surface deformed layer due to microgalvanic action. During anodic polarisation of mechanically polished alloy in sodium chloride solution, two breakdown potentials were observed at −750 mV and −700 mV, respectively. The first breakdown potential is associated with an increased electrochemical activity of the near‐surface deformed layer, and the second breakdown potential is associated with typical pitting of the bulk alloy. Copyright © 2009 John Wiley &amp; Sons, Ltd.</abstract><cop>Chichester, UK</cop><pub>John Wiley &amp; Sons, Ltd</pub><doi>10.1002/sia.3136</doi><tpages>4</tpages><orcidid>https://orcid.org/0000-0003-2183-0671</orcidid><oa>free_for_read</oa></addata></record>
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source Wiley Online Library Journals Frontfile Complete
subjects AA7075 aluminium alloy
Alloying elements
Aluminum base alloys
Breakdown
Chemical Sciences
Condensed matter: structure, mechanical and thermal properties
corrosion
Cross-disciplinary physics: materials science
rheology
Defects and impurities in crystals
microstructure
Deformation
Engineering Sciences
Exact sciences and technology
Grain and twin boundaries
Grain boundaries
grain boundary
Material chemistry
Materials
Materials science
Nanostructure
near-surface deformed layer
Physics
Polished
Polishing
Segregations
Solid surfaces and solid-solid interfaces
Structure of solids and liquids
crystallography
Surface structure and topography
Surface treatments
Surfaces and interfaces
thin films and whiskers (structure and nonelectronic properties)
title Corrosion behaviour of mechanically polished AA7075-T6 aluminium alloy
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