A fast method to measure the degree of oxidation of dialdehyde celluloses using multivariate calibration and infrared spectroscopy

The properties of dialdehyde celluloses, which are usually generated by periodate oxidation, are highly dependent on the aldehyde content, i.e. the degree of oxidation (DO). Thus far, the established methods for determining the DO in dialdehyde celluloses lack simplicity or sufficient speed. More th...

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Veröffentlicht in:Carbohydrate polymers 2022-02, Vol.278, p.118887-118887, Article 118887
Hauptverfasser: Simon, Jonas, Tsetsgee, Otgontuul, Iqbal, Nohman Arshad, Sapkota, Janak, Ristolainen, Matti, Rosenau, Thomas, Potthast, Antje
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container_end_page 118887
container_issue
container_start_page 118887
container_title Carbohydrate polymers
container_volume 278
creator Simon, Jonas
Tsetsgee, Otgontuul
Iqbal, Nohman Arshad
Sapkota, Janak
Ristolainen, Matti
Rosenau, Thomas
Potthast, Antje
description The properties of dialdehyde celluloses, which are usually generated by periodate oxidation, are highly dependent on the aldehyde content, i.e. the degree of oxidation (DO). Thus far, the established methods for determining the DO in dialdehyde celluloses lack simplicity or sufficient speed. More than 60 dialdehyde cellulose samples with varying aldehyde content were analysed by near-infrared and Fourier-transform infrared spectroscopy. This was found to be a reliable method for quickly predicting the DO if combined with partial least squares regression (PLSR). The proposed PLSR models can predict the DO with a high determination coefficient (R2) of 99% when applied to a single pulp type and 94% when applied to multiple types. This new approach quickly and reliably determines the DO of dialdehyde celluloses. It can be easily implemented in everyday research to save money, time and resources, especially because the raw datasets and measured DO values are provided. [Display omitted]
doi_str_mv 10.1016/j.carbpol.2021.118887
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subjects Calibration
Carbohydrate Conformation
Cellulose - analogs & derivatives
Cellulose - chemistry
Chemical Sciences
Dialdehyde cellulose
Infrared spectroscopy
Multivariate calibration modelling
Near-infrared spectroscopy
Oxidation-Reduction
Partial least-squares regression
Periodate oxidation
Spectrophotometry, Infrared
title A fast method to measure the degree of oxidation of dialdehyde celluloses using multivariate calibration and infrared spectroscopy
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