Picosecond self-diffusion in ethanol-water mixtures
We report the self-diffusion in ethanol-water mixtures as a function of the water-ethanol ratio measured at different temperatures using quasi-elastic neutron spectroscopy (QENS). For our protiated samples, QENS is mainly sensitive to the dominant ensemble-averaged incoherent scattering from the hyd...
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Veröffentlicht in: | Physical chemistry chemical physics : PCCP 2019-05, Vol.21 (18), p.9547-9552 |
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creator | Seydel, Tilo Edkins, Robert M Edkins, Katharina |
description | We report the self-diffusion in ethanol-water mixtures as a function of the water-ethanol ratio measured at different temperatures using quasi-elastic neutron spectroscopy (QENS). For our protiated samples, QENS is mainly sensitive to the dominant ensemble-averaged incoherent scattering from the hydrogen atoms of the liquid mixtures. The energy range and resolution render our experiment sensitive to the picosecond time scale and nanometer length scale. These observation scales complement different scales accessible by nuclear magnetic resonance techniques. Subsequent to testing different models, we find that a simple jump-diffusion model averaging over both types of molecules, water and ethanol, best fits our data. |
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For our protiated samples, QENS is mainly sensitive to the dominant ensemble-averaged incoherent scattering from the hydrogen atoms of the liquid mixtures. The energy range and resolution render our experiment sensitive to the picosecond time scale and nanometer length scale. These observation scales complement different scales accessible by nuclear magnetic resonance techniques. 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Subsequent to testing different models, we find that a simple jump-diffusion model averaging over both types of molecules, water and ethanol, best fits our data.</description><subject>Condensed Matter</subject><subject>Ethanol</subject><subject>General Physics</subject><subject>Hydrogen atoms</subject><subject>Incoherent scattering</subject><subject>NMR</subject><subject>Nuclear magnetic resonance</subject><subject>Physics</subject><subject>Self diffusion</subject><subject>Soft Condensed Matter</subject><subject>Spectrum analysis</subject><issn>1463-9076</issn><issn>1463-9084</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNpd0E1PwzAMBuAIgRgMLvwAVIkLIBXipEmT41QBQ0xiBzhHaZpqGW0zmpaPf0_Hxg6cbFmPLPtF6AzwDWAqb400KwxSkLc9dAQJp7HEItnf9SkfoeMQlhhjYEAP0YgCJlim7AjRuTM-WOObIgq2KuPClWUfnG8i10S2W-jGV_Gn7mwb1e6r61sbTtBBqatgT7d1jF7v716yaTx7fnjMJrPYJIR0sRU2Jxw0BWOYTKyhuBCSM7Me5mBoKq3lXAAhORWpyLXhQkhhSoopTggdo6vN3oWu1Kp1tW6_lddOTScztZ5hykAkJP2AwV5u7Kr1770NnapdMLaqdGN9HxQhwDAFythAL_7Rpe_bZvhkUAQSkXKQg7reKNP6EFpb7i4ArNaxq0xm89_YnwZ8vl3Z57UtdvQvZ_oDrVd56Q</recordid><startdate>20190508</startdate><enddate>20190508</enddate><creator>Seydel, Tilo</creator><creator>Edkins, Robert M</creator><creator>Edkins, Katharina</creator><general>Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><scope>1XC</scope><orcidid>https://orcid.org/0000-0002-6885-5457</orcidid><orcidid>https://orcid.org/0000-0001-9630-1630</orcidid><orcidid>https://orcid.org/0000-0001-6117-5275</orcidid></search><sort><creationdate>20190508</creationdate><title>Picosecond self-diffusion in ethanol-water mixtures</title><author>Seydel, Tilo ; Edkins, Robert M ; Edkins, Katharina</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c422t-e8eb261a31cc594ec30d8965c261ab1c379ee668122b3878bac68898cf3030423</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Condensed Matter</topic><topic>Ethanol</topic><topic>General Physics</topic><topic>Hydrogen atoms</topic><topic>Incoherent scattering</topic><topic>NMR</topic><topic>Nuclear magnetic resonance</topic><topic>Physics</topic><topic>Self diffusion</topic><topic>Soft Condensed Matter</topic><topic>Spectrum analysis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Seydel, Tilo</creatorcontrib><creatorcontrib>Edkins, Robert M</creatorcontrib><creatorcontrib>Edkins, Katharina</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><collection>Hyper Article en Ligne (HAL)</collection><jtitle>Physical chemistry chemical physics : PCCP</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Seydel, Tilo</au><au>Edkins, Robert M</au><au>Edkins, Katharina</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Picosecond self-diffusion in ethanol-water mixtures</atitle><jtitle>Physical chemistry chemical physics : PCCP</jtitle><addtitle>Phys Chem Chem Phys</addtitle><date>2019-05-08</date><risdate>2019</risdate><volume>21</volume><issue>18</issue><spage>9547</spage><epage>9552</epage><pages>9547-9552</pages><issn>1463-9076</issn><eissn>1463-9084</eissn><abstract>We report the self-diffusion in ethanol-water mixtures as a function of the water-ethanol ratio measured at different temperatures using quasi-elastic neutron spectroscopy (QENS). 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subjects | Condensed Matter Ethanol General Physics Hydrogen atoms Incoherent scattering NMR Nuclear magnetic resonance Physics Self diffusion Soft Condensed Matter Spectrum analysis |
title | Picosecond self-diffusion in ethanol-water mixtures |
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