Adsorption of isoproturon on homoionic clays
The adsorption of isoproturon (3-(4-isopropylphenyl)- 1,1 dimethylurea)] on a montmorillonite and on a kaolinite was studied by batch experiments and Fourier transform infrared spectroscopy (FT-IR). The clays were saturated with cations such as Al 3+, Ca 2+, Cu 2+, Na + and hexadecyl-trimethylammoni...
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| Veröffentlicht in: | Chemosphere (Oxford) 1997-12, Vol.35 (11), p.2619-2626 |
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| container_title | Chemosphere (Oxford) |
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| creator | Pantani, O.L. Dousset, S. Schiavon, M. Fusi, P. |
| description | The adsorption of isoproturon (3-(4-isopropylphenyl)- 1,1 dimethylurea)] on a montmorillonite and on a kaolinite was studied by batch experiments and Fourier transform infrared spectroscopy (FT-IR). The clays were saturated with cations such as Al
3+, Ca
2+, Cu
2+, Na
+ and hexadecyl-trimethylammonium (HDTMA). The studied clays did not show detectable catalytic activity on abiotic degradation of isoproturon, as evidenced by HPLC analysis. Adsorption was found related to clay specific external surface for HDTMA-saturated clays, while it seems independent from clay kind and inorganic cation. For clays saturated with inorganic cations, no penetration into the mont-morillonite interlayer was found and FT-IR spectroscopy showed the involvement of CO group of isoproturon in adsorption. |
| doi_str_mv | 10.1016/S0045-6535(97)00335-4 |
| format | Article |
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3+, Ca
2+, Cu
2+, Na
+ and hexadecyl-trimethylammonium (HDTMA). The studied clays did not show detectable catalytic activity on abiotic degradation of isoproturon, as evidenced by HPLC analysis. Adsorption was found related to clay specific external surface for HDTMA-saturated clays, while it seems independent from clay kind and inorganic cation. For clays saturated with inorganic cations, no penetration into the mont-morillonite interlayer was found and FT-IR spectroscopy showed the involvement of CO group of isoproturon in adsorption.</description><identifier>ISSN: 0045-6535</identifier><identifier>EISSN: 1879-1298</identifier><identifier>DOI: 10.1016/S0045-6535(97)00335-4</identifier><identifier>CODEN: CMSHAF</identifier><language>eng</language><publisher>Oxford: Elsevier Ltd</publisher><subject>adsorption ; Agricultural sciences ; aluminum ; Applied sciences ; Biological and physicochemical properties of pollutants. Interaction in the soil ; calcium ; cation saturation ; cations ; Chemistry ; copper ; Earth Sciences ; Environmental Engineering ; Environmental Sciences ; Exact sciences and technology ; General and physical chemistry ; Geochemistry ; herbicide residues ; hexadecyltrimethylammonium ; inorganic ions ; isoproturon ; kaolinite ; Life Sciences ; montmorillonite ; Pollution ; Sciences of the Universe ; sodium ; Soil and sediments pollution ; Soil study ; Solid-liquid interface ; Surface physical chemistry</subject><ispartof>Chemosphere (Oxford), 1997-12, Vol.35 (11), p.2619-2626</ispartof><rights>1997</rights><rights>1998 INIST-CNRS</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c394t-27de2b2a2131004fbadf5ce92df90aa2d14c0bfbfe5453ef073d3a5beac993cd3</citedby><cites>FETCH-LOGICAL-c394t-27de2b2a2131004fbadf5ce92df90aa2d14c0bfbfe5453ef073d3a5beac993cd3</cites><orcidid>0000-0002-4284-889X</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/S0045-6535(97)00335-4$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>230,314,777,781,882,3537,27905,27906,45976</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=2051390$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://hal.univ-lorraine.fr/hal-03550022$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Pantani, O.L.</creatorcontrib><creatorcontrib>Dousset, S.</creatorcontrib><creatorcontrib>Schiavon, M.</creatorcontrib><creatorcontrib>Fusi, P.</creatorcontrib><title>Adsorption of isoproturon on homoionic clays</title><title>Chemosphere (Oxford)</title><description>The adsorption of isoproturon (3-(4-isopropylphenyl)- 1,1 dimethylurea)] on a montmorillonite and on a kaolinite was studied by batch experiments and Fourier transform infrared spectroscopy (FT-IR). The clays were saturated with cations such as Al
3+, Ca
2+, Cu
2+, Na
+ and hexadecyl-trimethylammonium (HDTMA). The studied clays did not show detectable catalytic activity on abiotic degradation of isoproturon, as evidenced by HPLC analysis. Adsorption was found related to clay specific external surface for HDTMA-saturated clays, while it seems independent from clay kind and inorganic cation. For clays saturated with inorganic cations, no penetration into the mont-morillonite interlayer was found and FT-IR spectroscopy showed the involvement of CO group of isoproturon in adsorption.</description><subject>adsorption</subject><subject>Agricultural sciences</subject><subject>aluminum</subject><subject>Applied sciences</subject><subject>Biological and physicochemical properties of pollutants. Interaction in the soil</subject><subject>calcium</subject><subject>cation saturation</subject><subject>cations</subject><subject>Chemistry</subject><subject>copper</subject><subject>Earth Sciences</subject><subject>Environmental Engineering</subject><subject>Environmental Sciences</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><subject>Geochemistry</subject><subject>herbicide residues</subject><subject>hexadecyltrimethylammonium</subject><subject>inorganic ions</subject><subject>isoproturon</subject><subject>kaolinite</subject><subject>Life Sciences</subject><subject>montmorillonite</subject><subject>Pollution</subject><subject>Sciences of the Universe</subject><subject>sodium</subject><subject>Soil and sediments pollution</subject><subject>Soil study</subject><subject>Solid-liquid interface</subject><subject>Surface physical chemistry</subject><issn>0045-6535</issn><issn>1879-1298</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1997</creationdate><recordtype>article</recordtype><recordid>eNqFkE1LAzEQhoMoWKs_QdyDBwuuTpJNd3OSUtQKBQ-155DNh42sm5Kshf57s13p1dOQyfNkJi9C1xgeMODp4wqgYPmUUXbHywkApSwvTtAIVyXPMeHVKRodkXN0EeMXQBIZH6H7mY4-bDvn28zbzEW_Db77Cf2xzTb-26cbpzLVyH28RGdWNtFc_dUxWr88f8wX-fL99W0-W-aK8qLLSakNqYkkmOI019ZSW6YMJ9pykJJoXCiobW0NKxg1FkqqqWS1kYpzqjQdo8nw7kY2Yhvctwx74aUTi9lS9D2gjAEQssOJZQOrgo8xGHsUMIg-HnGIR_R_F7wUh3hEkbzbwdvKqGRjg2yVi0eZAMOUQ8JuBsxKL-RnSMh6RQBTIFVJphVJxNNAmJTIzpkgonKmVUa7YFQntHf_rPIL6FWCGQ</recordid><startdate>19971201</startdate><enddate>19971201</enddate><creator>Pantani, O.L.</creator><creator>Dousset, S.</creator><creator>Schiavon, M.</creator><creator>Fusi, P.</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>FBQ</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>1XC</scope><orcidid>https://orcid.org/0000-0002-4284-889X</orcidid></search><sort><creationdate>19971201</creationdate><title>Adsorption of isoproturon on homoionic clays</title><author>Pantani, O.L. ; Dousset, S. ; Schiavon, M. ; Fusi, P.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c394t-27de2b2a2131004fbadf5ce92df90aa2d14c0bfbfe5453ef073d3a5beac993cd3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1997</creationdate><topic>adsorption</topic><topic>Agricultural sciences</topic><topic>aluminum</topic><topic>Applied sciences</topic><topic>Biological and physicochemical properties of pollutants. Interaction in the soil</topic><topic>calcium</topic><topic>cation saturation</topic><topic>cations</topic><topic>Chemistry</topic><topic>copper</topic><topic>Earth Sciences</topic><topic>Environmental Engineering</topic><topic>Environmental Sciences</topic><topic>Exact sciences and technology</topic><topic>General and physical chemistry</topic><topic>Geochemistry</topic><topic>herbicide residues</topic><topic>hexadecyltrimethylammonium</topic><topic>inorganic ions</topic><topic>isoproturon</topic><topic>kaolinite</topic><topic>Life Sciences</topic><topic>montmorillonite</topic><topic>Pollution</topic><topic>Sciences of the Universe</topic><topic>sodium</topic><topic>Soil and sediments pollution</topic><topic>Soil study</topic><topic>Solid-liquid interface</topic><topic>Surface physical chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Pantani, O.L.</creatorcontrib><creatorcontrib>Dousset, S.</creatorcontrib><creatorcontrib>Schiavon, M.</creatorcontrib><creatorcontrib>Fusi, P.</creatorcontrib><collection>AGRIS</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Hyper Article en Ligne (HAL)</collection><jtitle>Chemosphere (Oxford)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Pantani, O.L.</au><au>Dousset, S.</au><au>Schiavon, M.</au><au>Fusi, P.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Adsorption of isoproturon on homoionic clays</atitle><jtitle>Chemosphere (Oxford)</jtitle><date>1997-12-01</date><risdate>1997</risdate><volume>35</volume><issue>11</issue><spage>2619</spage><epage>2626</epage><pages>2619-2626</pages><issn>0045-6535</issn><eissn>1879-1298</eissn><coden>CMSHAF</coden><abstract>The adsorption of isoproturon (3-(4-isopropylphenyl)- 1,1 dimethylurea)] on a montmorillonite and on a kaolinite was studied by batch experiments and Fourier transform infrared spectroscopy (FT-IR). The clays were saturated with cations such as Al
3+, Ca
2+, Cu
2+, Na
+ and hexadecyl-trimethylammonium (HDTMA). The studied clays did not show detectable catalytic activity on abiotic degradation of isoproturon, as evidenced by HPLC analysis. Adsorption was found related to clay specific external surface for HDTMA-saturated clays, while it seems independent from clay kind and inorganic cation. For clays saturated with inorganic cations, no penetration into the mont-morillonite interlayer was found and FT-IR spectroscopy showed the involvement of CO group of isoproturon in adsorption.</abstract><cop>Oxford</cop><pub>Elsevier Ltd</pub><doi>10.1016/S0045-6535(97)00335-4</doi><tpages>8</tpages><orcidid>https://orcid.org/0000-0002-4284-889X</orcidid></addata></record> |
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| source | Elsevier ScienceDirect Journals |
| subjects | adsorption Agricultural sciences aluminum Applied sciences Biological and physicochemical properties of pollutants. Interaction in the soil calcium cation saturation cations Chemistry copper Earth Sciences Environmental Engineering Environmental Sciences Exact sciences and technology General and physical chemistry Geochemistry herbicide residues hexadecyltrimethylammonium inorganic ions isoproturon kaolinite Life Sciences montmorillonite Pollution Sciences of the Universe sodium Soil and sediments pollution Soil study Solid-liquid interface Surface physical chemistry |
| title | Adsorption of isoproturon on homoionic clays |
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